Exam 9: Thermochemistry: Chemical Energy

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Which of CH4(g),C2H2(g),and CH3OH(l)provides the most energy per gram upon combustion and which provides the least? CH4(g)+ 2 O2(g)→ CO2(g)+ 2 H2O(l)ΔH° = -890 kJ 2 C2H2(g)+ 5 O2(g)→ 4 CO2(g)+ 2 H2O(l)ΔH° = -2599 kJ 2 CH3OH(l)+ 3 O2(g)→ 2 CO2(g)+ 4 H2O(l)ΔH° = -1453 kJ

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Which is expected to have the lowest specific heat capacity at 25°C?

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For the of freezing liquid butane at a given temperature and pressure,

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For a process at constant pressure,24,800 calories of heat are released.This quantity of heat is equivalent to

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Calculate Gibb's free energy and determine if the event is spontaneous or non-spontaneous for ΔH = 42 Jand ΔS = -111 J/K at 400 K.

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Which of the following can be interpreted as a measure of randomness?

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Determine the sign of ΔS° for each of the following: I.C6H6(s)→ C6H6(l) II.2 SO2(g)+ O2(g)→ 2 SO3(g)

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Heat transfer measured in a coffee-cup calorimeter at constant pressure is a measure of ________,but heat transfer measured in a bomb calorimeter at constant volume is a measure of ________.

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For the conversion of ice to water at 0°C and 1 atm,

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The first law of thermodynamics

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The following drawing is a representation of a reaction for which ΔH° = -22 kJ.This reaction is likely to be The following drawing is a representation of a reaction for which ΔH° = -22 kJ.This reaction is likely to be

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Which equation represents the reaction whose ΔH,represents the standard enthalpy of formation of CHCl3(l)at 25°C? (i.e. ,for which is ΔH = ΔH°f of CHCl3)

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The following drawing is a representation of the exothermic reaction in which ozone forms dioxygen. The following drawing is a representation of the exothermic reaction in which ozone forms dioxygen.   -What are the signs of ΔH and ΔS for this reaction? -What are the signs of ΔH and ΔS for this reaction?

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At 25°C the heat of fusion of aluminum is 10.6 kJ/mol and the heat of sublimation is 326.4 kJ/mol.What is the heat of vaporization of aluminum at 25°C?

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Because the number of moles of gas are increasing from 6 to 7 in the reaction shown below,at constant pressure ΔE is predicted to be slightly ________ negative than ΔH. C3H8(g)+ 5 O2(g)→ 3 CO2(g)+ 4 H2O(g)

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Find ΔH° for the reaction C3H8(g)+ 5 O2(g)→ 3 CO2(g)+ 4 H2O(l). ΔH° = -2046 kJ for the reaction: C3H8(g)+ 5 O2(g)→ 3 CO2(g)+ 4 H2O(g) The heat of vaporization of water is 44.0 kJ/mol.Note that H2O is a liquid in the first reaction and a gas in the second.

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Imagine a reaction that results in a change in both volume and temperature,as shown in the diagram below.What is the sign of the work being done,and what is the sign of the enthalpy change involved in this reaction? Imagine a reaction that results in a change in both volume and temperature,as shown in the diagram below.What is the sign of the work being done,and what is the sign of the enthalpy change involved in this reaction?

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Calculate the total quantity of heat required to convert 25.0 g of liquid CCl4(l)from 45.0°C to gaseous CCl4 76.8°C (the normal boiling point for CCl4)? The specific heat of CCl4(l)is Calculate the total quantity of heat required to convert 25.0 g of liquid CCl<sub>4</sub>(l)from 45.0°C to gaseous CCl<sub>4</sub> 76.8°C (the normal boiling point for CCl<sub>4</sub>)? The specific heat of CCl<sub>4</sub>(l)is   its heat of fusion is   and its heat of vaporization is  its heat of fusion is Calculate the total quantity of heat required to convert 25.0 g of liquid CCl<sub>4</sub>(l)from 45.0°C to gaseous CCl<sub>4</sub> 76.8°C (the normal boiling point for CCl<sub>4</sub>)? The specific heat of CCl<sub>4</sub>(l)is   its heat of fusion is   and its heat of vaporization is  and its heat of vaporization is Calculate the total quantity of heat required to convert 25.0 g of liquid CCl<sub>4</sub>(l)from 45.0°C to gaseous CCl<sub>4</sub> 76.8°C (the normal boiling point for CCl<sub>4</sub>)? The specific heat of CCl<sub>4</sub>(l)is   its heat of fusion is   and its heat of vaporization is

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The sign of ΔS° for reaction below is expected to be ________. 2 H2(g)+ O2(g)→ 2 H2O(g)

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The heat of combustion per mole for acetylene,C2H2(g),is -1299.5 kJ/mol.Assuming that the combustion products are CO2(g)and H2O(l),and given that the enthalpy of formation is -393.5 kJ/mol for CO2(g)and -285.8 kJ/mol for H2O(l),find the enthalpy of formation of C2H2(g).

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