Exam 17: Acid-Base Equilibria and Solubility Equilibria

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If the pH of a buffer solution is greater than the pKa value of the buffer acid, the buffer will have more capacity to neutralize added base than added acid.

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Which is more soluble in an acidic solution than in pure water?

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The molar solubility of manganese(II) carbonate is 4.2 × 10-6 M. What is Ksp for this compound?

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A 20.0-mL sample of 0.25 M HNO3 is titrated with 0.15 M NaOH. What is the pH of the solution after 30.0 mL of NaOH have been added to the acid?

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Calculate the NaOH concentration necessary to precipitate Ca(OH)2 from a solution in which [Ca2+] = 1.0. Ksp of Ca(OH)2 = 8 x 10-6.

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Calculate the pH of a buffer solution that contains 0.25 M benzoic acid (C6H5CO2H) and 0.15 M sodium benzoate (C6H5COONa). (Ka = 6.5 × 10-5 for benzoic acid)

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A mixture made of 100 mL of 0.5 M CH3COOH and 100 mL of 0.5 M CH3COONa is classified as a buffer solution.

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What happens to the solution if sodium acetate is added to a solution of acetic acid? CH3COOH(aq) What happens to the solution if sodium acetate is added to a solution of acetic acid? CH<sub>3</sub>COOH(aq)   H<sup>+</sup>(aq) + CH<sub>3</sub>COO<sup>-</sup>(aq) H+(aq) + CH3COO-(aq)

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When sodium acetate is added to a solution of acetic acid, what happens to the pH of the solution? Explain why this effect occurs? CH3COOH(aq) When sodium acetate is added to a solution of acetic acid, what happens to the pH of the solution? Explain why this effect occurs? CH<sub>3</sub>COOH(aq)   H<sup>+</sup>(aq)CH<sub>3</sub>COO<sup>-</sup>(aq) H+(aq)CH3COO-(aq)

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Which results in a buffered solution?

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Calculate the solubility of silver oxalate, Ag2C2O4, in pure water. [Ksp(Ag2C2O4) = 1.0 × 10-11]

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Which is more soluble in an acidic solution than in pure water?

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A 50.0-mL sample of 0.50 M HCl is titrated with 0.50 M NaOH. What is the pH of the solution after 28.0 mL of NaOH have been added to the acid?

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A 25.0-mL sample of 1.00 M NH3 is titrated with 0.15 M HCl. What is the pH of the solution after 15.00 mL of acid have been added to the ammonia solution? [Kb(NH3) = 1.8 × 10-5]

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A 35.0-mL sample of 0.20 M LiOH is titrated with 0.25 M HCl. What is the pH of the solution after 23.0 mL of HCl have been added to the base?

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The ________ is the point in a titration where neutralization is complete.

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What is the pH of a solution prepared by mixing 500.mL of 0.10 M NaOCl and 500. mL of 0.20 M HOCl? [Ka(HOCl) = 3.2 × 10-8]

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What is the [H3O+] in a buffer that consists of 0.30 M HCOOH and 0.20 M HCOONa? [Ka(HCOOH) = 1.7 × 10-4]

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A 25.0-mL sample of 0.10 M C2H5NH2 (ethylamine) is titrated with 0.15 M HCl. What is the pH of the solution after 9.00 mL of acid have been added to the amine? [Kb(C2H5NH2) = 6.5 × 10-4]

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What is the ion product expression for magnesium fluoride, MgF2?

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