Exam 17: Acid-Base Equilibria and Solubility Equilibria

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A 10.0-mL sample of 0.75 M CH3CH2COOH is titrated with 0.30 M NaOH. What is the pH of the solution after 22.0 mL of NaOH have been added to the acid? [Ka(CH3CH2COOH) = 1.3 × 10-5]

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A

Which is more soluble in a basic solution than in pure water?

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B

For PbCl2 (Ksp = 2.4 × 10-4), will a precipitate of PbCl2 form when 0.10 L of 3.0 × 10-2M Pb(NO3)2 is added to 400 mL of 9.0 × 10-2M NaCl?

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Which of the following compounds is appreciably more soluble in 1 M HNO3 than in pure water?

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An indicator is a weak acid that is one color in its protonated form and another color in its deprotonated form.

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What is the effect on the equilibrium when sodium formate is added to a solution of formic acid? HCOOH(aq) What is the effect on the equilibrium when sodium formate is added to a solution of formic acid? HCOOH(aq)   H<sup>+</sup>(aq) + HCOO<sup>-</sup>(aq) H+(aq) + HCOO-(aq)

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Which indicator would be the best to use if 0.050 M benzoic acid (Ka = 6.6 × 10-5) is titrated with 0.050 M NaOH?

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The molar solubility of tin(II) iodide is 1.28 × 10-2 mol/L. What is Ksp for this compound?

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The endpoint in a titration is defined as the point when the appropriate indicator changes color.

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Which combination may be used to prepare a buffer having a pH of 8.8? Ka= 7 × 10-3 for H3PO4; 8 × 10-8 for H2PO4-; 5 × 10-13 for HPO42-

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Which of the following is correct?

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Methyl red is a common acid-base indicator. It has a Ka equal to 6.3 × 10-6. Its un-ionized form is red and its anionic form is yellow. What color would a methyl red solution have at pH = 7.8?

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Which pair of substances could form a buffered aqueous solution?

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What is the pH of a buffer that consists of 0.45 M CH3COOH and 0.35 M CH3COONa? [Ka(CH3COOH) = 1.8 × 10-5]

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A wildlife biologist is interested in testing the pH of the water in a lake. He obtains a 200.0-mL sample of the lake water and titrates this sample with a 0.050 M NaOH solution. Neutralization of the lake water requires 40.0 mL of the NaOH solution. Assuming that lake water sample only contains a strong acid, estimate the pH of the lake.

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A(n) ________ is an ion containing a central metal cation bonded to one or more molecules or ions.

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Bromothymol blue is a common acid-base indicator. It has a Ka equal to 1.6 × 10-7. Its un-ionized form is yellow and its conjugate base is blue. What color would a solution have at pH = 5.8?

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A 20.0-mL sample of 0.30 M HClO was titrated with 0.30 M NaOH. The following data were collected during the titration. Determine to Ka for HClO. A 20.0-mL sample of 0.30 M HClO was titrated with 0.30 M NaOH. The following data were collected during the titration. Determine to K<sub>a</sub> for HClO.

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When a strong acid is titrated with a strong base, the pH at the equivalence point

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An acetic acid buffer containing 0.50 M CH3COOH and 0.50 M CH3COONa has a pH of 4.74. What will the pH be after 0.0020 mol of HCl has been added to 100.0 mL of the buffer?

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