Exam 14: Chemical Equilibrium

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At an elevated temperature,Kp = 4.2 × 10-9 for the reaction 2 HBr(g)⇌ H2(g)+ Br2(g).If the initial partial pressures of HBr,H2,and Br2 are 1.0 × 10-2 atm,2.0 × 10-4 atm,and 2.0 × 10-4 atm,respectively,what is the equilibrium partial pressure of H2?

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The reaction CaCO3(s)⇌ CaO(s)+ O2(g)is endothermic 298 K.The effect of increasing the total volume of the system at equilibrium will ________ (decrease,increase,have no effect on)the total quantity of CaCO3 once equilibrium is reestablished.

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Given the reaction: 2 HI ⇌ H2 + I2.If Kc' for the reverse reaction is 1.85 × 10-2 at 425°C,what is Kc for the forward reaction at the same temperature?

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The reaction A2 + B2 ⇌ 2AB has an equilibrium constant Kc = 1.8.The following pictures represent reaction mixtures that contain A2 molecules (shaded)and B2 molecules (unshaded),and AB molecules. The reaction A<sub>2</sub> + B<sub>2 </sub>⇌ 2AB has an equilibrium constant K<sub>c</sub> = 1.8.The following pictures represent reaction mixtures that contain A<sub>2</sub> molecules (shaded)and B<sub>2</sub> molecules (unshaded),and AB molecules.   -Which nonequilibrium mixture will react in the forward direction to reach equilibrium? -Which nonequilibrium mixture will react in the forward direction to reach equilibrium?

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For the reaction shown below,which change in conditions made to the system at equilibrium will result in a net reaction to the right to form more product? C(s)+ 2 H2(g)⇌ CH4(g)ΔH° = - 74.8 kJ

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Ammonium carbamate can dissociate into gases at 25°C according to the reaction: NH2COONH4(s)⇌ 2 NH3(g)+ CO2(g) If sufficient ammonium carbamate is sealed in a flask,the total pressure will be 0.117 atm at equilibrium.What is the value of Kp at 25°C?

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Write the equilibrium equation for the reverse reaction: 4 CH4 (g)+ 6 O2 (g)⇌ 4 CO (g)+ 8 H2O (g)

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For the reaction,A(g)+ 2 B(g)⇌ 2 C(g),Kc = 5.00 × 10-10 at 25°C.Which of the following statements is true?

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Given the reaction at a certain temperature: 2 HI(g)⇌ H2(g)+ I2(g).At equilibrium,the partial pressure of HI is 1.8 × 10-3 atm,and the partial pressures for H2 and I2 are 0.10 atm each.Find Kp at that temperature.

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Cyclohexane,C6H12,undergoes a molecular rearrangement in the presence of AlCl3 to form methylcyclopentane,CH3C5H9, according to the equation: C6H12 ⇌ CH3C5H9 If Kc = 0.143 at 25°C for this reaction,find the equilibrium concentrations of C6H12 and CH3C5H9 if the initial concentrations are 0.200 M and 0.200 M,respectively.

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Cyclohexane (C6H12)undergoes a molecular rearrangement in the presence of AlCl3 to form methylcyclopentane (MCP)according to the equation: C6H12 ⇌ MCP If Kc = 0.143 at 25°C for this reaction,predict the direction the reaction will shift if the initial concentrations of C6H12 and MCP are 0.200 M and 0.100 M,respectively.The system

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For the isomerization reaction: butane ⇌ isobutane Kp equals 25 at 500°C.If the initial pressures of butane and isobutane are 10.atm and 0.0 atm,respectively,what are the pressures of the two gases at equilibrium?

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The equilibrium constant is equal to 5.00 at 1300 K for the reaction: 2 SO2(g)+ O2(g)⇌ 2 SO3(g). If initial concentrations are [SO2] = 3.60 M,[O2] = 0.45 M,and [SO3] = 5.40 M,the system is

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What is the equilibrium equation for the following reaction? C2H4 (g)+ 3 O2 (g)⇌ 2 CO2 (g)+ 2 H2O (l)

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Which will alter the composition of an equilibrium mixture?

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The following pictures represent the equilibrium state for four different reactions of the type The following pictures represent the equilibrium state for four different reactions of the type   A atoms are unshaded.X atoms are shaded.   -Which reaction has the smallest equilibrium constant? A atoms are unshaded.X atoms are shaded. The following pictures represent the equilibrium state for four different reactions of the type   A atoms are unshaded.X atoms are shaded.   -Which reaction has the smallest equilibrium constant? -Which reaction has the smallest equilibrium constant?

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Which of the following statements about a catalyst is true?

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What is the equilibrium equation for the dissociation of formic acid in water? HCOOH (aq)+ H2O (l)⇌ H3O+ (aq)+ HCOO- (aq)

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Write the equilibrium equation for the forward reaction: 4 CH4 (g)+ 6 O2 (g)⇌ 4 CO (g)+ 8 H2O (g)

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At a certain temperature,bromine and nitric oxide react to form nitrosyl bromide: Br2(g)+ 2 NO(g)⇌ 2 NOBr(g). When 0.010 mol Br2 is mixed with 0.025 mol NO and 0.015 mol NOBr in a 2.50 L flask,the concentration of NOBr decreases.Which statement below is true?

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