Exam 22: Transition Metals: Biological and Medical Applications

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Paramagnetic substances are attracted to magnetic fields. A set of synthetic mineral crystals was prepared with different metal ions substituted into the identical octahedral site in the lattice. If each crystal contained exactly the same number of the indicated metal ion, which would have the greatest attraction to a magnetic field?

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Metal ions complexed with ________ are found in many important biological compounds.

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How many unpaired spins are there in the tetrahedral complex ion, NiCl42?

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A solution containing the ion CoF63 has an absorption maximum at max 680 nm. The color of this solution is ________

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Molecules that have isomers that are nonsuperimposable mirror images are called ________

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How many chelation sites and donor groups does EDTA have?

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Cobalt is critical for function of which of the following?

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Which of the following square planar complexes would have enantiomers?

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The effects of lead poisoning can sometimes be reversed by addition of a chelating agent to sequester the metal from the body. Which of the following compounds would be most effective to act as such a chelating agent?

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Which of the following is a chelation agent?

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What is the correct formula for sodium tetracyanodihydroxovanadate(II)?

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Which of the following complexes has the largest crystal field splitting of the d orbitals?

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Which statement concerning the crystal field theory of octahedral transition metal complexes is not correct?

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Which pieces of information are needed to explain why Ni(CN)42 is diamagnetic? I.It has six d electrons. II.It has eight d electrons. III.It is tetrahedral. IV.It is square planar. V.It is strong field. VI.It is weak field.

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Cisplatin and other metallodrugs used with cancer are believed to function by ________

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Porphyrins are polydentate ligands found in nature. They support the iron centers in heme proteins, which allows for the transport of oxygen throughout the blood stream. A structure of the core of a porphyrin is shown below. Based on the structure, what type of denticity would the ligand likely possess? Porphyrins are polydentate ligands found in nature. They support the iron centers in heme proteins, which allows for the transport of oxygen throughout the blood stream. A structure of the core of a porphyrin is shown below. Based on the structure, what type of denticity would the ligand likely possess?

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How many unpaired electrons are there in the octahedral complex ion, Mn(CN)64?

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A solution containing an octahedral metal ion has an absorption maximum at max 535 nm. The color of this solution is ________

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Draw and label (cis and trans) the stereoisomers of the square planar complex ion CuCl2Br22.

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In Na2[Zn(CN)4], the counter ion is ________, and in [Co(NH3)4Cl2]NO3, the counter ion is ________.

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