Exam 8: Carbohydrates

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The structure below shows β\beta -D-gulopyranose.  The structure below shows  \beta -D-gulopyranose.    Which of the structures below represents a Fischer projection of D-gulose?  Which of the structures below represents a Fischer projection of D-gulose?

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This figure is used in questions . This figure is used in questions .   -Which structures shown in the figure above represent possible structures of glucose? -Which structures shown in the figure above represent possible structures of glucose?

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How many stereoisomers are possible for an aldopentose such as ribose?

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Matching -The ______ sugars are monosaccharides in which a hydroxyl group is replaced with a hydrogen atom.

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Starch is a mixture of

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Matching -______ is a heteropolymer composed of D-glucoronate and N-acetyl-D-glucosamine that acts as shock absorber and lubricant.

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This figure is used in questions . This figure is used in questions .   -Which structure shown in the figure above represents deoxyribose? -Which structure shown in the figure above represents deoxyribose?

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Which of the following polysaccharides cannot be digested by mammalian salivary, gastric, or pancreatic enzymes?

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D-Allose is an aldohexose.Methylation of which hydroxyl group on β\beta -D-allopyranose prevents the molecule from mutarotating to α\alpha -D-allopyranose?

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Matching -Bulky ring substituents preferentially occupy ______ positions in the chair conformation.

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The transformation of a monosaccharide into its ______ occurs easily and does not require the assistance of a catalyst.

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This figure is used in questions . This figure is used in questions .   -Which structure(s)shown in the figure above represent reducing sugar(s)? -Which structure(s)shown in the figure above represent reducing sugar(s)?

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This figure is used in questions . This figure is used in questions .   -Which of the carbon atoms shown in the figure above represent the anomeric carbon? -Which of the carbon atoms shown in the figure above represent the anomeric carbon?

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Which statement about N-linked glycosylation is correct?

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The picture below shows a Fischer projection of D-glucose.  The picture below shows a Fischer projection of D-glucose.    a.Is glucose and aldose or a ketose? b.What is the name of the molecule that is formed upon oxidation of the aldehyde to a carboxyl group? c.Draw a Fischer projection of D-galactose, which is an epimer of glucose with respect to the C4 position. d.Draw a Haworth projection of  \beta -D-glucopyranose. e.What is the name of the linear polymer in which glucopyranose residues are linked to each other through  \beta (1→4)glycosidic bonds. a.Is glucose and aldose or a ketose? b.What is the name of the molecule that is formed upon oxidation of the aldehyde to a carboxyl group? c.Draw a Fischer projection of D-galactose, which is an epimer of glucose with respect to the C4 position. d.Draw a Haworth projection of β\beta -D-glucopyranose. e.What is the name of the linear polymer in which glucopyranose residues are linked to each other through β\beta (1→4)glycosidic bonds.

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How many stereoisomers are possible for a ketopentose such as ribulose?

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This figure is used in questions This figure is used in questions   -Which sugar shown in the figure above is the enantiomer of sugar A? -Which sugar shown in the figure above is the enantiomer of sugar A?

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Matching -An example of a homopolysaccharide in liver and muscle is ______.

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This figure is used in questions . This figure is used in questions .   -Which of the structures shown in the figure above is a glucopyranose? -Which of the structures shown in the figure above is a glucopyranose?

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This figure is used in questions . This figure is used in questions .   -The structures shown in the figure above are represented as -The structures shown in the figure above are represented as

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