Exam 13: Chemical Kinetics: Reactions in the Atmosphere

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The rate of popcorn popping at different temperatures was found to be described by the Arrhenius equation. How many times faster does the popcorn pop at 210°C compared with that at 180°C when the activation energy is 167 kJ/mol?

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N2O5 is used as a source of NO2 in chemical reactions. The compound decomposes in a first order reaction. If the initial concentration of N2O5 0.400 M, and the concentration is 0.025 M after 120 seconds, what is the rate constant k of the reaction?

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A scientist conducts an experiment to determine the rate of the following reaction: A scientist conducts an experiment to determine the rate of the following reaction:   If the initial concentration of H<sub>2</sub> was 0.150 M and the concentration of H<sub>2</sub> was 0.050 M after 2.10 s, what is the average rate of the reaction? If the initial concentration of H2 was 0.150 M and the concentration of H2 was 0.050 M after 2.10 s, what is the average rate of the reaction?

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One reaction that occurs in an automobile catalytic converter is the conversion of carbon monoxide to carbon dioxide. How is the rate of this reaction related to the rate at which the concentration of a reactant or product changes? 2CO(g) O2(g) →2CO2(g) I. Rate One reaction that occurs in an automobile catalytic converter is the conversion of carbon monoxide to carbon dioxide. How is the rate of this reaction related to the rate at which the concentration of a reactant or product changes? 2CO(g) <font face=symbol></font> O<sub>2</sub>(g) →2CO<sub>2</sub>(g) I. Rate <font face=symbol></font>   <font face=symbol></font>II. Rate <font face=symbol></font>   <font face=symbol></font>III. Rate <font face=symbol></font>   <font face=symbol></font>IV. Rate <font face=symbol></font>   <font face=symbol></font> II. Rate One reaction that occurs in an automobile catalytic converter is the conversion of carbon monoxide to carbon dioxide. How is the rate of this reaction related to the rate at which the concentration of a reactant or product changes? 2CO(g) <font face=symbol></font> O<sub>2</sub>(g) →2CO<sub>2</sub>(g) I. Rate <font face=symbol></font>   <font face=symbol></font>II. Rate <font face=symbol></font>   <font face=symbol></font>III. Rate <font face=symbol></font>   <font face=symbol></font>IV. Rate <font face=symbol></font>   <font face=symbol></font> III. Rate One reaction that occurs in an automobile catalytic converter is the conversion of carbon monoxide to carbon dioxide. How is the rate of this reaction related to the rate at which the concentration of a reactant or product changes? 2CO(g) <font face=symbol></font> O<sub>2</sub>(g) →2CO<sub>2</sub>(g) I. Rate <font face=symbol></font>   <font face=symbol></font>II. Rate <font face=symbol></font>   <font face=symbol></font>III. Rate <font face=symbol></font>   <font face=symbol></font>IV. Rate <font face=symbol></font>   <font face=symbol></font> IV. Rate One reaction that occurs in an automobile catalytic converter is the conversion of carbon monoxide to carbon dioxide. How is the rate of this reaction related to the rate at which the concentration of a reactant or product changes? 2CO(g) <font face=symbol></font> O<sub>2</sub>(g) →2CO<sub>2</sub>(g) I. Rate <font face=symbol></font>   <font face=symbol></font>II. Rate <font face=symbol></font>   <font face=symbol></font>III. Rate <font face=symbol></font>   <font face=symbol></font>IV. Rate <font face=symbol></font>   <font face=symbol></font>

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For the reaction 2A 3B For the reaction 2A <font face=symbol></font> 3B   <font face=symbol></font>4C <font face=symbol></font> 5D, the rate of the reaction in terms of <font face=symbol></font>A would be written as ________ 4C 5D, the rate of the reaction in terms of A would be written as ________

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The energy profiles for four different reactions are shown below. The scales are the same for each. Which reaction requires the least energetic collisions to reach the transition state? The energy profiles for four different reactions are shown below. The scales are the same for each. Which reaction requires the least energetic collisions to reach the transition state?

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The reaction A(g) B(g) The reaction A(g) <font face=symbol></font> B(g)   <font face=symbol></font>C(g) has the following rate law: Rate <font face=symbol></font> k[A]<sup>2</sup>[B]. If the concentration of A is tripled while the concentration of B is doubled, the rate will increase by a factor of ________. C(g) has the following rate law: Rate k[A]2[B]. If the concentration of A is tripled while the concentration of B is doubled, the rate will increase by a factor of ________.

