Exam 14: Chemical Kinetics

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At 25°C the rate constant for the first-order decomposition of a pesticide solution is 6.40 × 10-3 min-1. If the starting concentration of pesticide is 0.0314 M, what concentration will remain after 62.0 min at 25°C?

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Is a bimolecular reaction necessarily second-order? Is a second order reaction necessarily bimolecular? Answer, with explanations and clarifications.

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What is the name given for the study of how fast reactions take place?

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The compound RX3 decomposes according to the equation 3RX3 → R + R2X3 + 3X2 In an experiment the following data were collected for the decomposition at 100°C. What is the average rate of change of RX3 over the entire experiment? The compound RX<sub>3</sub> decomposes according to the equation 3RX<sub>3</sub> → R + R<sub>2</sub>X<sub>3</sub> + 3X<sub>2</sub> In an experiment the following data were collected for the decomposition at 100°C. What is the average rate of change of RX<sub>3</sub> over the entire experiment?

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The rate of a ________-________ is a constant that is independent of reactant concentration.

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A transition state is a species (or state) corresponding to an energy maximum on a reaction energy diagram.

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A ________-________ is a reaction whose rate depends on the concentration of one of the reactants raised to the first power.

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What is the half-life for a zeroth-order reaction?

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A(n) ________ increases the reaction rate without being consumed.

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Consider the reaction 2NH3(g) → N2(g) + 3H2(g) If the rate Δ[H2]/Δt is 0.030 mol L-1 • s-1, what is Δ[NH3]/Δt?

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For a zeroth-order reaction, if the concentration of reactant A is plotted vs. time, which corresponds to the slope of this plot?

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A reaction has the following rate law: rate = k[A][B]2 In experiment 1, the concentrations of A and B are both 0.10 mol • L-1; in experiment 2, the concentrations are both 0.30 mol • L-1. If the temperature stays constant, what is the value of the ratio, rate(2)/rate(1)?

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The following diagram represents the first-order decomposition of A to form X according to the following balanced chemical equation: A → X. Each sphere represents 1.0 mmol of atoms, and the volume of the box is 1.0 L. The following diagram represents the first-order decomposition of A to form X according to the following balanced chemical equation: A → X. Each sphere represents 1.0 mmol of atoms, and the volume of the box is 1.0 L.   What is the half-life of the reaction? What is the half-life of the reaction?

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The rate of a reaction is determined by the rate of the fastest step in the mechanism.

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What rate constant can be determined from only the half-life of a reaction?

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What is the integrated rate law for a first-order reaction?

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Consider the following potential energy profile for the A → B reaction. The overall reaction is ________. Consider the following potential energy profile for the A → B reaction. The overall reaction is ________.

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What is the molecularity of the following elementary reaction? NHCl2(aq) + OH-(aq) → NCl2-(aq) +H2O(l)

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Which is true concerning the following potential energy diagram? Which is true concerning the following potential energy diagram?

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