Exam 18: Electrochemistry

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The initial concentrations of Ag+(aq)and Cu2+(aq)are both 1.0 M.What will happen to the cell voltage if The initial concentrations of Ag<sup>+</sup>(aq)and Cu<sup>2+</sup>(aq)are both 1.0 M.What will happen to the cell voltage if   Cu(NO<sub>3</sub>)<sub>2</sub> is added to the compartment containing the 1.0 M Cu<sup>2+</sup>(aq)? The cell voltage will Cu(NO3)2 is added to the compartment containing the 1.0 M Cu2+(aq)? The cell voltage will

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Which statement below is not true?

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Which cell involves a nonspontaneous redox reaction?

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What species is oxidized in the reaction: CuSO4(aq)+ Mg(s)→ MgSO4(aq)+ Cu(s)?

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What is the balanced chemical equation for the galvanic cell reaction expressed using shorthand notation below? Al(s)∣ Al3+(aq)∣∣ Cd2+(aq)∣ Cd(s)

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What is the reduction half-reaction for the following overall cell reaction? Ni2+(aq)+ 2 Ag(s)→ Ni(s)+ 2 Ag+(aq)

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In the redox reaction 2 S2O32-(aq)+ I3-(aq)→ S4O62-(aq)+ 3 I-(aq),if 18.75 mL of 0.2500 M Na2S2O3 is needed for complete reaction with 15.00 mL of the I3- solution,what is the molar concentration of I3-?

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Based on the following information, F2(g)+ 2 e- → 2 F-(aq)E° = +2.87 V Mg2+(aq)+ 2 e- → 2 Mg(s)E° = -2.37 V Which of the following chemical species is the strongest reducing agent?

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Consider the galvanic cell,Pt(s)∣ H2(1 atm)|H+(1 M)∣∣ Cl-(1 M)∣ Hg2Cl2(s)|Hg(l).Which one of the following changes to the cell would cause the cell potential to increase (i.e. ,become more positive)?

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Consider the following galvanic cell. Consider the following galvanic cell.   -Identify the anode and cathode,and indicate the direction of Na<sup>+</sup> ion and NO<sub>3</sub><sup>-</sup> ion flow from the salt bridge. -Identify the anode and cathode,and indicate the direction of Na+ ion and NO3- ion flow from the salt bridge.

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Shown below is an electrochemical cell with anode a and cathode c.Both the anode and the cathode are inert electrodes.The liquid shown in compartment b of the cell is molten potassium chloride,KCl(l). Shown below is an electrochemical cell with anode a and cathode c.Both the anode and the cathode are inert electrodes.The liquid shown in compartment b of the cell is molten potassium chloride,KCl(l).   -Determine whether this is a galvanic or an electrolytic cell and give the reaction occurring at the anode and the reaction occurring at the cathode. -Determine whether this is a galvanic or an electrolytic cell and give the reaction occurring at the anode and the reaction occurring at the cathode.

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Consider the following galvanic cell. Consider the following galvanic cell.   -What is the balanced equation for the cell reaction? -What is the balanced equation for the cell reaction?

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  -According to Table 17.1,which aqueous metal ion will reduce Ag<sup>+</sup>,but not Cu<sup>2+</sup>? -According to Table 17.1,which aqueous metal ion will reduce Ag+,but not Cu2+?

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Consider the following galvanic cell. Consider the following galvanic cell.   -Identify the anode and cathode,and indicate the direction of ion flow to and from each electrode. -Identify the anode and cathode,and indicate the direction of ion flow to and from each electrode.

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What is the relation between ΔG° and E° for the cell reaction below? Ni2+(aq)+ Fe(s)→ Fe2+(aq)+ Ni(s)

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The chlor-alkali industry is based on the electrolysis of aqueous NaCl.What are the products of this electrolysis?

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Consider the following standard reduction potentials, Zn2+(aq)+ 2 e- → Zn(s)E° = -0.76 V I2(s)+ 2 e- → 2 I-(aq)E° = +0.54 V Under standard conditions,

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  -Using Table 17.1,find E° for 2 H<sub>2</sub>O(l)→ 2 H<sub>2</sub>(g)+ O<sub>2</sub>(g). -Using Table 17.1,find E° for 2 H2O(l)→ 2 H2(g)+ O2(g).

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What is the Al3+:Ag+concentration ratio in the cell Al(s)|Al3+(aq)∣∣ Ag+(aq)|Ag(s)if the measured cell potential is 2.34 V?

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The following cell has a potential of 0.45 V at 25°C. Pt(s)∣ H2(1 atm)|H+(? M)∣∣ Cl-(1 M)∣ Hg2Cl2(s)|Hg(l) The standard half-cell potential for the half-reaction Hg2Cl2(s)+ 2 e- → 2 Hg(l)+ 2 Cl-(aq)is 0.28 V.What is the pH in the anode compartment?

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