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The steps in a reaction mechanism are as follows. Which species is acting as a catalyst? Step 1: The steps in a reaction mechanism are as follows. Which species is acting as a catalyst? Step 1:   Step 2:   Step 3:  Step 2: The steps in a reaction mechanism are as follows. Which species is acting as a catalyst? Step 1:   Step 2:   Step 3:  Step 3: The steps in a reaction mechanism are as follows. Which species is acting as a catalyst? Step 1:   Step 2:   Step 3:

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Collision theory assumes that the rate of a reaction depends on ________

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The device in automobiles that has decreased NO and partially oxidized hydrocarbons from exhaust gases is termed a(n) ________ .

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A scientist conducts an experiment to determine the rate of the following reaction: A scientist conducts an experiment to determine the rate of the following reaction:   If the initial concentration of NO was 0.00 M and the concentration of NO was 0.050 M after 0.100 s, what is the average rate of the reaction? If the initial concentration of NO was 0.00 M and the concentration of NO was 0.050 M after 0.100 s, what is the average rate of the reaction?

(Multiple Choice)
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Given the following data for the reaction A Given the following data for the reaction A   <font face=symbol></font>B, determine the frequency factor, A, of the reaction. k (M/s) T (K) 2)04 <font face=symbol></font> 10<font face=symbol><sup></sup></font><sup>4</sup> 250 6)78 <font face=symbol></font> 10<font face=symbol><sup></sup></font><sup>3</sup> 400 B, determine the frequency factor, A, of the reaction. k (M/s) T (K) 2)04 104 250 6)78 103 400

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NO2 contributes to the "brown haze" associated with photochemical smog events. At what time of day is NO2 concentration highest?

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The energy needed to form an activated complex is called ________

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The mechanism for the reaction The mechanism for the reaction   in the presence of I<font face=symbol><sup></sup></font>(aq) is proposed to be: Step 1:   (slow) Step 2:   (fast) What is the molecularity of the rate-determining step? in the presence of I(aq) is proposed to be: Step 1: The mechanism for the reaction   in the presence of I<font face=symbol><sup></sup></font>(aq) is proposed to be: Step 1:   (slow) Step 2:   (fast) What is the molecularity of the rate-determining step? (slow) Step 2: The mechanism for the reaction   in the presence of I<font face=symbol><sup></sup></font>(aq) is proposed to be: Step 1:   (slow) Step 2:   (fast) What is the molecularity of the rate-determining step? (fast) What is the molecularity of the rate-determining step?

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Indicate which of the following compounds is a component of photochemical smog.

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Given the following data for the reaction A Given the following data for the reaction A   <font face=symbol></font>B, determine the frequency factor, A, of the reaction.  B, determine the frequency factor, A, of the reaction. Given the following data for the reaction A   <font face=symbol></font>B, determine the frequency factor, A, of the reaction.

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The mechanism for the first-order reaction The mechanism for the first-order reaction   in the presence of I<font face=symbol><sup></sup></font>(aq) is proposed to be: Step 1:   (slow) Step 2:   (fast) Identify the catalyst in the reaction. in the presence of I(aq) is proposed to be: Step 1: The mechanism for the first-order reaction   in the presence of I<font face=symbol><sup></sup></font>(aq) is proposed to be: Step 1:   (slow) Step 2:   (fast) Identify the catalyst in the reaction. (slow) Step 2: The mechanism for the first-order reaction   in the presence of I<font face=symbol><sup></sup></font>(aq) is proposed to be: Step 1:   (slow) Step 2:   (fast) Identify the catalyst in the reaction. (fast) Identify the catalyst in the reaction.

(Multiple Choice)
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One reaction that occurs in an automobile catalytic converter is the conversion of nitrogen monoxide to nitrogen and oxygen. How could the rate of this reaction be expressed correctly in terms of the rate at which the concentration of a reactant or product changes? 2NO(g) One reaction that occurs in an automobile catalytic converter is the conversion of nitrogen monoxide to nitrogen and oxygen. How could the rate of this reaction be expressed correctly in terms of the rate at which the concentration of a reactant or product changes? 2NO(g)   <font face=symbol></font>N<sub>2</sub>(g) <font face=symbol></font> O<sub>2</sub>(g) N2(g) O2(g)

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The rate law of a particular reaction was determined to be Rate k[A][B]. What is the unit of the rate constant for the reaction?

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