Exam 13: Chemical Kinetics: Reactions in the Atmosphere

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For the rate law Rate k[A]1/2[B], the partial order with respect to A is ________, the partial order with respect to B is ________, and the total order is ________.

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The energy profiles for four different reactions are shown below. The scales are the same for each. Which reaction is the most endothermic? The energy profiles for four different reactions are shown below. The scales are the same for each. Which reaction is the most endothermic?

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If the rate of appearance of O2 in the reaction: If the rate of appearance of O<sub>2</sub> in the reaction:   is 0.250 M/s over the first 5.50 s, how much oxygen will form during this time? is 0.250 M/s over the first 5.50 s, how much oxygen will form during this time?

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Given the following data for the reaction A Given the following data for the reaction A   <font face=symbol></font>B, determine the activation energy, E<sub>a</sub>, of the reaction. k (M/s) T (K) 2)04 <font face=symbol></font> 10<font face=symbol><sup></sup></font><sup>4</sup> 250 6)78 <font face=symbol></font> 10<font face=symbol><sup></sup></font><sup>3</sup> 400 B, determine the activation energy, Ea, of the reaction. k (M/s) T (K) 2)04 104 250 6)78 103 400

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The following figure shows Arrhenius plots for four different reactions. Which reaction has the greatest temperature dependence? The following figure shows Arrhenius plots for four different reactions. Which reaction has the greatest temperature dependence?

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The energy profiles for four different reactions are shown below. The scales are the same for each. Which reaction is the most exothermic? The energy profiles for four different reactions are shown below. The scales are the same for each. Which reaction is the most exothermic?

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The decomposition of ozone is thought to proceed through the following mechanism: Step 1: The decomposition of ozone is thought to proceed through the following mechanism: Step 1:   Step 2:   If the rate law <font face=symbol></font> k[O<sub>3</sub>][NO], what is the molecularity of steps 1 and 2, and which step is the slow, or rate-determining, step? Step 2: The decomposition of ozone is thought to proceed through the following mechanism: Step 1:   Step 2:   If the rate law <font face=symbol></font> k[O<sub>3</sub>][NO], what is the molecularity of steps 1 and 2, and which step is the slow, or rate-determining, step? If the rate law k[O3][NO], what is the molecularity of steps 1 and 2, and which step is the slow, or rate-determining, step?

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One reaction that contributes to acid rain is the conversion of dinitrogen pentoxide to nitric acid upon reaction with water. How could the rate of this reaction be expressed correctly in terms of the rate at which the concentration of a reactant or product changes? N2O5(g) H2O(g) One reaction that contributes to acid rain is the conversion of dinitrogen pentoxide to nitric acid upon reaction with water. How could the rate of this reaction be expressed correctly in terms of the rate at which the concentration of a reactant or product changes? N<sub>2</sub>O<sub>5</sub>(g) <font face=symbol></font> H<sub>2</sub>O(g)   <font face=symbol></font>2HNO<sub>3</sub>(g) 2HNO3(g)

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Given the following data for the reaction A Given the following data for the reaction A   <font face=symbol></font>B, determine the frequency factor, A, of the reaction.  B, determine the frequency factor, A, of the reaction. Given the following data for the reaction A   <font face=symbol></font>B, determine the frequency factor, A, of the reaction.

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The greatest NO concentration is observed ________

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The rate of popcorn popping at different temperatures was found to be described by the Arrhenius equation. How many times faster does the popcorn pop at 210°C compared with that at 180°C when the activation energy is 167 kJ/mol?

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From the following concentration versus time plot for four different reactions, which has the greatest instantaneous rate of disappearance at the time indicated by the arrow? From the following concentration versus time plot for four different reactions, which has the greatest instantaneous rate of disappearance at the time indicated by the arrow?

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What is the predicted rate law for the following mechanism for the decomposition of hydrogen peroxide? Step 1: What is the predicted rate law for the following mechanism for the decomposition of hydrogen peroxide? Step 1:   (slow) Step 2:   (fast) What is the rate law? (slow) Step 2: What is the predicted rate law for the following mechanism for the decomposition of hydrogen peroxide? Step 1:   (slow) Step 2:   (fast) What is the rate law? (fast) What is the rate law?

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The reaction A(g) B(g) The reaction A(g) <font face=symbol></font> B(g)   <font face=symbol></font>C(g) has the following rate law: Rate <font face=symbol></font> k[A]<sup>1/2</sup>[B]<sup>2</sup>. If the concentration of A is quadrupled while the concentration of B is halved, the rate will change by a factor of ________. C(g) has the following rate law: Rate k[A]1/2[B]2. If the concentration of A is quadrupled while the concentration of B is halved, the rate will change by a factor of ________.

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NO2 concentrations during photochemical smog events often have two peaks, one in the early morning (8 A.M.) and another, smaller peak around 7 P.M. The second peak is due to ________

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A proposed mechanism for the decomposition of ozone in the stratosphere is: Step 1: A proposed mechanism for the decomposition of ozone in the stratosphere is: Step 1:   Step 2:   What is the molecularity of step 2? Step 2: A proposed mechanism for the decomposition of ozone in the stratosphere is: Step 1:   Step 2:   What is the molecularity of step 2? What is the molecularity of step 2?

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For the reaction 2A 3B For the reaction 2A <font face=symbol></font> 3B   <font face=symbol></font>4C <font face=symbol></font> 5D, the rate of the reaction in terms of <font face=symbol></font>D would be written as ________. 4C 5D, the rate of the reaction in terms of D would be written as ________.

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Which of the following is not important as a contributing factor to photochemical smog?

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For the rate law Rate k[A]5/2[B], the partial order with respect to A is ________, the partial order with respect to B is ________, and the total order is ________.

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The half-life (t1/2) of a first-order reaction is 0.100 s. What is the rate constant?

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