Exam 14: Chemical Equilibrium: How Much Product Does a Reaction Really Make

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A chemical equilibrium 2 A A chemical equilibrium 2<sub> </sub>A   B Has a forward rate constant, k<sub>f </sub><font face=symbol></font> 10 M <font face=symbol><sup></sup></font><sup>1 </sup>s<font face=symbol><sup></sup></font><sup>1</sup>, and a reverse rate constant, k<sub>r</sub> <font face=symbol></font> 5 s<font face=symbol><sup></sup></font><sup>1</sup>. If the system has a concentration of [A] <font face=symbol></font> 0.10 M at equilibrium, what must be the concentration of B at equilibrium? B Has a forward rate constant, kf 10 M 1 s1, and a reverse rate constant, kr 5 s1. If the system has a concentration of [A] 0.10 M at equilibrium, what must be the concentration of B at equilibrium?

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A chemical equilibrium 2 A A chemical equilibrium 2<sub> </sub>A   B Has a forward rate constant, k<sub>f</sub> <font face=symbol></font> 10 M <font face=symbol><sup></sup></font><sup>1</sup>s<font face=symbol><sup></sup></font><sup>1</sup>, and a reverse rate constant, k<sub>r</sub> <font face=symbol></font> 5.0 s<font face=symbol><sup></sup></font><sup>1</sup>. What is the value of the equilibrium constant for this system? B Has a forward rate constant, kf 10 M 1s1, and a reverse rate constant, kr 5.0 s1. What is the value of the equilibrium constant for this system?

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For the following reaction, Kc = 0.500 at 300K. What is the value of Kp? 2A(g) B(g) For the following reaction, K<sub>c</sub> = 0.500 at 300K. What is the value of K<sub>p</sub>? 2A(g) <font face=symbol></font>B(g)   2C(g) <font face=symbol></font> D(g) 2C(g) D(g)

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In the following reaction, calculate Q, given the concentrations of each species, and predict what must occur (if anything) for the reaction to achieve equilibrium. N2(g) 3H2(g) In the following reaction, calculate Q, given the concentrations of each species, and predict what must occur (if anything) for the reaction to achieve equilibrium. N<sub>2</sub>(g) <font face=symbol></font> 3H<sub>2</sub>(g)   2NH<sub>3</sub>(g) K <font face=symbol></font> 9.60 [N<sub>2</sub>] <font face=symbol></font> [H<sub>2</sub>] <font face=symbol></font> 0.100 M and [NH<sub>3</sub>] <font face=symbol></font> 0.352 M 2NH3(g) K 9.60 [N2] [H2] 0.100 M and [NH3] 0.352 M

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For a chemical reaction at equilibrium, which of the following will change the value of the equilibrium constant K? I.changing the temperature II.changing the total concentration of reactants and products III.changing the reaction coefficients

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Addition of products to a chemical reaction in solution or gas phase at equilibrium results in ________

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Sulfur dioxide, gaseous water, and oxygen gas react to prepare sulfuric acid in the following unbalanced equation. Sulfur dioxide, gaseous water, and oxygen gas react to prepare sulfuric acid in the following unbalanced equation.       Under equilibrium conditions, the partial pressures of the components are P<sub>SO2</sub> <font face=symbol></font> 0.1 atm, P<sub>H2O</sub> <font face=symbol></font> 0.05 atm, P<sub>O2</sub> <font face=symbol></font> 0.25 atm, P<sub>H2SO4</sub> <font face=symbol></font> 2.75 atm. What is the value of the equilibrium constant, K<sub>p</sub>, for the reaction? Sulfur dioxide, gaseous water, and oxygen gas react to prepare sulfuric acid in the following unbalanced equation.       Under equilibrium conditions, the partial pressures of the components are P<sub>SO2</sub> <font face=symbol></font> 0.1 atm, P<sub>H2O</sub> <font face=symbol></font> 0.05 atm, P<sub>O2</sub> <font face=symbol></font> 0.25 atm, P<sub>H2SO4</sub> <font face=symbol></font> 2.75 atm. What is the value of the equilibrium constant, K<sub>p</sub>, for the reaction? Sulfur dioxide, gaseous water, and oxygen gas react to prepare sulfuric acid in the following unbalanced equation.       Under equilibrium conditions, the partial pressures of the components are P<sub>SO2</sub> <font face=symbol></font> 0.1 atm, P<sub>H2O</sub> <font face=symbol></font> 0.05 atm, P<sub>O2</sub> <font face=symbol></font> 0.25 atm, P<sub>H2SO4</sub> <font face=symbol></font> 2.75 atm. What is the value of the equilibrium constant, K<sub>p</sub>, for the reaction? Under equilibrium conditions, the partial pressures of the components are PSO2 0.1 atm, PH2O 0.05 atm, PO2 0.25 atm, PH2SO4 2.75 atm. What is the value of the equilibrium constant, Kp, for the reaction?

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Two students measured an equilibrium constant for the same chemical reaction. Ken obtained a value of 130 for the equilibrium constant, but Barbie obtained a value of 11.4. The instructor checked their results and said they were both correct. How can that be?

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Which of A-D is equal in an equilibrium?

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In a simple equilibrium A B In a simple equilibrium A <font face=symbol></font> B   C, will there be any stress to the system if both B and C are added to the equilibrium system simultaneously and in the same amount? C, will there be any stress to the system if both B and C are added to the equilibrium system simultaneously and in the same amount?

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In the Reaction, Initial, Change, Equilibrium (RICE) table started for calculating equilibrium concentrations of the reaction shown, the terms in the "change" row are ________ In the Reaction, Initial, Change, Equilibrium (RICE) table started for calculating equilibrium concentrations of the reaction shown, the terms in the change row are ________

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For an equilibrium reaction with K 1.2 108, the forward rate constant was found to be 3.5 105. What is the value of the reverse rate constant?

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Students often write expressions for the equilibrium constant Kc and reaction quotient Qc in exactly the same way. To avoid confusion, you must remember that Kc uses concentrations under ________ conditions, while Qc uses concentrations under ________ conditions.

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The law of mass action is a result of ________

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Which of the following occurs when products are removed from a chemical reaction in solution or the gas phase at equilibrium?

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For an equilibrium reaction with K 4.3 103, the reverse rate constant was found to be 2.1 102. What is the value of the forward rate constant?

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The reaction of nitrogen gas with oxygen gas, shown here, has a Kp value of 0.25. If a closed vessel was charged with the two reactants, each at an initial partial pressure of 0.250 atm, what would be the equilibrium partial pressure of NO(g)? N2(g) O2(g) The reaction of nitrogen gas with oxygen gas, shown here, has a K<sub>p</sub> value of 0.25. If a closed vessel was charged with the two reactants, each at an initial partial pressure of 0.250 atm, what would be the equilibrium partial pressure of NO(g)? N<sub>2</sub>(g) <font face=symbol></font> O<sub>2</sub>(g)   2NO(g) 2NO(g)

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Which of the following is true for a chemical reaction at equilibrium regarding the concentration of products?

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Which statement about a chemical reaction is not correct?

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Cylinders of NO gas may contain small quantities of oxygen as an impurity, leading to the formation of NO2 in equilibrium with the NO and the oxygen. Is this contamination by NO2 dependent on the pressure in the tank?

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