Exam 11: Solutions and Their Properties

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A phase diagram of temperature versus composition for a mixture of the two volatile liquids octane (bp = 69°C)and decane (bp = 126°C)is shown. A phase diagram of temperature versus composition for a mixture of the two volatile liquids octane (bp = 69°C)and decane (bp = 126°C)is shown.   -Assume that you start with a mixture containing 0.80 mol of decane and 0.20 mol of octane,at what approximate temperature will the mixture begin to boil? -Assume that you start with a mixture containing 0.80 mol of decane and 0.20 mol of octane,at what approximate temperature will the mixture begin to boil?

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B

Which of the following mixtures have components which can be separated by filtration?

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C

Which of the following should most favor the solubility of an ionic solid in water?

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Dinitrogen monoxide is still used as a general anesthetic.The Henry's law constant for the solubility of N2O in water is 2.5 × 10-2 mol/L·atm.What is the molar solubility of N2O in water if the partial pressure of N2O is 1500 m Hg?

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What is the expected freezing point of a 0.50 m solution of Li2SO4 in water? Kf for water is 1.86°C/m.

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For a liquid solution made by dissolving a solid or a gas in a liquid,the

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Substances with high lattice energies tend to be less soluble than substances with low lattice energies.On that basis predict the relative aqueous solubility at 20°C,from highest to lowest,of the following ionic compounds: Ce2(SO4)3,K2SO4,KBr,NaCl.

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What volume of 0.716 M KBr solution is needed to provide 10.5 g of KBr?

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Which of the following statements is true for a supersaturated solution?

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The dose of amoxicillin given to a young child is 40 mg/kg of body weight/day.If the amoxicillin is administered as a suspension having a concentration of 400 mg/5 mL,how many mL of amoxicillin must be administered per dose for a child weighing 18 pounds?

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Which of the following is not an application of colligative properties?

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KBr does not dissolve well in nonpolar solvents because

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  -What is the approximate boiling temperature of the liquid formed from the condensation of the vapor above a boiling solution that is 0.70 X<sub>A</sub> and 0.30 X<sub>B</sub>? -What is the approximate boiling temperature of the liquid formed from the condensation of the vapor above a boiling solution that is 0.70 XA and 0.30 XB?

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A solution of 0.2113 g of water dissolved in 25.0 g of a solvent freezes at 11.5°C below the freezing point of the solvent.What is Kf for this solvent?

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Which ion-dipole interaction results in the larger (more negative)hydration energy? Which ion-dipole interaction results in the larger (more negative)hydration energy?

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What molality of pentane is obtained by dissolving 5.0 g pentane,C5H12,in 245.0 g hexane,C6H14?

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The vapor pressure of water at 25°C is 23.8 mm Hg.The vapor pressure lowering,ΔP,of an aqueous solution containing 0.500 mole fraction NaCl is ________ (equal to,greater than,less than)11.9 mm Hg?

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Arrows in the energy diagram below represent enthalpy changes occurring in the endothermic formation of a solution: ΔHsoln = enthalpy of solution ΔHsolute-solute = enthalpy change involving solute-solute interactions ΔHsolute-solvent = enthalpy change involving solute-solvent interactions ΔHsolvent-solvent = enthalpy change involving solvent-solvent interactions Arrows in the energy diagram below represent enthalpy changes occurring in the endothermic formation of a solution: ΔH<sub>soln</sub> = enthalpy of solution ΔH<sub>solute-solute</sub> = enthalpy change involving solute-solute interactions ΔH<sub>solute-solvent</sub> = enthalpy change involving solute-solvent interactions ΔH<sub>solvent-solvent</sub> = enthalpy change involving solvent-solvent interactions   -Which arrows represent ΔH<sub>solute-solute</sub> and ΔH<sub>solvent-solvent</sub>? -Which arrows represent ΔHsolute-solute and ΔHsolvent-solvent?

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To make a 2.00 m solution,one could take 2.00 moles of solute and add

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Sodium hydroxide is available commercially as a 50.0% by weight aqueous solution.The density of the solution is 1.53 g/mL.Calculate the molarity of this sodium hydroxide solution.

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