Exam 13: Chemical Kinetics

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Methanol can be produced by the following reaction: CO(g)+ 2 H2(g)→ CH3OH(g). How is the rate of disappearance of hydrogen gas related to the rate of appearance of methanol? - Methanol can be produced by the following reaction: CO(g)+ 2 H<sub>2</sub>(g)→ CH<sub>3</sub>OH(g). How is the rate of disappearance of hydrogen gas related to the rate of appearance of methanol? -   = ? = ?

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What factor affects the rate of a chemical reaction?

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The decomposition of ozone in the stratosphere can occur by the following two-step mechanism: Step 1: Br + O3 → BrO + O2 Step 2: BrO + O → Br + O2 Which species is an intermediate in this mechanism?

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A concentration-time study of the gas phase reaction 2 A3 → 3 A2 produced the data in the table below. Time (s)[A3] (M)[A2] (M) 0 4.00 × 10-4 0 10 2.00 × 10-4 3.00 × 10-4 20 1.00 × 10-4 4.50 × 10-4 30 5.00 × 10-5 ? What is the average rate of formation of A2 in the time interval 20-30 seconds?

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For the zeroth-order reaction: C → products,-Δ[C]/Δt = k,which of the following graphs would be expected to give a straight line?

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At 55° the decomposition of N2O5 is first order,having a rate constant,k = 1.7 × 10-3 s-1.If the initial concentration of N2O5 is 6.4 × 10-3 M,the number of half-lives that are required for the N2O5 concentration to fall to 2.0 × 10-4 M is ________,and the amount of time required is ________ minutes.

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A reaction is second order in NO and first order in O2 has a rate constant,k = 1.4 × 104 M-2s-1.What is the initial rate of reaction when the concentrations of NO and O2 are 0.015 M and 0.030 M,respectively?

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A common rule in organic chemistry is that increasing the temperature of a reaction at room temperature by 10°C doubles the rate.Calculate Ea for a reaction that follows this rule.Assume room temperature is 25°C.

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Consider the first-order reaction A → B in which A molecules (shaded spheres)are converted to B molecules (unshaded spheres). Consider the first-order reaction A → B in which A molecules (shaded spheres)are converted to B molecules (unshaded spheres).   -Which drawing (a)-(d)represents the reaction mixture at t = 2 minutes? -Which drawing (a)-(d)represents the reaction mixture at t = 2 minutes?

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Which term describes the measure of the decrease in the concentration of a product per unit time?

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