Exam 4: Solution Chemistry: The Hydrosphere

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Identify the oxidizing and reducing agents in the following oxidation-reduction reaction. CH4(g) + 2O2(g) Identify the oxidizing and reducing agents in the following oxidation-reduction reaction. CH<sub>4</sub>(g) + 2O<sub>2</sub>(g)   CO(g)+2H<sub>2</sub>(g) CO(g)+2H2(g)

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Oxidizing agent: O2 Reducing agent: CH4
An oxidizing agent is a chemical species that removes electrons from another species. A reducing agent is a chemical species that gives electrons to another species.

Write the balanced molecular equation and the net ionic equation for the reaction of solid magnesium hydroxide with a solution of sulfuric acid.

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Mg(OH)2(s) Mg(OH)<sub>2</sub>(s)   H<sub>2</sub>SO<sub>4</sub>(aq)   MgSO<sub>4</sub>(aq)   H<sub>2</sub>O(l ) Mg(OH)<sub>2</sub>(s)   2H<sub>3</sub>O<sup>+</sup>(aq)   Mg<sup>2+</sup>(aq)   4H<sub>2</sub>O(l ) or Mg(OH)<sub>2</sub>(s)   2H<sup>+</sup>(aq)   Mg<sup>2+</sup>(aq)   2H<sub>2</sub>O(l ) H2SO4(aq) Mg(OH)<sub>2</sub>(s)   H<sub>2</sub>SO<sub>4</sub>(aq)   MgSO<sub>4</sub>(aq)   H<sub>2</sub>O(l ) Mg(OH)<sub>2</sub>(s)   2H<sub>3</sub>O<sup>+</sup>(aq)   Mg<sup>2+</sup>(aq)   4H<sub>2</sub>O(l ) or Mg(OH)<sub>2</sub>(s)   2H<sup>+</sup>(aq)   Mg<sup>2+</sup>(aq)   2H<sub>2</sub>O(l ) MgSO4(aq) Mg(OH)<sub>2</sub>(s)   H<sub>2</sub>SO<sub>4</sub>(aq)   MgSO<sub>4</sub>(aq)   H<sub>2</sub>O(l ) Mg(OH)<sub>2</sub>(s)   2H<sub>3</sub>O<sup>+</sup>(aq)   Mg<sup>2+</sup>(aq)   4H<sub>2</sub>O(l ) or Mg(OH)<sub>2</sub>(s)   2H<sup>+</sup>(aq)   Mg<sup>2+</sup>(aq)   2H<sub>2</sub>O(l ) H2O(l )
Mg(OH)2(s) Mg(OH)<sub>2</sub>(s)   H<sub>2</sub>SO<sub>4</sub>(aq)   MgSO<sub>4</sub>(aq)   H<sub>2</sub>O(l ) Mg(OH)<sub>2</sub>(s)   2H<sub>3</sub>O<sup>+</sup>(aq)   Mg<sup>2+</sup>(aq)   4H<sub>2</sub>O(l ) or Mg(OH)<sub>2</sub>(s)   2H<sup>+</sup>(aq)   Mg<sup>2+</sup>(aq)   2H<sub>2</sub>O(l ) 2H3O+(aq) Mg(OH)<sub>2</sub>(s)   H<sub>2</sub>SO<sub>4</sub>(aq)   MgSO<sub>4</sub>(aq)   H<sub>2</sub>O(l ) Mg(OH)<sub>2</sub>(s)   2H<sub>3</sub>O<sup>+</sup>(aq)   Mg<sup>2+</sup>(aq)   4H<sub>2</sub>O(l ) or Mg(OH)<sub>2</sub>(s)   2H<sup>+</sup>(aq)   Mg<sup>2+</sup>(aq)   2H<sub>2</sub>O(l ) Mg2+(aq) Mg(OH)<sub>2</sub>(s)   H<sub>2</sub>SO<sub>4</sub>(aq)   MgSO<sub>4</sub>(aq)   H<sub>2</sub>O(l ) Mg(OH)<sub>2</sub>(s)   2H<sub>3</sub>O<sup>+</sup>(aq)   Mg<sup>2+</sup>(aq)   4H<sub>2</sub>O(l ) or Mg(OH)<sub>2</sub>(s)   2H<sup>+</sup>(aq)   Mg<sup>2+</sup>(aq)   2H<sub>2</sub>O(l ) 4H2O(l )
or Mg(OH)2(s) Mg(OH)<sub>2</sub>(s)   H<sub>2</sub>SO<sub>4</sub>(aq)   MgSO<sub>4</sub>(aq)   H<sub>2</sub>O(l ) Mg(OH)<sub>2</sub>(s)   2H<sub>3</sub>O<sup>+</sup>(aq)   Mg<sup>2+</sup>(aq)   4H<sub>2</sub>O(l ) or Mg(OH)<sub>2</sub>(s)   2H<sup>+</sup>(aq)   Mg<sup>2+</sup>(aq)   2H<sub>2</sub>O(l ) 2H+(aq) Mg(OH)<sub>2</sub>(s)   H<sub>2</sub>SO<sub>4</sub>(aq)   MgSO<sub>4</sub>(aq)   H<sub>2</sub>O(l ) Mg(OH)<sub>2</sub>(s)   2H<sub>3</sub>O<sup>+</sup>(aq)   Mg<sup>2+</sup>(aq)   4H<sub>2</sub>O(l ) or Mg(OH)<sub>2</sub>(s)   2H<sup>+</sup>(aq)   Mg<sup>2+</sup>(aq)   2H<sub>2</sub>O(l ) Mg2+(aq) Mg(OH)<sub>2</sub>(s)   H<sub>2</sub>SO<sub>4</sub>(aq)   MgSO<sub>4</sub>(aq)   H<sub>2</sub>O(l ) Mg(OH)<sub>2</sub>(s)   2H<sub>3</sub>O<sup>+</sup>(aq)   Mg<sup>2+</sup>(aq)   4H<sub>2</sub>O(l ) or Mg(OH)<sub>2</sub>(s)   2H<sup>+</sup>(aq)   Mg<sup>2+</sup>(aq)   2H<sub>2</sub>O(l ) 2H2O(l )

