Exam 15: Chemical Equilibrium

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A quantity of liquid methanol, CH3OH, is introduced into a rigid 3.00-L vessel, the vessel is sealed, and the temperature is raised to 500 K. At this temperature, the methanol vaporizes and decomposes according to the reaction CH3OH(g) A quantity of liquid methanol, CH<sub>3</sub>OH, is introduced into a rigid 3.00-L vessel, the vessel is sealed, and the temperature is raised to 500 K. At this temperature, the methanol vaporizes and decomposes according to the reaction CH<sub>3</sub>OH(g)   CO(g) + 2 H<sub>2</sub>(g), K<sub>c </sub>= 6.90 × 10<sup>-2</sup> If the concentration of H<sub>2</sub> in the equilibrium mixture is 0.426 M, what mass of methanol was initially introduced into the vessel? CO(g) + 2 H2(g), Kc = 6.90 × 10-2 If the concentration of H2 in the equilibrium mixture is 0.426 M, what mass of methanol was initially introduced into the vessel?

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Equilibrium constants are known for the following reactions: S(s) + (3/2)O2(g) Equilibrium constants are known for the following reactions: S(s) + (3/2)O<sub>2</sub>(g)   SO<sub>3</sub>(g) K<sub>c</sub> = 9.2 × 10<sup>23</sup> SO<sub>3</sub>(g)   SO<sub>2</sub>(g) + (1/2)O<sub>2</sub>(g) K<sub>c</sub> = 4.8 × 10<sup>-4</sup> Thus, for the reaction S(s) + O<sub>2</sub>(g)   SO<sub>2</sub>(g), K<sub>c</sub> = 4.4 × 10<sup>20</sup>. SO3(g) Kc = 9.2 × 1023 SO3(g) Equilibrium constants are known for the following reactions: S(s) + (3/2)O<sub>2</sub>(g)   SO<sub>3</sub>(g) K<sub>c</sub> = 9.2 × 10<sup>23</sup> SO<sub>3</sub>(g)   SO<sub>2</sub>(g) + (1/2)O<sub>2</sub>(g) K<sub>c</sub> = 4.8 × 10<sup>-4</sup> Thus, for the reaction S(s) + O<sub>2</sub>(g)   SO<sub>2</sub>(g), K<sub>c</sub> = 4.4 × 10<sup>20</sup>. SO2(g) + (1/2)O2(g) Kc = 4.8 × 10-4 Thus, for the reaction S(s) + O2(g) Equilibrium constants are known for the following reactions: S(s) + (3/2)O<sub>2</sub>(g)   SO<sub>3</sub>(g) K<sub>c</sub> = 9.2 × 10<sup>23</sup> SO<sub>3</sub>(g)   SO<sub>2</sub>(g) + (1/2)O<sub>2</sub>(g) K<sub>c</sub> = 4.8 × 10<sup>-4</sup> Thus, for the reaction S(s) + O<sub>2</sub>(g)   SO<sub>2</sub>(g), K<sub>c</sub> = 4.4 × 10<sup>20</sup>. SO2(g), Kc = 4.4 × 1020.

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The reaction of nitrogen with oxygen to form nitrogen monoxide can be represented by the following equation. N2(g) + O2(g) The reaction of nitrogen with oxygen to form nitrogen monoxide can be represented by the following equation. N<sub>2</sub>(g) + O<sub>2</sub>(g)   2NO(g) At 2000.°C, the equilibrium constant, K<sub>c</sub>, has a value of 4.10 × 10<sup>-4</sup>. What is the value of K<sub>P</sub>? (R = 0.08206 L • atm/K • mol) 2NO(g) At 2000.°C, the equilibrium constant, Kc, has a value of 4.10 × 10-4. What is the value of KP? (R = 0.08206 L • atm/K • mol)

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Ammonium iodide dissociates reversibly to ammonia and hydrogen iodide. NH4I(s) Ammonium iodide dissociates reversibly to ammonia and hydrogen iodide. NH<sub>4</sub>I(s)   NH<sub>3</sub>(g) + HI(g) At 400°C, K<sub>P</sub> = 0.215. Calculate the partial pressure of ammonia at equilibrium when a sufficient quantity of ammonium iodide is heated to 400°C. NH3(g) + HI(g) At 400°C, KP = 0.215. Calculate the partial pressure of ammonia at equilibrium when a sufficient quantity of ammonium iodide is heated to 400°C.

