Exam 14: Chemical Equilibrium

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The following pictures represent the initial state and the equilibrium state for the gaseous state reaction of A2 molecules (shaded spheres)with B atoms (unshaded spheres)to give AB molecules. The following pictures represent the initial state and the equilibrium state for the gaseous state reaction of A<sub>2</sub> molecules (shaded spheres)with B atoms (unshaded spheres)to give AB molecules.   -If the volume of the equilibrium mixture is decreased,what will happen to the number of AB molecules and the number of B atoms? -If the volume of the equilibrium mixture is decreased,what will happen to the number of AB molecules and the number of B atoms?

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At a certain temperature,bromine and nitric oxide react to form nitrosyl bromide: Br2(g)+ 2 NO(g)⇌ 2 NOBr(g). When initial amounts of Br2,NO,and NOBr are mixed,the concentration of NOBr increases.Which statement below is true?

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The equilibrium constant,Kp,equals 3.40 at 25°C for the isomerization reaction: cis-2-butene ⇌ trans-2-butene. If a flask initially contains 1.00 atm of each gas,in what direction will the system shift to reach equilibrium?

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Shown below is a concentration vs.time plot for the reaction A ⇌ 2B.For this reaction the value of the equilibrium constant is Shown below is a concentration vs.time plot for the reaction A ⇌ 2B.For this reaction the value of the equilibrium constant is

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A catalyst increases the rate of a chemical reaction by providing a lower-energy mechanism for the reaction.When this occurs,which one of the following is not affected?

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If Kc is the equilibrium constant for a forward reaction,2 A⇌ B,what is Kc' for the reaction 4 A⇌ 2B?

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Picture (1)represents the equilibrium mixture for the reaction A + B ⇌ 2 AB at 298 K. Picture (1)represents the equilibrium mixture for the reaction A + B ⇌ 2 AB at 298 K.   -If this reaction is exothermic,which picture (2)-(4)represents the equilibrium mixture at 400 K? -If this reaction is exothermic,which picture (2)-(4)represents the equilibrium mixture at 400 K?

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Gaseous hydrogen bromide decomposes at elevated temperatures according to the following equation: Gaseous hydrogen bromide decomposes at elevated temperatures according to the following equation:   . At a certain temperature a 2.00 L flask is initially filled only with 0.600 mol of HBr.What is the value of K<sub>c</sub> at that temperature if the flask contains 0.104 mol of H<sub>2</sub> at equilibrium? . At a certain temperature a 2.00 L flask is initially filled only with 0.600 mol of HBr.What is the value of Kc at that temperature if the flask contains 0.104 mol of H2 at equilibrium?

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The decomposition of ammonia is: 2 NH3(g)⇌ N2(g)+ 3 H2(g).If the partial pressure of ammonia is 1.60 × 10-3 atm and the partial pressures of N2 and H2 are each 0.250 atm at equilibrium,what is the value for Kc at 400°C for the forward reaction?

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What is true about the relationship of Kp and Kc for the reaction: 2 CH4(g)+ 3 O2(g)⇌ 2 CO(g)+ 4 H2O(g)?

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For the reaction A2 + 2 B3 ⇌ 2 AB3,the rate of the forward reaction is 0.25 M/s and the rate of the reverse reaction is 0.75 M/s.The reaction is not at equilibrium.In order to attain equilibrium the reaction must proceed in the ________ (forward,reverse)direction in order to achieve equilibrium.

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Shown below is a concentration vs.time plot for the reaction A ⇌ B.For this reaction the value of the equilibrium constant is Shown below is a concentration vs.time plot for the reaction A ⇌ B.For this reaction the value of the equilibrium constant is

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The oxidation of sulfur dioxide by oxygen to sulfur trioxide has been implicated as an important step in the formation of acid rain: 2 SO2(g)+ O2(g)⇌ 2 SO3(g).If the equilibrium partial pressures of SO2,O2,and SO3 are 0.564 atm,0.102 atm,and 0.333 atm respectively at 1000 K,what is Kp at that temperature?

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For the reaction shown below,N2O4 and NO2 have equilibrium concentrations,[N2O4]eq = 2.160 × 10-4 and [NO2]eq = 1.001 × 10-3,respectively.The equilibrium constant,Kc,for this reaction equals ________. N2O4(g)⇌ 2 NO2(g)

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Salt solubilities can be compared by the concentration of cation formed when the salt dissolves in the general reaction: MaXb(s)⇌ a Mb+(aq)+ b Xa-(aq).Given the following salts and their equilibrium constants for the reaction above at 25°C,which salt is the least soluble?

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At some temperature,a 4.0 L flask is found to contain 10.0 mol of CO2,8.0 mol of C,and 10.0 mol of CO,at equilibrium.What is the value of the equilibrium constant,Kc,for this reaction?

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The equilibrium constant,Kp,equals 3.40 for the isomerization reaction: cis-2-butene ⇌ trans-2-butene. If a flask initially contains 0.250 atm of cis-2-butene and 0.125 atm of trans-2-butene,what is the equilibrium pressure of each gas?

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A reaction reaches dynamic equilibrium at a given temperature when

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The decomposition of nitrosyl bromide is exothermic: 2 NOBr(g)⇌ 2 NO(g)+ Br2(g).Which of the following changes in reaction condition will shift the reaction to the left?

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Picture (1)represents the equilibrium mixture for the gas-phase reaction A + B ⇌ 2 AB at 298 K.If the volume of the equilibrium mixture is decreased,which picture (2)-(4)represents the equilibrium at the reduced volume? Picture (1)represents the equilibrium mixture for the gas-phase reaction A + B ⇌ 2 AB at 298 K.If the volume of the equilibrium mixture is decreased,which picture (2)-(4)represents the equilibrium at the reduced volume?

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