Exam 22: Transition Metals: Biological and Medical Applications
Exam 1: Matter and Energy: The Origin of the Universe103 Questions
Exam 2: Atoms, Ions, and Molecules: Matter Starts Here144 Questions
Exam 3: Stoichiometry: Mass, Formulas, and Reactions141 Questions
Exam 4: Solution Chemistry: The Hydrosphere148 Questions
Exam 5: Thermochemistry: Energy Changes in Reactions139 Questions
Exam 6: Properties of Gases: The Air We Breathe164 Questions
Exam 7: A Quantum Model of Atoms: Waves and Particles166 Questions
Exam 8: Chemical Bonds: What Makes a Gas a Greenhouse Gas156 Questions
Exam 9: Molecular Geometry: Shape Determines Function188 Questions
Exam 10: Intermolecular Forces: The Uniqueness of Water165 Questions
Exam 11: Solutions: Properties and Behavior150 Questions
Exam 12: Solids: Crystals, Alloys, and Polymers130 Questions
Exam 13: Chemical Kinetics: Reactions in the Atmosphere155 Questions
Exam 14: Chemical Equilibrium: How Much Product Does a Reaction Really Make111 Questions
Exam 15: Acidbase Equilibria: Proton Transfer in Biological Systems122 Questions
Exam 16: Additional Aqueous Equilibria: Chemistry and the Oceans127 Questions
Exam 17: Thermodynamics: Spontaneous and Nonspontaneous Reactions and Processes186 Questions
Exam 18: Electrochemistry: The Quest for Clean Energy167 Questions
Exam 19: Nuclear Chemistry: Applications to Energy and Medicine165 Questions
Exam 20: Organic and Biological Molecules: the Compounds of Life168 Questions
Exam 21: The Main Group Elements: Life and the Periodic Table96 Questions
Exam 22: Transition Metals: Biological and Medical Applications142 Questions
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Which pieces of information are needed to explain why NiCl42 is paramagnetic?
I.It has six d electrons.
II.It has eight d electrons.
III.It is strong field.
IV.It is weak field.
V.It is tetrahedral.
VI.It is square planar.
Free
(Multiple Choice)
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Correct Answer:
B
For the coordination compound [Cr(NH3)3(H2O)3]Cl3, identify, in order, the charge on the complex ion, the oxidation state of the metal, and the coordination number of the metal.
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(Multiple Choice)
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Correct Answer:
E
What is the oxidation state of the gold atom in the AuCl4-complex ion?
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(Multiple Choice)
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Correct Answer:
D
Which d orbitals are indicated by the arrow in the crystal field splitting diagram for a square planar field? 
(Multiple Choice)
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Explain why Ni(CN)42 is diamagnetic and NiCl42 is paramagnetic in terms of the possible geometries (tetrahedral and square planar) and the magnitudes of the crystal field splitting?
(Essay)
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Which statement describing the splitting of metal d orbitals in an octahedral complex ion is not correct?
(Multiple Choice)
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What is the correct formula for pentaammineaquairon(II) nitrate?
(Short Answer)
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Transition metal ions often absorb visible light in promoting electrons from a ground state to an excited state. Why doesn't aluminum(III) ion have this property?
(Multiple Choice)
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As the value of the crystal field splitting, o, increases from one complex ion to another, ________
(Multiple Choice)
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When the five 3d orbitals on a metal ion experience a square planar field in a complex, they split into ________ energy levels.
(Multiple Choice)
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Which statement A-D regarding isomers in transition metal compounds is not correct?
(Multiple Choice)
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A strong crystal field produces a large value for the crystal field splitting, o, while a weak crystal field produces a small crystal field splitting. Which would be more likely to put a metal ion in a high-spin configuration?
(Multiple Choice)
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Draw the d orbital splitting diagram for the octahedral complex ion, Mn(CN)64, and predict the number of unpaired spins in the molecule.
(Essay)
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Which of the following cations would possess, the largest crystal field splitting (o), assuming an identical ligand set for all ions?
(Multiple Choice)
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CoCl42(aq) absorbs light in the orange region of the spectrum. The color of a solution containing this ion is ________
(Multiple Choice)
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