Molarity, M, is defined as ________

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D

If 50.0 mL of a 0.10 M solution of sodium chloride is mixed with 50.0 mL of 0.10 M magnesium chloride, what is the molar concentration of chloride in the resulting solution?

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Hartmann's solution is used in intravenous therapy to replace lost body fluid and mineral salts. The total ion concentration in Hartmann's solution is 276 mM. It often is prepared from a more concentrated stock solution. How much stock solution is needed to prepare 500 mL of Hartmann's solution? The total ion concentration in the stock solution is 1.38 M.

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Most alkaline earth salts are soluble. Identify an exception to this generalization.

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In a demonstration of strong electrolytes, weak electrolytes, and nonelectrolytes, Professor Popsnorkle used a lightbulb apparatus that showed how much a solution conducted electricity by the brightness of the lightbulb. When pure water was tested, the bulb did not light. Then Professor Popsnorkle tested the following aqueous solutions. Which one caused the bulb to burn the brightest?

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Which contains more solute particles: a 0.10 M aqueous solution of methanol (CH3OH) or a 0.10 M aqueous solution of salt (NaCl)?

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Draw pictures that represent: (a) a strong electrolyte, (b) a weak electrolyte, and (c) a nonelectrolyte solution. Omit solvent molecules for clarity and use the following formula unit in each diagram as a starting point. Draw pictures that represent: (a) a strong electrolyte, (b) a weak electrolyte, and (c) a nonelectrolyte solution. Omit solvent molecules for clarity and use the following formula unit in each diagram as a starting point.   Strong electrolyte Weak electrolyte Nonelectrolyte Strong electrolyte Weak electrolyte Nonelectrolyte

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Sodium fluoride is added to drinking water in some municipalities to protect teeth against cavities. The idea is to convert hydroxyapatite, Ca10(PO4)6(OH)2, into more stable fluorapatite, Ca10(PO4)6F2. What is the molarity of a 5.0 mg/L sodium fluoride solution?

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In which one of the following compounds is the oxidation number of silicon not equal to +4?

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Why is an aqueous solution of table salt (NaCl) a good conductor of electricity but a solution containing an equal molar concentration of table sugar (C12H22O11) is not?

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Identify the reducing agent in the following reaction. Fe2+(aq) Identify the reducing agent in the following reaction. Fe<sup>2+</sup>(aq)   Ce<sup>4+</sup>(aq)   Fe<sup>3+</sup>(aq)   Ce<sup>3+</sup>(aq) Ce4+(aq) Identify the reducing agent in the following reaction. Fe<sup>2+</sup>(aq)   Ce<sup>4+</sup>(aq)   Fe<sup>3+</sup>(aq)   Ce<sup>3+</sup>(aq) Fe3+(aq) Identify the reducing agent in the following reaction. Fe<sup>2+</sup>(aq)   Ce<sup>4+</sup>(aq)   Fe<sup>3+</sup>(aq)   Ce<sup>3+</sup>(aq) Ce3+(aq)

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If one regular antacid tablet contains 500 mg of solid CaCO3 (100 g/mol), how many mL of 1.0 M stomach acid (HCl) could it neutralize?

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Identify which of the following compounds are soluble in water.

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Write the net ionic equation for the precipitation reaction that occurs between potassium bromide and lead(II) nitrate.

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Which one of the following statements is not correct?

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In the dilution of 10.0 mL of a 0.10 M solution of HCl to a volume of 20.0 mL, what remains unchanged?

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A typical adult body contains about 6.0 L of blood. The hemoglobin content is about 16 g per 100.0 mL of blood. The molar mass of hemoglobin is approximately 64,000 g/mol. (a) What is the molar concentration of hemoglobin in blood, and (b) how many moles of hemoglobin are present in a typical adult?

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Mercury is one of the most toxic metal ions to fish, as they can only tolerate a concentration slightly above 1.5  Mercury is one of the most toxic metal ions to fish, as they can only tolerate a concentration slightly above 1.5     mM. What is the mercury concentration in  \mu g/L?  Mercury is one of the most toxic metal ions to fish, as they can only tolerate a concentration slightly above 1.5     mM. What is the mercury concentration in  \mu g/L? mM. What is the mercury concentration in μ\mu g/L?

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