Exam 13: Chemical Kinetics

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The decomposition of dinitrogen pentoxide is described by the chemical equation 2 N2O5(g)→ 4 NO2(g)+ O2(g) If the rate of appearance of O2 is equal to 2.80 mol/min at a particular moment,what is the rate of disappearance of N2O5 at that moment?

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The decomposition of dinitrogen pentoxide is described by the chemical equation 2 N2O5(g)→ 4 NO2(g)+ O2(g) If the rate of appearance of NO2 is equal to 0.560 mol/min at a particular moment,what is the rate of appearance of O2 at that moment?

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A concentration-time study of the gas phase reaction 2 A3 → 3 A2 produced the data in the table below. Time (s)[A3] (M)[A2] (M) 0 4.00 × 10-4 0 10 2.00 × 10-4 3.00 × 10-4 20 1.00 × 10-4 4.50 × 10-4 30 5.00 × 10-5 ? What is the concentration of A2 after 30 seconds?

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For the reaction shown below,if the rate of formation of O2 is 6.5 × 10-6 M/s,the rate of decomposition of N2O5 over the same time interval is ________. 2 N2O5(g)→ 4 NO2(g)+ O2(g)

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The following reaction is second order in A and first order in B: A + B → Products Rate = k[A]2[B] What is the initial rate of this reaction in vessel (b)relative to the initial rate of this reaction in vessel (a)? Each vessel has the same volume.Shaded spheres represent A molecules,and unshaded spheres represent B molecules present at the beginning of the reaction. The following reaction is second order in A and first order in B: A + B → Products Rate = k[A]<sup>2</sup>[B] What is the initial rate of this reaction in vessel (b)relative to the initial rate of this reaction in vessel (a)? Each vessel has the same volume.Shaded spheres represent A molecules,and unshaded spheres represent B molecules present at the beginning of the reaction.

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For a particular first-order reaction,it takes 48 minutes for the concentration of the reactant to decrease to 25% of its initial value.What is the value for rate constant (in s-1)for the reaction?

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Consider the first-order decomposition of A molecules (shaded spheres)in two vessels of equal volume.What is the half-life of decomposition in vessel (b)relative to the half-life of decomposition in vessel (a)? Consider the first-order decomposition of A molecules (shaded spheres)in two vessels of equal volume.What is the half-life of decomposition in vessel (b)relative to the half-life of decomposition in vessel (a)?

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For the zeroth-order reaction: A → products,what will happen to the rate of reaction if the concentration of A is tripled?

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  -What is the activation energy for the destruction of ozone? -What is the activation energy for the destruction of ozone?

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Consider a reaction that occurs by the following one-step mechanism: A2 + B2 → 2 AB The potential energy profile for this reaction is shown below. Consider a reaction that occurs by the following one-step mechanism: A<sub>2</sub> + B<sub>2</sub> → 2 AB The potential energy profile for this reaction is shown below.   -The energy of reaction,ΔE,is given by the difference in energy between which two reaction stages? -The energy of reaction,ΔE,is given by the difference in energy between which two reaction stages?

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Consider the first-order reaction A → B in which A molecules (shaded spheres)are converted to B molecules (unshaded spheres). Consider the first-order reaction A → B in which A molecules (shaded spheres)are converted to B molecules (unshaded spheres).   -Which drawing (a)-(d)represents the reaction mixture at t = 3 minutes? -Which drawing (a)-(d)represents the reaction mixture at t = 3 minutes?

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What is the overall reaction order for the reaction that has the rate law: Rate = k[Cl ]2[N2]?

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The reaction that occurs in a Breathalyzer,a device used to determine the alcohol level in a person's bloodstream,is given below.If the rate of appearance of Cr2(SO4)3 is 1.24 mol/min at a particular moment,what is the rate of disappearance of C2H6O at that moment? 2 K2Cr2O7 + 8 H2SO4 + 3 C2H6O → 2 Cr2(SO4)3 + 2 K2SO4 + 11 H2O

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Chlorine reacts with chloroform according to the reaction given below: Cl2 + CHCl3 → CCl4 + HCl When the initial concentration of Cl2 is doubled the reaction rate increases by a factor of 1.41.What is the order of the reaction with respect to Cl2?

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The following reaction is first order in A and first order in B: A + B → Products Rate = k[A][B] What is the rate constant k of this reaction in vessel (b)relative to the rate constant k of this reaction in vessel (a)? Each vessel has the same volume.Shaded spheres represent A molecules,and unshaded spheres represent B molecules. The following reaction is first order in A and first order in B: A + B → Products Rate = k[A][B] What is the rate constant k of this reaction in vessel (b)relative to the rate constant k of this reaction in vessel (a)? Each vessel has the same volume.Shaded spheres represent A molecules,and unshaded spheres represent B molecules.

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The following pictures represent the progress of a reaction in which two A molecules combine to give a more complex molecule A2,2A → A2. The following pictures represent the progress of a reaction in which two A molecules combine to give a more complex molecule A<sub>2</sub>,2A → A<sub>2</sub>.   -What is the order of reaction with respect to A? -What is the order of reaction with respect to A?

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A mechanism for a naturally occurring reaction that destroys ozone is: Step 1: O3(g)+ HO(g)→ HO2(g)+ O2(g) Step 2: HO2(g)+ O(g)→ HO(g)+ O2(g) Which species is a catalyst?

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  -What is the activation energy for the formation of ozone? -What is the activation energy for the formation of ozone?

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Platinum in the catalytic converter of an automobile catalyzes the conversion of CO to CO2 is an example of a ________ (heterogeneous,homogeneous)catalyst.

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Hydrogen peroxide decomposes to water and oxygen according to the reaction below: 2 H2O2(aq)→ 2 H2O(l)+ O2(g) In the presence of large excesses of I- ion,the following set of data is obtained.What is the average rate of disappearance of H2O2(aq)in M/s in the first 45.0 seconds of the reaction if 1.00 L of H2O2 reacts at 25°C and 1.00 atm pressure? Hydrogen peroxide decomposes to water and oxygen according to the reaction below: 2 H<sub>2</sub>O<sub>2</sub>(aq)→ 2 H<sub>2</sub>O(l)+ O<sub>2</sub>(g) In the presence of large excesses of I<sup>-</sup> ion,the following set of data is obtained.What is the average rate of disappearance of H<sub>2</sub>O<sub>2</sub>(aq)in M/s in the first 45.0 seconds of the reaction if 1.00 L of H<sub>2</sub>O<sub>2</sub> reacts at 25°C and 1.00 atm pressure?

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