Exam 14: Chemical Equilibrium: How Much Product Does a Reaction Really Make
Exam 1: Matter and Energy: The Origin of the Universe103 Questions
Exam 2: Atoms, Ions, and Molecules: Matter Starts Here144 Questions
Exam 3: Stoichiometry: Mass, Formulas, and Reactions141 Questions
Exam 4: Solution Chemistry: The Hydrosphere148 Questions
Exam 5: Thermochemistry: Energy Changes in Reactions139 Questions
Exam 6: Properties of Gases: The Air We Breathe164 Questions
Exam 7: A Quantum Model of Atoms: Waves and Particles166 Questions
Exam 8: Chemical Bonds: What Makes a Gas a Greenhouse Gas156 Questions
Exam 9: Molecular Geometry: Shape Determines Function188 Questions
Exam 10: Intermolecular Forces: The Uniqueness of Water165 Questions
Exam 11: Solutions: Properties and Behavior150 Questions
Exam 12: Solids: Crystals, Alloys, and Polymers130 Questions
Exam 13: Chemical Kinetics: Reactions in the Atmosphere155 Questions
Exam 14: Chemical Equilibrium: How Much Product Does a Reaction Really Make111 Questions
Exam 15: Acidbase Equilibria: Proton Transfer in Biological Systems122 Questions
Exam 16: Additional Aqueous Equilibria: Chemistry and the Oceans127 Questions
Exam 17: Thermodynamics: Spontaneous and Nonspontaneous Reactions and Processes186 Questions
Exam 18: Electrochemistry: The Quest for Clean Energy167 Questions
Exam 19: Nuclear Chemistry: Applications to Energy and Medicine165 Questions
Exam 20: Organic and Biological Molecules: the Compounds of Life168 Questions
Exam 21: The Main Group Elements: Life and the Periodic Table96 Questions
Exam 22: Transition Metals: Biological and Medical Applications142 Questions
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An increase in the number of moles of gas as the reaction goes from reactants to products in a gas-phase equilibrium results in ________
(Multiple Choice)
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A reaction is run under conditions in which the equilibrium constant is known to be 2.5. 102. At equilibrium, the forward rate is determined to be 5.0 104 mol L1 s1. What is the rate of the reverse reaction under these conditions?
(Short Answer)
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The equilibrium constant for the formation of calcium carbonate from the ions in solution is 2.2 108 according to the reaction:
What is the value of the equilibrium constant for the reverse of this reaction?
(Multiple Choice)
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The reaction of bromine gas with chlorine gas, shown here, has a Kp value of 7.20. If a closed vessel was charged with the two reactants, each at an initial partial pressure of 0.500 atm, and the product also at 0.500 atm, what would be the equilibrium partial pressure of BrCl(g)? Br2(g) Cl2(g)
2BrCl(g)
(Multiple Choice)
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Hydrofluoric acid is used in the preparation of numerous pharmaceuticals (e.g., Prozac) and industrial materials (e.g., Teflon). It can be produced by the reaction of hydrogen and fluorine gases. Starting with initial concentrations of 2.00 M for H2 and 2.00 M for F2, what would be the equilibrium concentration of HF? The equilibrium constant for the reaction Kc 115.
(Multiple Choice)
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Water can decompose at an elevated temperature to give hydrogen and oxygen according to the equation below. At a particular temperature in a vessel containing water vapor and air, the partial pressures of H2O, H2, and O2 are 0.055 atm, 0.0065 atm, and 0.19 atm, respectively. What is the value of the reaction quotient, QP, for this reaction under these conditions? 2H2O(g)
2H2(g) O2(g)
(Multiple Choice)
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The sulfide ion, S2, reacts with water as a weak base:
S2 H2O
SH OH K 1.0
If sodium sulfide were dissolved in water to make a solution of 0.50 M, what would be the resulting concentration of OH?
(Short Answer)
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Which of the following occurs when reactants are added to a chemical reaction in solution or the gas phase at equilibrium?
(Multiple Choice)
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If the temperature of an endothermic reaction at equilibrium could be increased instantaneously, what would be the instantaneous effect on Q and K before equilibrium was again achieved?
(Multiple Choice)
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Using the Reaction, Initial, Change, Equilibrium (RICE) table started for calculating equilibrium concentrations of the reaction shown, what is the expression for the equilibrium constant in terms of x? 2NOCl(g)
2NO(g) Cl2(g)
R [NOCl] [NO] [Cl2]
I 0.20 M 0 M 0 M
C
E
(Multiple Choice)
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The gas-phase equilibrium of the oxidation of sulfur dioxide, shown here, has an equilibrium constant, Kp, value of 4.17 102 at 200C. If a closed vessel was filled with sulfur trioxide and the initial pressure of SO3 was 0.033 atm at 200C, what would be the final partial pressure of SO3? 2SO2(g) O2(g)
2SO3(g)
(Multiple Choice)
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The reaction of bromine gas with chlorine gas, shown below, has a Kp value of 0.127. If a closed vessel was charged with the reactant at an initial partial pressure of 0.500 atm, what would be the equilibrium partial pressure of Br2(g)? 2BrCl(g)
Br2(g) Cl2(g)
(Multiple Choice)
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Sulfur dioxide emitted in the burning of coal is "scrubbed" from the effluent using ________
(Multiple Choice)
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In equilibrium expressions, the concentrations of pure solids and liquids ________
(Multiple Choice)
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If the reaction quotient Q is equal to the related equilibrium constant, K, ________
(Multiple Choice)
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For the reaction of hydrogen and nitrogen gases at 30°C to form two moles of ammonia gas (NH3), the value of KP is 4.5 1012. What is the equilibrium expression for Kc for the production of two moles of ammonia in terms of KP and variables from the ideal gas law?
(Short Answer)
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Gaseous hydrogen and iodine can be used to prepare HI in the following balanced chemical reaction. Calculate a value for the reaction quotient when [H2] [I2] 4.67 10-3 M and [HI] 4.07 10-2 M. H2(g) I2(g)
2HI(g)
(Multiple Choice)
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How would an increase in temperature affect the following equilibrium? H2O(l )
H2(g)
O2(g)
H 482.0 kJ/mol
(Multiple Choice)
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Equilibrium constants for gases can be expressed in terms of concentrations, Kc, or in terms of partial pressures, Kp. Which one of the following statements regarding Kc and Kp is correct?
(Multiple Choice)
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