Exam 13: Chemical Kinetics: Reactions in the Atmosphere

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Ammonia gas (NH3) is produced from hydrogen and nitrogen gas according to the following reaction: Ammonia gas (NH<sub>3</sub>) is produced from hydrogen and nitrogen gas according to the following reaction:   If the rate of production of ammonia is R(NH<sub>3</sub>), what is the rate of loss of hydrogen and nitrogen gas, respectively? If the rate of production of ammonia is R(NH3), what is the rate of loss of hydrogen and nitrogen gas, respectively?

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The following graph shows the kinetics curves for the reaction of oxygen with hydrogen to form water: The following graph shows the kinetics curves for the reaction of oxygen with hydrogen to form water:   . Which curve is hydrogen?  . Which curve is hydrogen? The following graph shows the kinetics curves for the reaction of oxygen with hydrogen to form water:   . Which curve is hydrogen?

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Which of the following is a possible graph of concentration versus time for a reaction product?

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Assuming that each of the following graphs has the same concentration and time axes, which has the greatest initial rate of disappearance of reactant?

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The first-order reaction A The first-order reaction A   <font face=symbol></font>B, has k <font face=symbol></font> 5.67 s<font face=symbol><sup></sup></font><sup>1</sup>. If [A]<sub>0</sub> <font face=symbol></font> 0.500 M, how long will it take to reach [A] <font face=symbol></font> 0.124 M ? B, has k 5.67 s1. If [A]0 0.500 M, how long will it take to reach [A] 0.124 M ?

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Chlorine dioxide formed from chlorofluorocarbons was found to catalyze the decomposition of atmospheric ozone. In laboratory experiments, the rate of the catalyzed reaction was measured at different temperatures with the following results. What is the activation energy of this reaction? T (K) K (M1 s1) 193 34)0 208 197

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A proposed mechanism for the decomposition of ozone in the stratosphere is: Step 1: A proposed mechanism for the decomposition of ozone in the stratosphere is: Step 1:   Step 2:   What is the molecularity of step 1? Step 2: A proposed mechanism for the decomposition of ozone in the stratosphere is: Step 1:   Step 2:   What is the molecularity of step 1? What is the molecularity of step 1?

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Which of the following plots indicates that the reaction is zero order?

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The following figure shows Arrhenius plots for four different reactions. Which reaction has the least temperature dependence? The following figure shows Arrhenius plots for four different reactions. Which reaction has the least temperature dependence?

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A reaction mechanism consists of a series of ________ steps.

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Which of these could be the units of the rate constant for a first-order reaction?

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The reaction 2NO(g) O2(g) The reaction 2NO(g) <font face=symbol></font> O<sub>2</sub>(g)   <font face=symbol></font>2NO<sub>2</sub>(g) has the following rate law: Rate <font face=symbol></font> k[O<sub>2</sub>][NO]<sup>2</sup>. If the concentration of NO is reduced by a factor of two, the rate will ________ 2NO2(g) has the following rate law: Rate k[O2][NO]2. If the concentration of NO is reduced by a factor of two, the rate will ________

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The following figure shows Arrhenius plots for four different reactions. Which reaction has the greatest activation energy? The following figure shows Arrhenius plots for four different reactions. Which reaction has the greatest activation energy?

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For the reaction A For the reaction A   <font face=symbol></font>2B <font face=symbol></font> 3C, the rate of the reaction in terms of <font face=symbol></font>C would be written as ________. 2B 3C, the rate of the reaction in terms of C would be written as ________.

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A catalyst that is in a different phase from the reactants and products is a(n) ________ catalyst.

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Consider the rate law expression Rate k[A][B]2. Which of the following is not true about the reaction?

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Which of the following plots would indicate that a reaction was first order?

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Which point in the reaction profile below represents a transition state? Which point in the reaction profile below represents a transition state?

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In a(n) ________ step of a reaction mechanism, the partial orders (or molecularities) are determined by the stoichiometric coefficients of the reaction.

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Nitric oxide and nitrogen dioxide are found in photochemical smog. Nitrogen dioxide is formed from nitrogen monoxide in the exhaust of automobile engines. A possible mechanism for this reaction is given below. What is the rate law predicted by the mechanism? Reaction: Nitric oxide and nitrogen dioxide are found in photochemical smog. Nitrogen dioxide is formed from nitrogen monoxide in the exhaust of automobile engines. A possible mechanism for this reaction is given below. What is the rate law predicted by the mechanism? Reaction:   Step 1 (fast):   Step 2 (slow):  Step 1 (fast): Nitric oxide and nitrogen dioxide are found in photochemical smog. Nitrogen dioxide is formed from nitrogen monoxide in the exhaust of automobile engines. A possible mechanism for this reaction is given below. What is the rate law predicted by the mechanism? Reaction:   Step 1 (fast):   Step 2 (slow):  Step 2 (slow): Nitric oxide and nitrogen dioxide are found in photochemical smog. Nitrogen dioxide is formed from nitrogen monoxide in the exhaust of automobile engines. A possible mechanism for this reaction is given below. What is the rate law predicted by the mechanism? Reaction:   Step 1 (fast):   Step 2 (slow):

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