Exam 17: Acid-Base Equilibria and Solubility Equilibria

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A wildlife biologist is interested in testing the pH of the water in a lake. He obtains a 200.0-mL sample of the water and titrates this sample with a 0.050 M NaOH solution. Neutralization of the lake water requires 40.0 mL of the NaOH solution. Is the lake acidic, basic, or neutral?

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What is the concentration of Pb2+ ions in a solution prepared by adding 5.00 g of lead(II) iodide to 500. mL of 0.150 M KI? [Ksp(PbI2) =1.4 × 10-8]

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A(n) ________ occurs when a compound containing an ion in common with a dissolved substance is added to a solution at equilibrium resulting in a shift of the equilibrium to the left.

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Which is the best acid to prepare a buffer with the lowest pH?

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Will a precipitate of AgCl form when 0.050 mol NaCl(s) and 0.050 mol AgNO3(s) are dissolved in 500. mL of 3.0 M NH3? (Kf for Ag(NH3)2+ is 1.5 × 107; Ksp(AgCl) = 1.6 × 10-10)

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Explain why it is important that the amount of added strong acid not exceed the original amount of conjugate base present in the buffer.

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The ________ is the point in a titration where the color of the indicator changes.

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Which of the following acids is the best acid to prepare a buffer with the highest pH?

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Suppose 3.0 ×10-3 mol of NaOH are added to 6.0 ×10-3 mol of the weak acid HA. Which is the best representation of the final solution at equilibrium? (Each circle represents 1.0 ×10-3 mol of atoms, and the volume of each box is 1.0 L. Solvent water molecules are omitted for clarity.)

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Will a precipitate (ppt) form when 300.0 mL of 5.0 × 10-5M AgNO3 are added to 200.0 mL of 2.5 × 10-7M NaBr? Answer yes or no, and identify the precipitate if there is one.

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Calculate the solubility of zinc hydroxide, Zn(OH)2, in 1.00 M NaOH. Ksp= 3.0 × 10-16 for Zn(OH)2, Kf = 3.0 × 1015 for Zn(OH)42-.

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At 25°C, the base ionization constant for NH3 is 1.8 × 10-5. Determine the pH of a solution prepared by adding 0.0500 mol of solid ammonium chloride to 100. mL of 0.150 M ammonia.

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For a conjugate acid-base pair, Kw = Ka/Kb

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