Exam 13: Chemical Kinetics

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The isomerization reaction,CH3NC → CH3CN,is first order and the rate constant is equal to 0.46 s-1 at 600 K.What is the concentration of CH3NC after 0.20 minutes if the initial concentration is 0.40 M?

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A reaction has a rate constant,k = 1.2 × 10-12 s-1 at 273 K and k = 5.1 × 10-7 s-1 at 373 K has an activation energy,Ea = ________ kJ/mol.

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Iodide and hypochlorite ion react in aqueous solution according to the reaction below: I- + OCl- → OI- + Cl- If the concentration of OH- in the solution is doubled,the rate of the reaction is halved.What is the order of the reaction with respect to OH-?

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The decomposition of dinitrogen pentoxide is described by the chemical equation 2 N2O5(g)→ 4 NO2(g)+ O2(g) If the rate of appearance of O2 is equal to 2.40 mol/min at a particular moment,what is the rate of disappearance of N2O5 at that moment?

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The reaction below is first order in H2 and second order in NO.What is the rate law for this reaction? 2 H2(g)+ 2 NO(g)→ N2(g)+ 2 H2O(g)

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The reaction for the decomposition of dinitrogen monoxide gas to form an oxygen radical is: The reaction for the decomposition of dinitrogen monoxide gas to form an oxygen radical is:   .If the activation energy is 250 kJ/mol and the frequency factor is 8.0 × 10<sup>11</sup> s<sup>-1</sup>,what is the rate constant for the first-order reaction at 1000 K? .If the activation energy is 250 kJ/mol and the frequency factor is 8.0 × 1011 s-1,what is the rate constant for the first-order reaction at 1000 K?

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The first-order isomerization reaction: cyclopropane → propene,has a rate constant of 1.10 × 10-4 s-1 at 470°C and 5.70 × 10-4 s-1 at 500°C.What is the activation energy,Ea,for the reaction?

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The decomposition of dinitrogen pentoxide is described by the chemical equation 2 N2O5(g)→ 4 NO2(g)+ O2(g) If the rate of disappearance of N2O5 is equal to 1.40 mol/min at a particular moment,what is the rate of appearance of NO2 at that moment?

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Given the following hypothetical reaction: 2 E(g)+ F(g)+ G(g)→ products.If the rate law is: Rate = k[E]2[F]-1,what is the overall order of reaction?

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The reaction below is first order in H2 and one-half order in Br2.The rate law for this reaction is ________. H2(g)+ Br2(g)→ 2 HBr(g)

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A gaseous compound,C,undergoes catalytic decomposition at an initial rate of 0.45 M/s when [C]o = 3.0 × 10-3 M and 0.45 M/s when [C]o = 9.0 × 10-3 M.Therefore,this is a ________ order reaction.

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For the reaction shown below,what is the relationship between the rate of formation of Br2 and the rate of reaction of ClO2- over the same time period? ClO2-(aq)+ 4 Br-(aq)+ 4 H+(aq)→ Cl-(aq)+ 2 Br2(aq)+2 H2O(l)

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Hydrogen iodide decomposes at 800 K via a second-order process to produce hydrogen and iodine according to the following chemical equation. 2HI(g)→ H2(g)+ I2(g) At 800 K it takes 233 seconds for the initial concentration of HI to decrease from 5.75 × 10-2 M to 2.50 × 10-2 M.What is the rate constant for the reaction at this temperature?

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The following reaction is second order in A and first order in B: A + B → Products Rate = k[A]2[B] What is the rate constant k of this reaction in vessel (b)relative to the rate constant k of this reaction in vessel (a)? Each vessel has the same volume.Shaded spheres represent A molecules,and unshaded spheres represent B molecules. The following reaction is second order in A and first order in B: A + B → Products Rate = k[A]<sup>2</sup>[B] What is the rate constant k of this reaction in vessel (b)relative to the rate constant k of this reaction in vessel (a)? Each vessel has the same volume.Shaded spheres represent A molecules,and unshaded spheres represent B molecules.

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The first-order reaction,2 N2O(g)→ 2 N2(g)+ O2(g),has a rate constant equal to 0.76 s-1 at 1000 K.How long will it take for the concentration of N2O to decrease to 6.0% of its initial concentration?

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Shown is a concentration versus time plot for a reaction involving gases A,B,and C. Shown is a concentration versus time plot for a reaction involving gases A,B,and C.   -Which equation best represents the reaction? -Which equation best represents the reaction?

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The reaction below is second order in ClO2 and first order in OH-.If the rate is expressed in M/s,the rate constant,k,has the units ________. 2 ClO2(aq)+ 2 OH-(aq)→ ClO3-(aq)+ ClO2-(aq)+ H2O(l)

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The first-order reaction,SO2Cl2 → SO2 + Cl2,has a half-life of 8.75 hours at 593 K.How long will it take for the concentration of SO2Cl2 to fall to 14.5% of its initial value?

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The following set of data was obtained by the method of initial rates for the reaction: 2 HgCl2(aq)+ C2O42-(aq)→ 2 Cl-(aq)+ 2 CO2(g)+ Hg2Cl2(s) What is the value of the rate constant,k? The following set of data was obtained by the method of initial rates for the reaction: 2 HgCl<sub>2</sub>(aq)+ C<sub>2</sub>O<sub>4</sub><sup>2-</sup>(aq)→ 2 Cl<sup>-</sup>(aq)+ 2 CO<sub>2</sub>(g)+ Hg<sub>2</sub>Cl<sub>2</sub>(s) What is the value of the rate constant,k?

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For the first-order reaction,2 N2O(g)→ 2 N2(g)+ O2(g),what is the concentration of N2O after 3 half-lives if For the first-order reaction,2 N<sub>2</sub>O(g)→ 2 N<sub>2</sub>(g)+ O<sub>2</sub>(g),what is the concentration of N<sub>2</sub>O after 3 half-lives if   mol of N<sub>2</sub>O is initially placed into a 1.00-L reaction vessel? mol of N2O is initially placed into a 1.00-L reaction vessel?

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