Exam 9: Thermochemistry: Chemical Energy

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At constant pressure,the combustion of 25.0 g of C2H6(g)releases 1300 kJ of heat.What is ΔH for the reaction given below? 2 C2H6(g)+ 7 O2(g)→ 4 CO2(g)+ 6 H2O(l)

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A slice of cheese pizza has a caloric content of 550 Cal.If this energy could be used to power a 2500 Watt microwave oven,how many minutes could the microwave oven be operated? 1 W = 1 J/s

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Calculate the enthalpy of combustion per mole for C6H12O6.Assume that the combustion products are CO2(g)and H2O(l). Calculate the enthalpy of combustion per mole for C<sub>6</sub>H<sub>12</sub>O<sub>6</sub>.Assume that the combustion products are CO<sub>2</sub>(g)and H<sub>2</sub>O(l).

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When heated,mercury(II)oxide decomposes into elemental mercury and oxygen: 2 HgO(s)→ 2 Hg(l)+ O2(g)ΔH° = 181.6 kJ ΔS° = 216.4 J/K Estimate the temperature at which HgO should begin to decompose if the partial pressure of O2(g)is constant at 1.00 atm.

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The following drawing is a representation of the exothermic reaction in which ozone forms dioxygen. The following drawing is a representation of the exothermic reaction in which ozone forms dioxygen.   -This reaction is likely to be -This reaction is likely to be

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When 1.0 mole of MgSO4 is dissolved in water contained in a calorimeter,the temperature of the water and dissolved ions increases.Therefore the sign of ΔH for this reaction is ________,heat is transferred ________ the system ________ the surroundings,and the reaction is classified as ________.

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The net reaction is represented by

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How much heat is absorbed/released when 10.00 g of NH3(g)reacts in the presence of excess O2(g)to produce NO(g)and H2O(l)according to the following chemical equation? 4 NH3(g)+ 5 O2(g)→ 4 NO(g)+ 6 H2O(l)ΔH° = +1168 kJ

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At 1 atm pressure,the heat of sublimation of gallium is 277 kJ/mol and the heat of vaporization is 271 kJ/mol.To the correct number of significant figures,how much heat is required to melt 1.50 mol of gallium at 1 atm pressure?

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A reaction for which ΔE = -850 kJ is one in which products have 850 kJ ________ internal energy than the reactants,and products are ________ stable than the reactants.

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What are the signs of ΔH,ΔS,and ΔG for the following spontaneous change? What are the signs of ΔH,ΔS,and ΔG for the following spontaneous change?

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When 0.500 mol of CH4(g)reacts with excess Cl2(g)at constant pressure according to the chemical equation shown below,354 kJ of heat are released.Calculate the value of ΔH for this reaction,as written. 2 CH4(g)+ 3 Cl2(g)→ 2 CHCl3(l)+ 3 H2(g)ΔH = ?

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For a particular process that is carried out at constant pressure,q = 200 kJ and w = -85 kJ.Therefore,

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Which depends only on the initial and final state?

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Which of the following scenarios involves a transfer of heat from system to surroundings?

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Given: 4 NO2(g)+ O2(g)→ 2 N2O5(g)ΔH° = -110.2 kJ find ΔH° for 8 N2O5(g)→ 16 NO2(g)+ 4 O2(g).

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  -The reaction represented in the above drawing is likely to be -The reaction represented in the above drawing is likely to be

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What is the thermodynamic criterion for equilibrium for a reaction at constant temperature and pressure (PV work only)?

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Calculate the work energy,w,gained or lost by the system when a gas expands from 20 L to 35 L against a constant external pressure of 2.0 atm.[1 L ∙ atm = 101 J]

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A reaction is performed in a 1-L balloon at 25°C and 1 atm pressure.At the end of the reaction the balloon has expanded to 1.5 L and the surface of the balloon has a temperature of 35°C and is at 1 atm pressure.Determine whether the signs of the heat transferred,the work,and the energy change,respectively,are positive or negative.

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