Exam 15: Chemical Equilibrium
Exam 1: Chemistry: the Central Science133 Questions
Exam 2: Atoms, Molecules, and Ions124 Questions
Exam 3: Stoichiometry: Ratios of Combination137 Questions
Exam 4: Reactions in Aqueous Solutions146 Questions
Exam 5: Thermochemistry141 Questions
Exam 6: Quantum Theory and the Electronic Structure of Atoms135 Questions
Exam 7: Electron Configuration and the Periodic Table120 Questions
Exam 8: Chemical Bonding I: Basic Concepts102 Questions
Exam 9: Chemical Bonding II: Molecular Geometry and Bonding Theories139 Questions
Exam 10: Gases137 Questions
Exam 11: Intermolecular Forces and the Physical Properties of Liquids and Solids137 Questions
Exam 12: Modern Materials108 Questions
Exam 13: Physical Properties of Solutions151 Questions
Exam 14: Chemical Kinetics132 Questions
Exam 15: Chemical Equilibrium146 Questions
Exam 16: Acids and Bases137 Questions
Exam 17: Acid-Base Equilibria and Solubility Equilibria133 Questions
Exam 18: Entropy, Free Energy, and Equilibrium107 Questions
Exam 19: Electrochemistry122 Questions
Exam 20: Nuclear Chemistry127 Questions
Exam 21: Environmental Chemistry135 Questions
Exam 22: Coordination Chemistry132 Questions
Exam 23: Metallurgy and the Chemistry of Metals152 Questions
Exam 24: Nonmetallic Elements and Their Compounds117 Questions
Exam 25: Organic Chemistry121 Questions
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A quantity of liquid methanol, CH3OH, is introduced into a rigid 3.00-L vessel, the vessel is sealed, and the temperature is raised to 500 K. At this temperature, the methanol vaporizes and decomposes according to the reaction CH3OH(g)
CO(g) + 2 H2(g), Kc = 6.90 × 10-2
If the concentration of H2 in the equilibrium mixture is 0.426 M, what mass of methanol was initially introduced into the vessel?
(Multiple Choice)
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Equilibrium constants are known for the following reactions:
S(s) + (3/2)O2(g)
SO3(g) Kc = 9.2 × 1023
SO3(g)
SO2(g) + (1/2)O2(g) Kc = 4.8 × 10-4
Thus, for the reaction S(s) + O2(g)
SO2(g), Kc = 4.4 × 1020.
(True/False)
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The reaction of nitrogen with oxygen to form nitrogen monoxide can be represented by the following equation. N2(g) + O2(g)
2NO(g)
At 2000.°C, the equilibrium constant, Kc, has a value of 4.10 × 10-4. What is the value of KP? (R = 0.08206 L • atm/K • mol)
(Multiple Choice)
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Ammonium iodide dissociates reversibly to ammonia and hydrogen iodide. NH4I(s)
NH3(g) + HI(g)
At 400°C, KP = 0.215. Calculate the partial pressure of ammonia at equilibrium when a sufficient quantity of ammonium iodide is heated to 400°C.
(Multiple Choice)
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Consider this reaction at equilibrium: 2H2O2(g)
2H2O(g) + O2(g), ΔHºrxn = -210 kJ/mol
If the volume of the system is expanded at constant temperature, what change will occur in the position of the equilibrium?
(Multiple Choice)
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Consider the following equilibria: 2SO3(g)
2SO2(g) + O2(g) Kc = 2.3 × 10-7
2NO3(g)
2NO2(g) + O2(g) Kc = 1.4 × 10-3
Calculate the equilibrium constant for the reaction
SO2(g) + NO3(g)
SO3(g) + NO2(g).
(Multiple Choice)
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For the reaction PCl3(g) + Cl2(g)
PCl5(g) at a particular temperature, Kc = 32.4. Suppose a system at that temperature is prepared with [PCl5] = 0.50 M, [Cl2] = 0.4 M, and [PCl3] = 0.10 M. Which of the following is correct?
(Multiple Choice)
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Sodium carbonate, Na2CO3(s), may be prepared by heating sodium bicarbonate, NaHCO3(s). 2NaHCO3(s)
Na2CO3(s) + CO2(g) + H2O(g) KP = 0.23 at 100ºC
If a sample of NaHCO3 is placed in an evacuated flask and allowed to achieve equilibrium at 100ºC, what will the total gas pressure be?
(Multiple Choice)
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What is KP at 298 K for the following reaction? (R = 8.314 J/K • mol) SO2(g) + NO2(g) → SO3(g) + NO(g) 
(Multiple Choice)
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Which is the correct equilibrium constant expression for the following reaction? FeO(s) + H2(g)
Fe(s) + H2O(g)
(Multiple Choice)
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For the reaction H2(g) + Br2(g)
2HBr(g), Kc = 81.4 at 385ºC. If [H2] = [Br2] = [HBr] = 2.4 × 10-4M at 385ºC, which one of the following is correct?
(Multiple Choice)
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Consider the reaction: 2A(g) + B(g) → 2C(g) If ΔG° = 50.0 kJ/mol at T = 25°C and PA = PB = 1 atm and PC = 2 atm, what is the value of ΔG? (R = 8.314 J/K • mol)
(Multiple Choice)
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The data below refer to the following reaction:
2NO(g) + I2(g)
2NOI(g)
Find the concentration of I2 when the system reaches equilibrium.
(Short Answer)
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At 500°C the equilibrium constant, KP , is 4.00 × 10-4 for the equilibrium: 2HCN(g)
H2(g) + C2N2(g)
What is Kp for the following reaction?
H2(g) + C2 N2(g)
2HCN(g)
(Multiple Choice)
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Consider the equilibrium:
A(s)
B(s) + C(g); ΔH°rxn > 0
Predict and explain how or whether the following actions would affect this equilibrium.
a. adding more solid A
b. lowering the temperature
c. increasing the pressure on the system by reducing its volume
d. adding helium gas to increase the total pressure
(Essay)
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What is the expression for the partial pressure of "A" for the following reaction under ideal conditions? A(g)
B(g)
(Multiple Choice)
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The equilibrium constant for the reaction Ni(s) + 4CO(g)
Ni(CO)4(g) is 5.0 × 104 at 25ºC. What is the equilibrium constant for the following reaction?
Ni(CO)4(g)
Ni(s) + 4CO(g)?
(Multiple Choice)
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Which is the correct equilibrium constant expression for the following reaction? 2BrCl3(g)
Br2(g) + 3Cl2(g)
(Multiple Choice)
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