Exam 18: Electrochemistry

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Based on the balanced chemical equation shown below,determine the mass percent of Fe3+ in a Based on the balanced chemical equation shown below,determine the mass percent of Fe<sup>3+</sup> in a   sample of iron ore,if 22.40 mL of a 0.1000 M stannous chloride,SnCl<sub>2</sub>(aq),solution is required to completely react with the<sub> </sub>Fe<sup>3+</sup> present in the ore sample.The chemical equation for the reaction is: 2 Fe<sup>3+</sup>(aq)+ Sn<sup>2+</sup>(aq)→ 2 Fe<sup>2+</sup>(aq)+ Sn<sup>4+</sup>(aq). sample of iron ore,if 22.40 mL of a 0.1000 M stannous chloride,SnCl2(aq),solution is required to completely react with the Fe3+ present in the ore sample.The chemical equation for the reaction is: 2 Fe3+(aq)+ Sn2+(aq)→ 2 Fe2+(aq)+ Sn4+(aq).

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A galvanic cell consists of one half-cell that contains Ag(s)and Ag+(aq),and one half-cell that contains Pb(s)and Pb2+(aq).What species are produced at the electrodes under standard conditions? Ag+(aq)+ e- → Ag(s)E° = +0.80 V Pb2+(aq)+ 2 e- → Pb(s)E° = -0.13 V

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In the shorthand notation for a galvanic cell,a double vertical line (∣∣)represents

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  -The cell reaction 2 Fe<sup>3+</sup>(aq)+ Zn(s)→ Zn<sup>2+</sup>(aq)+ 2 Fe<sup>2+</sup>(aq)occurs in the galvanic cell shown above.Where should the Fe<sup>3+</sup>(aq)and Fe<sup>2+</sup>(aq)be found? -The cell reaction 2 Fe3+(aq)+ Zn(s)→ Zn2+(aq)+ 2 Fe2+(aq)occurs in the galvanic cell shown above.Where should the Fe3+(aq)and Fe2+(aq)be found?

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What is the shorthand notation that represents the following galvanic cell reaction? Fe(s)+ Cu(NO3)2(aq)→ Fe(NO3)2(aq)+ Cu(s)

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Given Given     and   calculate E at 25°C for a cell based on the reaction:  Given     and   calculate E at 25°C for a cell based on the reaction:  and Given     and   calculate E at 25°C for a cell based on the reaction:  calculate E at 25°C for a cell based on the reaction: Given     and   calculate E at 25°C for a cell based on the reaction:

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Identify the anode and cathode half-reactions and categorize each as either oxidation or reduction.

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According to the balanced equation shown below,1.00 mole of oxalic acid,H2C2O4,reacts with ________ moles of permanganate ion,MnO4-. 5 H2C2O4(aq)+ 2 MnO4-(aq)+ 6 H+(aq)→ 10 CO2(g)+ 2 Mn2+(aq)+ 8 H2O(l)

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The standard cell potential for the following galvanic cell is 0.71 V. Pb(s)|Pb2+(aq)||Al3+(aq)|Al This reaction has an equilibrium constant,K = ________.

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For the reaction 2 Al(s)+ 3 Co2+(aq)→ 2 Al3+(aq)+ 3 Co(s),ΔG° is -799 kJ.What is E° for a standard cell based on this reaction?

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How many grams of nickel metal are plated out when a constant current of 15.0 A is passed through aqueous NiCl2 for 80.0 minutes?

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Based on the balanced chemical equation shown below,what volume of 0.250 M K2S2O3(aq),is needed to completely react with 12.44 mL of 0.125 M KI3(aq)? 2 S2O32-(aq)+ I3-(aq)→ S4O62-(aq)+ 3 I-(aq)

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Given that Br2(g)+ 2 e- → 2 Br-(aq)is the reduction half-reaction for the overall reaction Given that Br<sub>2</sub>(g)+ 2 e<sup>-</sup> → 2 Br<sup>-</sup>(aq)is the reduction half-reaction for the overall reaction   what is the oxidation half reaction? what is the oxidation half reaction?

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Doubling all the coefficients in the equation for the cell reaction

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For a particular cell based on the reaction: 3 AgCl(s)+ Al(s)→ 3 Ag(s)+ Al3+(aq)+ 3 Cl-(aq) E = +1.750 V and E° = +1.884 V at 25°C. What is the value of the equilibrium constant,K,at 25°C for the reaction?

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Shown below are the reactions occurring in the direct methanol fuel cell (DMFC). I.2 CH3OH(aq)+ 2 H2O(l)→ 2 CO2(g)+12 H+(aq)+12 e- II.3 O2(g)+ 12 H+(aq)+ 12 e- → 6 H2O(l) Overall 2 CH3OH(aq)+ 3 O2(g)→ 2 CO2(g)+ 4 H2O(l) Which is the anode reaction,and what is being oxidized in the overall reaction?

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The nickel-cadmium battery cell has a standard potential of +1.20 V.The cell reaction is 2 NiO(OH)(s)+ Cd(s)+ 2 H2O(l)→ 2 Ni(OH)2(s)+ Cd(OH)2(s). What is the standard free energy change for this reaction?

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Calculate the value of the reaction quotient,Q,for the galvanic cell expressed using shorthand notation below.Use the balanced chemical equation that has the smallest whole number stoichiometric coefficients. Zn(s)∣ Zn2+(aq,0.0100 M)∣∣ Ag+(aq,1.10 M)∣ Ag(s)

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What are the coefficients in front of IO3-(aq)and I-(aq)when the following equation is balanced in an acidic solution? ________ IO3-(aq)+ ________ I-(aq)→ ________ I2(aq)

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When the equation MnO4-(aq)+ C2O42-(aq)→ Mn2+(aq)+ CO2(g)is balanced in acidic solution using the smallest whole numbers,the coefficient in front of the CO2(g)is ________.

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