Exam 14: Chemical Equilibrium

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At a certain temperature,Kc equals 1.4 × 102 for the reaction: 2 CO(g)+ O2(g)⇌ 2 CO2(g). If a 2.50-L flask contains 0.400 mol of CO2 and 0.100 mol of O2 at equilibrium,how many moles of CO are also present in the flask?

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For a homogeneous equilibrium of gases,which of the following changes in reaction conditions will not alter the equilibrium concentrations?

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Shown below is a concentration vs.time plot for the reaction A ⇌ B.For this reaction the value of the equilibrium constant is Shown below is a concentration vs.time plot for the reaction A ⇌ B.For this reaction the value of the equilibrium constant is

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The solubility of 1:1 salts is measured by the equilibrium constant for the general reaction: MX(s)= Mn+(aq)+ Xn-(aq).Given the following salts and their equilibrium constants for the reaction above at 25°C,which salt is the least soluble?

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Given the hypothetical reaction: 2 A(s)+ x B(g)⇌ 3 C(g),Kp = 0.0105 and Kc = 0.45 at 250°C.What is the value of the coefficient x?

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A 1.50 L vessel contains an equilibrium mixture of 0.100 mol of NO,0.150 mol of Br2,and 0.250 mol of NOBr at 25°C.What is the value of Kp for the reaction below? 2 NO(g)+ Br2(g)⇌ 2 NOBr(g)

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Shown below is a concentration vs.time plot for the reaction A ⇌ B.For this reaction the value of the equilibrium constant is Shown below is a concentration vs.time plot for the reaction A ⇌ B.For this reaction the value of the equilibrium constant is

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The reaction CaCO3(s)⇌ CaO(s)+ O2(g)is endothermic 298 K.The effect of adding a catalyst to the system at equilibrium will ________ (decrease,increase,have no effect on)the total quantity of CaCO3 once equilibrium is reestablished.

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"If a stress is applied to a reaction mixture at equilibrium,the reaction occurs in the direction that will relieve the stress." This statement is called

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Picture (1)represents an equilibrium mixture of solid CaCO3,solid CaO,and gaseous CO2,obtained as a result of the endothermic decomposition of CaCO3. Picture (1)represents an equilibrium mixture of solid CaCO<sub>3</sub>,solid CaO,and gaseous CO<sub>2</sub>,obtained as a result of the endothermic decomposition of CaCO<sub>3</sub>.   -Which picture (2)-(4)represents the equilibrium mixture when more solid CaO is added? -Which picture (2)-(4)represents the equilibrium mixture when more solid CaO is added?

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The reaction A2 + B2 ⇌ 2 AB has an equilibrium constant Kc = 1.8.The following pictures represent reaction mixtures that contain A2 molecules (shaded)and B2 molecules (unshaded),and AB molecules.Which reaction mixture is at equilibrium? The reaction A<sub>2</sub> + B<sub>2</sub> ⇌ 2 AB has an equilibrium constant K<sub>c</sub> = 1.8.The following pictures represent reaction mixtures that contain A<sub>2</sub> molecules (shaded)and B<sub>2</sub> molecules (unshaded),and AB molecules.Which reaction mixture is at equilibrium?

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Shown below is a concentration vs.time plot for the reaction A ⇌ 2B.For this reaction the value of the equilibrium constant is Shown below is a concentration vs.time plot for the reaction A ⇌ 2B.For this reaction the value of the equilibrium constant is

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At 25°C,a certain first order reaction has a rate constant equal to 1.00 × 10-3 s-1 and an equilibrium constant,Kc,equal to 4.18.What is the rate constant for the reverse reaction?

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Which of the following will result in an increase in the amount of NH4Cl? NH4Cl (s)⇌ NH3 (g)+ HCl (g)

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Picture (1)represents an equilibrium mixture of solid CaCO3,solid CaO,and gaseous CO2,obtained as a result of the endothermic decomposition of CaCO3. Picture (1)represents an equilibrium mixture of solid CaCO<sub>3</sub>,solid CaO,and gaseous CO<sub>2</sub>,obtained as a result of the endothermic decomposition of CaCO<sub>3</sub>.   -Which picture (2)-(4)represents the equilibrium mixture when more solid CaCO<sub>3</sub> is added? -Which picture (2)-(4)represents the equilibrium mixture when more solid CaCO3 is added?

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Picture (1)represents an equilibrium mixture of solid CaCO3,solid CaO,and gaseous CO2,obtained as a result of the endothermic decomposition of CaCO3. Picture (1)represents an equilibrium mixture of solid CaCO<sub>3</sub>,solid CaO,and gaseous CO<sub>2</sub>,obtained as a result of the endothermic decomposition of CaCO<sub>3</sub>.   -Which picture (2)-(4)represents the equilibrium mixture at a higher temperature? -Which picture (2)-(4)represents the equilibrium mixture at a higher temperature?

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What is the equilibrium equation for the reaction: NH4NO3(s)⇌ N2O(g)+ 2 H2O(g)?

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A crude type of disappearing ink is based on the following endothermic equilibrium: [Co(H2O)6]Cl2 (aq)⇌ [CoCl2(H2O)4] (aq)+ 2 H2O (l) (colorless)(blue) If the reactant solution is used to write on a piece of paper and the paper is allowed to partially dry,what can be done to bring out the colored handwriting?

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Find the equilibrium constant for the reaction: A(g)+ B(g)⇌ 2C(g)at 25°C when k equals 1.4 × 10-12 M-1s-1 for the reaction A(g)+ B(g)→ 2C(g)at 25°C and k equals 2.7 × 10-13 M-1s-1 for the reaction: Find the equilibrium constant for the reaction: A(g)+ B(g)⇌ 2C(g)at 25°C when k equals 1.4 × 10<sup>-12</sup> M<sup>-1</sup>s<sup>-1</sup> for the reaction A(g)+ B(g)→ 2C(g)at 25°C and k equals 2.7 × 10<sup>-13</sup> M<sup>-1</sup>s<sup>-1</sup> for the reaction:

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For the reaction 2 A + B2 ⇌ 2 AB,the rate of the forward reaction is 0.75 M/s and the rate of the reverse reaction is 0.25 M/s.The reaction is not at equilibrium.In order to attain equilibrium the reaction must proceed in the ________ (forward,reverse)direction in order to achieve equilibrium.

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