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Consider this reaction at equilibrium: 2H2O2(g) Consider this reaction at equilibrium: 2H<sub>2</sub>O<sub>2</sub>(g)   2H<sub>2</sub>O(g) + O<sub>2</sub>(g), ΔHº<sub>rxn</sub> = -210 kJ/mol If the volume of the system is expanded at constant temperature, what change will occur in the position of the equilibrium? 2H2O(g) + O2(g), ΔHºrxn = -210 kJ/mol If the volume of the system is expanded at constant temperature, what change will occur in the position of the equilibrium?

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Consider the following equilibria: 2SO3(g) Consider the following equilibria: 2SO<sub>3</sub>(g)   2SO<sub>2</sub>(g) + O<sub>2</sub>(g) K<sub>c</sub> = 2.3 × 10<sup>-7</sup> 2NO<sub>3</sub>(g)   2NO<sub>2</sub>(g) + O<sub>2</sub>(g) K<sub>c</sub> = 1.4 × 10<sup>-3</sup> Calculate the equilibrium constant for the reaction SO<sub>2</sub>(g) + NO<sub>3</sub>(g)   SO<sub>3</sub>(g) + NO<sub>2</sub>(g). 2SO2(g) + O2(g) Kc = 2.3 × 10-7 2NO3(g) Consider the following equilibria: 2SO<sub>3</sub>(g)   2SO<sub>2</sub>(g) + O<sub>2</sub>(g) K<sub>c</sub> = 2.3 × 10<sup>-7</sup> 2NO<sub>3</sub>(g)   2NO<sub>2</sub>(g) + O<sub>2</sub>(g) K<sub>c</sub> = 1.4 × 10<sup>-3</sup> Calculate the equilibrium constant for the reaction SO<sub>2</sub>(g) + NO<sub>3</sub>(g)   SO<sub>3</sub>(g) + NO<sub>2</sub>(g). 2NO2(g) + O2(g) Kc = 1.4 × 10-3 Calculate the equilibrium constant for the reaction SO2(g) + NO3(g) Consider the following equilibria: 2SO<sub>3</sub>(g)   2SO<sub>2</sub>(g) + O<sub>2</sub>(g) K<sub>c</sub> = 2.3 × 10<sup>-7</sup> 2NO<sub>3</sub>(g)   2NO<sub>2</sub>(g) + O<sub>2</sub>(g) K<sub>c</sub> = 1.4 × 10<sup>-3</sup> Calculate the equilibrium constant for the reaction SO<sub>2</sub>(g) + NO<sub>3</sub>(g)   SO<sub>3</sub>(g) + NO<sub>2</sub>(g). SO3(g) + NO2(g).

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For the reaction PCl3(g) + Cl2(g) For the reaction PCl<sub>3</sub>(g) + Cl<sub>2</sub>(g)   PCl<sub>5</sub>(g) at a particular temperature, K<sub>c</sub> = 32.4. Suppose a system at that temperature is prepared with [PCl<sub>5</sub>] = 0.50 M, [Cl<sub>2</sub>] = 0.4 M, and [PCl<sub>3</sub>] = 0.10 M. Which of the following is correct? PCl5(g) at a particular temperature, Kc = 32.4. Suppose a system at that temperature is prepared with [PCl5] = 0.50 M, [Cl2] = 0.4 M, and [PCl3] = 0.10 M. Which of the following is correct?

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Sodium carbonate, Na2CO3(s), may be prepared by heating sodium bicarbonate, NaHCO3(s). 2NaHCO3(s) Sodium carbonate, Na<sub>2</sub>CO<sub>3</sub>(s), may be prepared by heating sodium bicarbonate, NaHCO<sub>3</sub>(s). 2NaHCO<sub>3</sub>(s)   Na<sub>2</sub>CO<sub>3</sub>(s) + CO<sub>2</sub>(g) + H<sub>2</sub>O(g) K<sub>P</sub> = 0.23 at 100ºC If a sample of NaHCO<sub>3</sub> is placed in an evacuated flask and allowed to achieve equilibrium at 100ºC, what will the total gas pressure be? Na2CO3(s) + CO2(g) + H2O(g) KP = 0.23 at 100ºC If a sample of NaHCO3 is placed in an evacuated flask and allowed to achieve equilibrium at 100ºC, what will the total gas pressure be?

