Exam 17: Acid-Base Equilibria and Solubility Equilibria

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The amount of strong acid added to a buffer solution cannot exceed the original amount of conjugate base present in order for the buffer to still work.

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Which is more soluble in a basic solution than in pure water?

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pH = pKa + log [conjugate base]/[weak acid] is the ________-________ equation.

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When an acid, HA, is titrated with 0.1 M NaOH, the pH at the half equivalence point of the titration is 4.5. What is the Ka of the acid?

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Calculate the pH at the equivalence point for the titration of 50.0 mL of 0.20 M NH3 with 0.20 M HCl. [Kb(NH3) = 1.8 × 10-5]

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When the concentration of the conjugate base of a weak acid is less than the concentration of the weak acid in a buffer solution, the pH of the solution is

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After 50.0 mL of a 0.100 M solution of NaOH is added to 50.0 mL of a 0.100 M solution of an unknown acid, the equilibrium pH is basic. What may be concluded about the identity of the acid?

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Below is a titration curve for the titration of 50.0 mL of a 0.100 M solution of the weak acid HA with a 0.100 M solution of NaOH. Below is a titration curve for the titration of 50.0 mL of a 0.100 M solution of the weak acid HA with a 0.100 M solution of NaOH.   What is the approximate pK<sub>a</sub> of HA? What is the approximate pKa of HA?

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A buffer is prepared by adding 300.0 mL of 2.0 M NaOH to 500.0 mL of 2.0 M CH3COOH. What is the pH of this buffer? [Ka(CH3COOH) = 1.8 × 10-5]

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A 20.00-mL sample of 0.3000 M HBr is titrated with 0.15 M NaOH. What is the pH of the solution after 40.3 mL of NaOH have been added to the acid?

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Write the ion product expression for calcium phosphate, Ca3(PO4)2.

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Describe how to make a sodium formate (HCOONa)/formic acid (HCOOH) buffer that has a pH of 4.77. Ka = 1.7 × 10-4

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Will a precipitate (ppt) form when 20.0 mL of 1.1 × 10-3 M Ba(NO3)2 are added to 80.0 mL of 8.4 × 10-4M Na2CO3?

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The endpoint is used to estimate the equivalence point.

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The "p" of the pH equation and pKa equation represents ________.

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What is the name used to describe the situation when a compound containing an ion in common with a dissolved substance is added to a solution at equilibrium which shifts the equilibrium?

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Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH. Which diagram best represents the equilibrium composition of the solution at point X on the titration curve below? (Solvent water molecules are omitted for clarity.) Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH. Which diagram best represents the equilibrium composition of the solution at point X on the titration curve below? (Solvent water molecules are omitted for clarity.)

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You have 500.0 mL of a buffer solution containing 0.30 M acetic acid (CH3COOH) and 0.20 M sodium acetate (CH3COONa). What will the pH of this solution be after the addition of 20.0 mL of 1.00 M NaOH solution? [Ka(CH3COOH) = 1.8 × 10-5]

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NaCl is added slowly to a solution that is 0.010 M each in Cu+, Ag+, and Au+. The Ksp for CuCl, AgCl, and AuCl are 1.9 × 10-7, 1.8 × 10-10, and 2.0 × 10-13, respectively. Which compound will precipitate first?

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What name is given to a solution that contains a weak acid and its conjugate base?

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