Exam 8: Thermochemistry: Chemical Energy

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Given that ΔH°= -311 kJ for the hydrogenation of acetylene,C2H2: H-C=C-H(g)+ 2 H2(g)→ CH3-CH3(g) And the following bond dissociation energies,estimate a value for the C-to-C triple bond dissociation energy. Given that ΔH°= -311 kJ for the hydrogenation of acetylene,C<sub>2</sub>H<sub>2</sub>: H-C=C-H(g)+ 2 H<sub>2</sub>(g)→ CH<sub>3</sub>-CH<sub>3</sub>(g) And the following bond dissociation energies,estimate a value for the C-to-C triple bond dissociation energy.

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C

Which is the most exothermic reaction?

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B

Find ΔE° for the reaction below if the process is carried out at a constant pressure of 1.00 atm and ΔV (the volume change)= -24.5 L.(1 L ∙ atm = 101 J) 2 CO(g)+ O2 (g)→ 2 CO2(g)ΔH° = -566.kJ

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C

When 0.455 g of anthracene,C14H10,is combusted in a bomb calorimeter that has a water jacket containing 500.g of water,the temperature of the water increases by 8.63°C.Assuming that the specific heat of water is 4.18 J/(g ∙ °C),and that the heat absorption by the calorimeter is negligible,estimate the enthalpy of combustion per mole of anthracene.

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For a particular process that is carried out at constant pressure,q = 145 kJ and w = - 35 kJ.Therefore,

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Which combination always results in a reaction being spontaneous?

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It takes 11.2 kJ of energy to raise the temperature of 145 g of benzene from 23.0°C to 68.0°C.What is the specific heat of benzene?

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When 2.000 moles of H2(g)reacts with 1.000 mol of O2(g)to form 2.000 mol of H2O(l)at 25°C and a constant pressure of 1.00 atm.If 136.6 kJ of heat are released during this reaction,and PΔV is equal to -7.400 kJ,then

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For the conversion of water to ice at 25°C and 1 atm,

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For a process at constant pressure,49,600 calories of heat are released.This quantity of heat is equivalent to

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The sign of ΔG for a reaction is if the reaction is spontaneous,________ if the reaction is at equilibrium,and ________ if the reaction is nonspontaneous.

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  -The reaction represented in the above drawing is likely to be -The reaction represented in the above drawing is likely to be

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Is thermal energy a form of kinetic or potential molecular energy?

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At constant pressure for which of the reactions shown below should ΔH° be greater than ΔE° ? I.2 SO2(g)+ O2(g)→ 2 SO3(g) II.C3H8(g)+ 5 O2(g)→ 3 CO2(g)+ 4 H2O(l) III.H2(g)+ Cl2(g)→ 2 HCl(g) IV.N2O4(g)→ 2 NO2(g)

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For the of freezing liquid ethanol at a given temperature and pressure,

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Imagine a reaction that results in a change in both volume and temperature,as shown in the diagram below.What is the sign of the work being done and the sign of the enthalpy change involved in this reaction? Imagine a reaction that results in a change in both volume and temperature,as shown in the diagram below.What is the sign of the work being done and the sign of the enthalpy change involved in this reaction?

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What is the thermodynamic criterion for equilibrium for a reaction at constant temperature and pressure (PV work only)?

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When heated,mercury(II)oxide decomposes into elemental mercury and oxygen: 2 HgO(s)→ 2 Hg(l)+ O2(g)ΔH° = 181.6 kJ ΔS° = 216.4 J/K Estimate the temperature at which HgO should begin to decompose if the partial pressure of O2(g)is constant at 1.00 atm.

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A reaction is performed in a 1-L balloon at 25°C and 1 atm pressure.At the end of the reaction the balloon has expanded to 1.5 L and the surface of the balloon has a temperature of 35°C and is at 1 atm pressure.Determine whether the signs of the heat transferred,the work,and the energy change,respectively,are positive or negative.

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At 1 atm pressure the heat of sublimation of gallium is 277 kJ/mol and the heat of vaporization is 271 kJ/mol.How much heat is required to melt 1.50 mol of gallium at 1 atm pressure?

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