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What is KP at 298 K for the following reaction? (R = 8.314 J/K • mol) SO2(g) + NO2(g) → SO3(g) + NO(g) What is K<sub>P</sub> at 298 K for the following reaction? (R = 8.314 J/K • mol) SO<sub>2</sub>(g) + NO<sub>2</sub>(g) → SO<sub>3</sub>(g) + NO(g)

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Which is the correct equilibrium constant expression for the following reaction? FeO(s) + H2(g) Which is the correct equilibrium constant expression for the following reaction? FeO(s) + H<sub>2</sub>(g)   Fe(s) + H<sub>2</sub>O(g) Fe(s) + H2O(g)

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For the reaction H2(g) + Br2(g) For the reaction H<sub>2</sub>(g) + Br<sub>2</sub>(g)   2HBr(g), K<sub>c</sub> = 81.4 at 385ºC. If [H<sub>2</sub>] = [Br<sub>2</sub>] = [HBr] = 2.4 × 10<sup>-4</sup><sup>M</sup> at 385ºC, which one of the following is correct? 2HBr(g), Kc = 81.4 at 385ºC. If [H2] = [Br2] = [HBr] = 2.4 × 10-4M at 385ºC, which one of the following is correct?

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What is the name for Qc?

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Consider the reaction: 2A(g) + B(g) → 2C(g) If ΔG° = 50.0 kJ/mol at T = 25°C and PA = PB = 1 atm and PC = 2 atm, what is the value of ΔG? (R = 8.314 J/K • mol)

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The data below refer to the following reaction: 2NO(g) + I2(g) The data below refer to the following reaction: 2NO(g) + I<sub>2</sub>(g)   2NOI(g)   Find the concentration of I<sub>2</sub> when the system reaches equilibrium. 2NOI(g) The data below refer to the following reaction: 2NO(g) + I<sub>2</sub>(g)   2NOI(g)   Find the concentration of I<sub>2</sub> when the system reaches equilibrium. Find the concentration of I2 when the system reaches equilibrium.

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A temperature increase favors an endothermic reaction.

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At 500°C the equilibrium constant, KP , is 4.00 × 10-4 for the equilibrium: 2HCN(g) At 500°C the equilibrium constant, K<sub>P</sub> , is 4.00 × 10<sup>-4</sup> for the equilibrium: 2HCN(g)   H<sub>2</sub>(g) + C<sub>2</sub>N<sub>2</sub>(g) What is K<sub>p</sub> for the following reaction? H<sub>2</sub>(g) + C<sub>2</sub> N<sub>2</sub>(g)   2HCN(g) H2(g) + C2N2(g) What is Kp for the following reaction? H2(g) + C2 N2(g) At 500°C the equilibrium constant, K<sub>P</sub> , is 4.00 × 10<sup>-4</sup> for the equilibrium: 2HCN(g)   H<sub>2</sub>(g) + C<sub>2</sub>N<sub>2</sub>(g) What is K<sub>p</sub> for the following reaction? H<sub>2</sub>(g) + C<sub>2</sub> N<sub>2</sub>(g)   2HCN(g) 2HCN(g)

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Consider the equilibrium: A(s) Consider the equilibrium: A(s)   B(s) + C(g); ΔH°<sub>rxn </sub>> 0 Predict and explain how or whether the following actions would affect this equilibrium. a. adding more solid A b. lowering the temperature c. increasing the pressure on the system by reducing its volume d. adding helium gas to increase the total pressure B(s) + C(g); ΔH°rxn > 0 Predict and explain how or whether the following actions would affect this equilibrium. a. adding more solid A b. lowering the temperature c. increasing the pressure on the system by reducing its volume d. adding helium gas to increase the total pressure

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What is the expression for the partial pressure of "A" for the following reaction under ideal conditions? A(g) What is the expression for the partial pressure of A for the following reaction under ideal conditions? A(g)   B(g) B(g)

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The equilibrium constant for the reaction Ni(s) + 4CO(g) The equilibrium constant for the reaction Ni(s) + 4CO(g)   Ni(CO)<sub>4</sub>(g) is 5.0 × 10<sup>4</sup> at 25ºC. What is the equilibrium constant for the following reaction? Ni(CO)<sub>4</sub>(g)   Ni(s) + 4CO(g)? Ni(CO)4(g) is 5.0 × 104 at 25ºC. What is the equilibrium constant for the following reaction? Ni(CO)4(g) The equilibrium constant for the reaction Ni(s) + 4CO(g)   Ni(CO)<sub>4</sub>(g) is 5.0 × 10<sup>4</sup> at 25ºC. What is the equilibrium constant for the following reaction? Ni(CO)<sub>4</sub>(g)   Ni(s) + 4CO(g)? Ni(s) + 4CO(g)?

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Which is the correct equilibrium constant expression for the following reaction? 2BrCl3(g) Which is the correct equilibrium constant expression for the following reaction? 2BrCl<sub>3</sub>(g)   Br<sub>2</sub>(g) + 3Cl<sub>2</sub>(g) Br2(g) + 3Cl2(g)

(Multiple Choice)
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