Exam 14: Chemical Equilibrium

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At a certain temperature,hydrogen and iodine react to form hydrogen iodide: H2(g)+ I2(g)⇌ 2 HI (g). When initial amounts of H2,I2,and HI are mixed,the concentration of HI increases.Which statement below is true?

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Oxalic acid can donate two protons to water in successive reactions: (1)H2C2O4(aq)+ H2O(l)⇌ H3O+(aq)+ HC2O4-(aq) (2)HC2O4-(aq)+ H2O(l)⇌ H3O+(aq)+ C2O42-(aq) If Kc1 = 5.9 × 10-2 and Kc2 = 6.4 × 10-5 at 25°C,what is the value of Kc for reaction (3)? (3)H2C2O4(aq)+ 2 H2O(l)⇌ 2 H3O+(aq)+ C2O42-(aq)

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Phosphorus pentachloride decomposes to phosphorus trichloride at high temperatures according to the reaction: PCl5(g)⇌ PCl3(g)+ Cl2(g) At 250°C,0.250 M PCl5 is added to a flask.If Kc = 1.80,what are the equilibrium concentrations of each gas?

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Nickel metal can be prepared by the reduction of nickel oxide: NiO(s)+ CO(g)⇌ CO2(g)+ Ni(s) At 936 K,Kp = 4.54 × 103 and at 1125 K,Kp = 1.58 × 103.Which statement is true?

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The overall reaction for photosynthesis can be represented by the following equation: 6 CO2(g)+ 6 H2O(l)⇌ C6H12O6(s)+ 6 O2(g) The enthalpy change for this reaction is 2802 kJ.Which of the following changes in condition will shift the equilibrium to the right?

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Shown below is a concentration vs.time plot for the reaction A ⇌ 2B.For this reaction the value of the equilibrium constant is Shown below is a concentration vs.time plot for the reaction A ⇌ 2B.For this reaction the value of the equilibrium constant is

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The equilibrium constant is equal to 5.00 at 1300 K for the reaction: 2 SO2(g)+ O2(g)⇌ 2 SO3(g). If initial concentrations are [SO2] = 1.20 M,[O2] = 0.45 M,and [SO3] = 1.80 M,the system is

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The following pictures represent mixtures of A2B4 molecules and AB2 molecules,which interconvert according to the equation A2B4 ⇌ 2 AB2.If mixture (1)is at equilibrium,which of the other mixtures are also at equilibrium? The following pictures represent mixtures of A<sub>2</sub>B<sub>4</sub> molecules and AB<sub>2</sub> molecules,which interconvert according to the equation A<sub>2</sub>B<sub>4</sub> ⇌ 2 AB<sub>2</sub>.If mixture (1)is at equilibrium,which of the other mixtures are also at equilibrium?

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Cyclohexane (C6H12)undergoes a molecular rearrangement in the presence of AlCl3 to form methylcyclopentane (CH3C5H9)according to the equation: C6H12 ⇌ CH3C5H9 If Kc = 0.143 at 25°C for this reaction,find the equilibrium concentrations of C6H12 and CH3C5H9 if the initial concentrations are 0.200 M and 0.100 M,respectively.

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At a certain temperature the equilibrium constant,Kc,equals 0.11 for the reaction: 2 ICl(g)⇌ I2(g)+ Cl2(g). What is the equilibrium concentration of ICl if 0.75 mol of I2 and 0.75 mol of Cl2 are initially mixed in a 2.0-L flask?

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The reaction CaCO3(s)⇌ CaO(s)+ O2(g)is endothermic 298 K.The effect of increasing the partial pressure of O2 in the system at equilibrium will ________ (decrease,increase,have no effect on)the total quantity of CaCO3 once equilibrium is reestablished.

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At 1000 K,Kp = 19.9 for the reaction Fe2O3(s)+ 3 CO(g)⇌ 2 Fe(s)+ 3 CO2(g).What is the value of Kp for the reaction 2 Fe2O3(s)+ 6 CO(g)⇌ 4 Fe(s)+ 6 CO2(g)?

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What is the equilibrium equation for the following reaction? 2 H2O (l)⇌ H3O+ (aq)+ OH- (aq)

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Consider the reaction A + B ⇌ 2 AB.The vessel on the right contains an equilibrium mixture of A atoms (shaded spheres),B atoms (unshaded spheres),and AB molecules. Consider the reaction A + B ⇌ 2 AB.The vessel on the right contains an equilibrium mixture of A atoms (shaded spheres),B atoms (unshaded spheres),and AB molecules.   -If the barrier between the two vessels is removed and the contents of the two vessels are allowed to mix,what will be observed? -If the barrier between the two vessels is removed and the contents of the two vessels are allowed to mix,what will be observed?

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Picture (1)represents an equilibrium mixture of solid CaCO3,solid CaO,and gaseous CO2,obtained as a result of the endothermic decomposition of CaCO3. Picture (1)represents an equilibrium mixture of solid CaCO<sub>3</sub>,solid CaO,and gaseous CO<sub>2</sub>,obtained as a result of the endothermic decomposition of CaCO<sub>3</sub>.   -Which picture (2)-(4)represents the equilibrium mixture after addition of four more CO<sub>2</sub> molecules? -Which picture (2)-(4)represents the equilibrium mixture after addition of four more CO2 molecules?

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For the reaction: 4 HCl(g)+ O2(g)⇌ 2 Cl2(g)+ 2 H2O(l),the equilibrium constant is 0.063 at 400 K.If the reaction quotient is 0.100,which of the following statements is not correct?

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If Kc equals 0.110 at 25°C for the reaction: N2O4(g)⇌ 2 NO2(g),what is Kc for the reaction: 6NO2(g)⇌ 3 N2O4(g)?

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For the reaction H2(g)+ S(s)⇌ H2S(g),if the rate constant for the forward reaction is greater than the rate constant for the reverse reaction,the value of Kc must be ________ (equal to,greater than,less than)1.

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For the reaction shown below,which change in conditions made to the system at equilibrium will result in a net reaction to the right to form more product? C(s)+ 2 H2(g)⇌ CH4(g)ΔH° = -74.8 kJ

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Which statement is true for a reaction with Kc equal to 8.90 × 10-12?

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