Exam 18: Electrochemistry

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Consider the following cell: Pt(s)∣ H2(g,p1)∣ H+(aq,pHA)∣∣ H+(aq,pHC)∣ H2(g,p2)∣ Pt(s) Where pHA is the pH of the aqueous solution in the anode half-cell and pHC is the pH of the aqueous solution in the cathode half-cell.If the partial pressure of H2(g)is the same for both half-cells, (p1 = p2),then E for the cell at 25°C is

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A galvanic cell uses the reaction Mg(s)+ Pb2+(aq)→ Mg2+(aq)+ Pb(s). Mg(s)→ Mg2+(aq)+ 2 e- is the ________ half-reaction,which occurs at the ________.

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Electrolysis of a metal nitrate solution M(NO3)2(aq)for 3.00 hours with a constant current of 20.0 A gives 119 g of the metal M.The identity of the metal M in the metal ion M2+ is ________.

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For the hypothetical reaction A + 2 Bx → Ay + 2 B,E° = 1.50 V = and ΔG° = -305 kJ.For this reaction,if the value of x is 4,then the value of y = .

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What is the shorthand notation for this cell?

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A galvanic cell consists of a La3+/La half-cell and a standard hydrogen electrode.If the La3+/La half-cell standard cell functions as the anode,and the standard cell potential is 2.52 V,what is the standard reduction potential for the La3+/La half-cell?

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What is the shorthand notation that represents the following galvanic cell reaction? 2 Fe2+(aq)+ Cl2(g)→ 2 Fe3+(aq)+ 2 Cl-(aq)

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What is true when the following equation is balanced in basic solution? P(s)+ PO43-(aq)→ HPO32-(aq)

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Based on the balanced chemical equation shown below,determine the mass percent of Fe3+ in a 0.6450 gram sample of iron ore,if 22.40 mL of a 0.1000 M stannous chloride,SnCl2(aq),solution is required to completely react with the Fe3+ present in the ore sample.The chemical equation for the reaction is: 2 Fe3+(aq)+ Sn2+(aq)→ 2 Fe2+(aq)+ Sn4+(aq).

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What is the relation between joules (J),volts (V),and coulombs (C)?

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What is the balanced equation for the galvanic cell reaction expressed using shorthand notation below? Cu(s)∣ Cu2+(aq)∣∣ Cl2(g)∣ Cl-(aq)∣ C(s)

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If the concentrations of Ag+(aq)and Cu2+(aq)are varied in this galvanic cell,which of the following four cells has the largest cell potential?

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Consider the galvanic cell shown below. Consider the galvanic cell shown below.   -What is the balanced equation for the cell reaction? -What is the balanced equation for the cell reaction?

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In the relationship ΔG = -nFE°,what is the value of n for the reaction shown below? 3 Fe2+(aq)+ 2 Al(s)→ 3 Fe(s)+ 2 Al3+(aq)

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Calculate the cell potential at 25°C for the cell Fe(s)∣ (Fe2+(0.100 M)∣∣ Pd2+(1.0 × 10-5 M)∣ Pd(s) Given that the standard reduction potential for Fe2+/Fe is -0.45 V and for Pd2+/Pd is +0.95 V.

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In a galvanic cell constructed from Pb(s)| Pb+2(aq)|| Hg+1 | Hg(s),which of the electrodes will gain mass?

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What is the balanced chemical equation for the galvanic cell reaction expressed using shorthand notation below? Al(s)∣ Al3+(aq)∣∣ Ni2+(aq)∣ Ni(s)

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  -For the galvanic cell shown above,in what direction should the anions and cations in half-cell A move? -For the galvanic cell shown above,in what direction should the anions and cations in half-cell A move?

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Shown below are the reactions occurring in the proton-exchange membrane (PEM)fuel cell. I.2 H2(g)→ 4 H+(aq)+ 4 e- II.O2(g)+ 4 H+(aq)+ 4 e- → 2 H2O(l) Overall 2 H2(g)+ O2(g)→ 2 H2O(l) Which is the cathode reaction,and what is being oxidized in the overall reaction?

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A particular 12V battery is based on a reaction having a standard cell potential,E° = +1.92 V.What happens when the battery "dies"?

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