Exam 14: Chemical Equilibrium
Exam 1: Chemical Tools: Experimentation and Measurement154 Questions
Exam 2: Atoms, molecules, and Ions275 Questions
Exam 3: Mass Relationships in Chemical Reactions159 Questions
Exam 4: Reactions in Aqueous Solutions211 Questions
Exam 5: Periodicity and the Electronic Structure of Atoms168 Questions
Exam 6: Ionic Compounds: Periodic Trends and Bonding138 Questions
Exam 7: Covalent Bonding and Electron-Dot Structures92 Questions
Exam 8: Covalent Compounds: Bonding Theories and Molecular Structure205 Questions
Exam 9: Thermochemistry: Chemical Energy170 Questions
Exam 10: Gases: Their Properties and Behavior188 Questions
Exam 11: Liquids, solids, and Phase Changes141 Questions
Exam 12: Solutions and Their Properties198 Questions
Exam 13: Chemical Kinetics190 Questions
Exam 14: Chemical Equilibrium171 Questions
Exam 15: Aqueous Equilibria: Acids and Bases231 Questions
Exam 16: Applications of Aqueous Equilibria201 Questions
Exam 17: Thermodynamics: Entropy, free Energy, and Equilibrium150 Questions
Exam 18: Electrochemistry212 Questions
Exam 19: Nuclear Chemistry176 Questions
Exam 20: Transition Elements and Coordination Chemistry190 Questions
Exam 21: Metals and Solid-State Materials154 Questions
Exam 22: The Main-Group Elements294 Questions
Exam 23: Connections to Organic and Biological Chemistry290 Questions
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At an elevated temperature,Kp = 4.2 × 10-9 for the reaction 2 HBr(g)⇌ H2(g)+ Br2(g).If the initial partial pressures of HBr,H2,and Br2 are 1.0 × 10-2 atm,2.0 × 10-4 atm,and 2.0 × 10-4 atm,respectively,what is the equilibrium partial pressure of H2?
(Short Answer)
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The reaction CaCO3(s)⇌ CaO(s)+ O2(g)is endothermic 298 K.The effect of increasing the total volume of the system at equilibrium will ________ (decrease,increase,have no effect on)the total quantity of CaCO3 once equilibrium is reestablished.
(Short Answer)
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Given the reaction: 2 HI ⇌ H2 + I2.If Kc' for the reverse reaction is 1.85 × 10-2 at 425°C,what is Kc for the forward reaction at the same temperature?
(Multiple Choice)
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The reaction A2 + B2 ⇌ 2AB has an equilibrium constant Kc = 1.8.The following pictures represent reaction mixtures that contain A2 molecules (shaded)and B2 molecules (unshaded),and AB molecules.
-Which nonequilibrium mixture will react in the forward direction to reach equilibrium?
(Multiple Choice)
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For the reaction shown below,which change in conditions made to the system at equilibrium will result in a net reaction to the right to form more product? C(s)+ 2 H2(g)⇌ CH4(g)ΔH° = - 74.8 kJ
(Multiple Choice)
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Ammonium carbamate can dissociate into gases at 25°C according to the reaction: NH2COONH4(s)⇌ 2 NH3(g)+ CO2(g)
If sufficient ammonium carbamate is sealed in a flask,the total pressure will be 0.117 atm at equilibrium.What is the value of Kp at 25°C?
(Multiple Choice)
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Write the equilibrium equation for the reverse reaction: 4 CH4 (g)+ 6 O2 (g)⇌ 4 CO (g)+ 8 H2O (g)
(Multiple Choice)
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For the reaction,A(g)+ 2 B(g)⇌ 2 C(g),Kc = 5.00 × 10-10 at 25°C.Which of the following statements is true?
(Multiple Choice)
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Given the reaction at a certain temperature: 2 HI(g)⇌ H2(g)+ I2(g).At equilibrium,the partial pressure of HI is 1.8 × 10-3 atm,and the partial pressures for H2 and I2 are 0.10 atm each.Find Kp at that temperature.
(Multiple Choice)
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Cyclohexane,C6H12,undergoes a molecular rearrangement in the presence of AlCl3 to form methylcyclopentane,CH3C5H9, according to the equation: C6H12 ⇌ CH3C5H9
If Kc = 0.143 at 25°C for this reaction,find the equilibrium concentrations of C6H12 and CH3C5H9 if the initial concentrations are 0.200 M and 0.200 M,respectively.
(Multiple Choice)
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Cyclohexane (C6H12)undergoes a molecular rearrangement in the presence of AlCl3 to form methylcyclopentane (MCP)according to the equation: C6H12 ⇌ MCP
If Kc = 0.143 at 25°C for this reaction,predict the direction the reaction will shift if the initial concentrations of C6H12 and MCP are 0.200 M and 0.100 M,respectively.The system
(Multiple Choice)
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For the isomerization reaction: butane ⇌ isobutane
Kp equals 25 at 500°C.If the initial pressures of butane and isobutane are 10.atm and 0.0 atm,respectively,what are the pressures of the two gases at equilibrium?
(Multiple Choice)
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The equilibrium constant is equal to 5.00 at 1300 K for the reaction: 2 SO2(g)+ O2(g)⇌ 2 SO3(g).
If initial concentrations are [SO2] = 3.60 M,[O2] = 0.45 M,and [SO3] = 5.40 M,the system is
(Multiple Choice)
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What is the equilibrium equation for the following reaction? C2H4 (g)+ 3 O2 (g)⇌ 2 CO2 (g)+ 2 H2O (l)
(Multiple Choice)
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Which will alter the composition of an equilibrium mixture?
(Multiple Choice)
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The following pictures represent the equilibrium state for four different reactions of the type
A atoms are unshaded.X atoms are shaded.
-Which reaction has the smallest equilibrium constant?
(Multiple Choice)
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Which of the following statements about a catalyst is true?
(Multiple Choice)
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What is the equilibrium equation for the dissociation of formic acid in water? HCOOH (aq)+ H2O (l)⇌ H3O+ (aq)+ HCOO- (aq)
(Multiple Choice)
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Write the equilibrium equation for the forward reaction: 4 CH4 (g)+ 6 O2 (g)⇌ 4 CO (g)+ 8 H2O (g)
(Multiple Choice)
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At a certain temperature,bromine and nitric oxide react to form nitrosyl bromide: Br2(g)+ 2 NO(g)⇌ 2 NOBr(g).
When 0.010 mol Br2 is mixed with 0.025 mol NO and 0.015 mol NOBr in a 2.50 L flask,the concentration of NOBr decreases.Which statement below is true?
(Multiple Choice)
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