Exam 12: Chemical Kinetics

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The first-order reaction,SO2Cl2 → SO2 + Cl2,has a half-life of 8.75 hours at 593 K.How long will it take for the concentration of SO2Cl2 to fall to 16.5% of its initial value?

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The fraction of collisions with sufficient energy to react is equal to

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For the zeroth-order reaction: A → products,what will happen to the rate of reaction if the concentration of A is doubled?

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Neptunium-239 has a half-life of 2.35 days.How many days must elapse for a sample of 239Np to decay to 1.00% of its original quantity?

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The following set of data was obtained by the method of initial rates for the reaction: S2O82-(aq)+ 3 I-(aq)→ 2 SO42-(aq)+ I3-(aq) What is the rate law for the reaction? The following set of data was obtained by the method of initial rates for the reaction: S<sub>2</sub>O<sub>8</sub><sup>2-</sup>(aq)+ 3 I<sup>-</sup>(aq)→ 2 SO<sub>4</sub><sup>2-</sup>(aq)+ I<sub>3</sub><sup>-</sup>(aq) What is the rate law for the reaction?

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The following set of data was obtained by the method of initial rates for the reaction: 2 HgCl2(aq)+ C2O42-(aq)→ 2 Cl-(aq)+ 2 CO2(g)+ Hg2Cl2(s) What is the value of the rate constant,k? The following set of data was obtained by the method of initial rates for the reaction: 2 HgCl<sub>2</sub>(aq)+ C<sub>2</sub>O<sub>4</sub><sup>2-</sup>(aq)→ 2 Cl<sup>-</sup>(aq)+ 2 CO<sub>2</sub>(g)+ Hg<sub>2</sub>Cl<sub>2</sub>(s) What is the value of the rate constant,k?

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A researcher needs 5.00 mg of 128Ba for an experiment.If the half-life of 128Ba is 2.43 days,how many milligrams of 128BaCl2 must she order from the manufacturer if it takes 4.50 days to ship the material from the manufacturer to the university? (Assume the molar mass of 128Ba is 128 g/mol. )

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What is the overall reaction order for the reaction that has the rate law: Rate = k[ O2] [ NO ]2?

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The following set of data was obtained by the method of initial rates for the reaction: 2 HgCl2(aq)+ C2O42-(aq)→ 2 Cl-(aq)+ 2 CO2(g)+ Hg2Cl2(s) What is the rate law for the reaction? The following set of data was obtained by the method of initial rates for the reaction: 2 HgCl<sub>2</sub>(aq)+ C<sub>2</sub>O<sub>4</sub><sup>2-</sup>(aq)→ 2 Cl<sup>-</sup>(aq)+ 2 CO<sub>2</sub>(g)+ Hg<sub>2</sub>Cl<sub>2</sub>(s) What is the rate law for the reaction?

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Which statement below regarding the half-life of a zeroth-order reaction is true?

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The following pictures represent the progress of a reaction in which two A molecules combine to give a more complex molecule A2,2A → A2. The following pictures represent the progress of a reaction in which two A molecules combine to give a more complex molecule A<sub>2</sub>,2A → A<sub>2</sub>.   -What is the order of reaction with respect to A? -What is the order of reaction with respect to A?

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What factor affects the rate of a chemical reaction?

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Neptunium-239 has a half-life of 2.35 days.How many days must elapse for a sample of 239Np to decay to 0.100% of its original quantity?

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The first-order reaction,SO2Cl2 → SO2 + Cl2,has a rate constant equal to 2.20 × 10-5 s-1 at 593 K.What percentage of the initial amount SO2Cl2 will remain after 6.00 hours?

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The reaction below is first order in H2 and second order in NO.What is the rate law for this reaction? 2 H2(g)+ 2 NO(g)→ N2(g)+ 2 H2O(g)

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A three-step mechanism has been suggested for the formation of carbonyl chloride: Step 1: Cl2→ 2 Cl (fast,equilibrium) Step 2: Cl + CO → COCl (fast,equilibrium) Step 3: COCl + Cl2 → COCl2 + Cl (slow) What is the molecularity of the rate-determining step?

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The first-order reaction,SO2Cl2 → SO2 + Cl2,has a rate constant equal to 2.20 × 10-5 s-1 at 593 K.What percentage of the initial amount of SO2Cl2 will remain after 2.00 hours?

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For a particular first-order reaction,it takes 48 minutes for the concentration of the reactant to decrease to 25% of its initial value.What is the value for rate constant (in s-1)for the reaction?

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The aquation of tris(1,10-phenanthroline)iron(II)in acid solution takes place according to the equation: Fe(phen)32+ + 3 H3O+ + 3 H2O → Fe(H2O)62+ + 3 phenH+ If the activation energy,Ea,is 126 kJ/mol and the rate constant at 30°C is 9.8 × 10-3 min-1,what is the frequency factor,A?

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The relative initial rates of the reaction A2 + B2 → products in vessels (a)-(d)are 1:1:4:4.Unshaded spheres represent A2 molecules,and shaded spheres represent B2 molecules present at the beginning of the reaction. The relative initial rates of the reaction A<sub>2</sub> + B<sub>2</sub> → products in vessels (a)-(d)are 1:1:4:4.Unshaded spheres represent A<sub>2</sub> molecules,and shaded spheres represent B<sub>2</sub> molecules present at the beginning of the reaction.   -What is the order of reaction with respect to B<sub>2</sub>? -What is the order of reaction with respect to B2?

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