Exam 9: Thermochemistry: Chemical Energy

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What is expected when the reaction shown below takes place in a thermally-insulated container outfitted with a movable piston at a constant atmospheric pressure of 1 atm? 2 C2H6(g)+ 7 O2(g)→ 4 CO2(g)+ 6 H2O(g)

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For the reaction 2CH4 (g)+ 3 Cl2 (g)→ 2 CHCl3 (l)+ 3 H2 (g),ΔH° = -118.6 kJ. ΔH°f = -134.1 kJ/mol for CHCl3 (l).Find ΔH°f for CH4 (g).

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For most chemical reactions

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Acetylene torches utilize the following reaction: 2 C2H2(g)+ 5 O2(g)→ 4 CO2(g)+ 2 H2O(g) Use the given standard enthalpies of formation to calculate ΔH° for this reaction. Acetylene torches utilize the following reaction: 2 C<sub>2</sub>H<sub>2</sub>(g)+ 5 O<sub>2</sub>(g)→ 4 CO<sub>2</sub>(g)+ 2 H<sub>2</sub>O(g) Use the given standard enthalpies of formation to calculate ΔH° for this reaction.

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For a particular process that is carried out at constant pressure,q = 140 kJ and w = -30 kJ.Therefore,

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Which is not a spontaneous process?

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A property whose value depends only on the present condition of the system and not how the system arrived at that condition is called a ________ function.

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When 2.500 mol of CH4(g)reacts with excess Cl2(g)at constant pressure according to the chemical equation shown below,1770.kJ of heat are released.Calculate the value of ΔH for this reaction,as written. 2 CH4(g)+ 3 Cl2(g)→ 2 CHCl3(l)+ 3 H2(g)ΔH = ?

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The law of conservation of energy is also known as the ________ law of thermodynamics.

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Calculate the total quantity of heat required to convert 50.0 g of liquid CCl4(l)from 25.0°C to gaseous CCl4 at 76.8°C (the normal boiling point for CCl4)? The specific heat of CCl4(l)is 0.857 J/(g ∙ °C),its heat of fusion is Calculate the total quantity of heat required to convert 50.0 g of liquid CCl<sub>4</sub>(l)from 25.0°C to gaseous CCl<sub>4</sub> at 76.8°C (the normal boiling point for CCl<sub>4</sub>)? The specific heat of CCl<sub>4</sub>(l)is 0.857 J/(g ∙ °C),its heat of fusion is   and its heat of vaporization is  and its heat of vaporization is Calculate the total quantity of heat required to convert 50.0 g of liquid CCl<sub>4</sub>(l)from 25.0°C to gaseous CCl<sub>4</sub> at 76.8°C (the normal boiling point for CCl<sub>4</sub>)? The specific heat of CCl<sub>4</sub>(l)is 0.857 J/(g ∙ °C),its heat of fusion is   and its heat of vaporization is

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For a process at constant pressure,

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For the freezing of liquid hexane,C6H,at a given temperature and pressure,

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At constant pressure for which of the reactions shown below should ΔH° be greater than ΔE°? I.2 SO2(g)+ O2(g)→ 2 SO3(g) II.C9H20(g)+ 14 O2(g)→ 9 CO2(g)+ 10 H2O(l) III.H2(g)+ F2(g)→ 2 HF(g) IV.N2O4(g)→ 2 NO2(g)

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The sum of the potential and kinetic energies for every molecule or ion in a system is the ________ energy of the system and is given the symbol ________.

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A gas absorbs 0.0 J of heat and then performs 13.1 J of work.The change in internal energy of the gas is

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At constant pressure,the combustion of 30.00 g of C2H6(g)releases 1560 kJ of heat.What is ΔH for the reaction given below? 2 C2H6(g)+ 7 O2(g)→ 4 CO2(g)+ 6 H2O(l)

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Imagine a reaction that results in a change in both volume and temperature,as shown in the diagram below.What is the sign of the work being done and the sign of the enthalpy change involved in this reaction? Imagine a reaction that results in a change in both volume and temperature,as shown in the diagram below.What is the sign of the work being done and the sign of the enthalpy change involved in this reaction?

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For a process at constant volume,

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One method for making ethanol,C2H5OH,involves the gas-phase hydration of ethylene,C2H4: Estimate ΔH for this reaction from the given average bond dissociation energies,D. One method for making ethanol,C<sub>2</sub>H<sub>5</sub>OH,involves the gas-phase hydration of ethylene,C<sub>2</sub>H<sub>4</sub>: Estimate ΔH for this reaction from the given average bond dissociation energies,D.    One method for making ethanol,C<sub>2</sub>H<sub>5</sub>OH,involves the gas-phase hydration of ethylene,C<sub>2</sub>H<sub>4</sub>: Estimate ΔH for this reaction from the given average bond dissociation energies,D.

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Coal gasification can be represented by the equation: 2 C(s)+ 2 H2O(g)→ CH4(g)+ CO2(g)ΔH = ? Use the following information to find ΔH for the reaction above. CO(g)+ H2(g)→ C(s)+ H2O(g)ΔH = -131 kJ CO(g)+ H2O(g)→ CO2(g)+ H2(g)ΔH = -41 kJ CO(g)+ 3 H2(g)→ CH4(g)+ H2O(g)ΔH = -206 kJ

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