Exam 11: Solutions and Their Properties

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At a given temperature the vapor pressures of benzene and toluene are 183 mm Hg and 59.2 mm Hg,respectively.Calculate the mole fraction of benzene in the vapor phase over a solution of benzene and toluene with Xbenzene = 0.600.

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Arrows in the energy diagram below represent enthalpy changes occurring in the exothermic formation of a solution: ΔHsoln = enthalpy of solution ΔHsolute-solute = enthalpy change involving solute-solute interactions ΔHsolute-solvent = enthalpy change involving solute-solvent interactions ΔHsolvent-solvent = enthalpy change involving solvent-solvent interactions Arrows in the energy diagram below represent enthalpy changes occurring in the exothermic formation of a solution: ΔH<sub>soln</sub> = enthalpy of solution ΔHsolute-solute = enthalpy change involving solute-solute interactions ΔHsolute-solvent = enthalpy change involving solute-solvent interactions ΔHsolvent-solvent = enthalpy change involving solvent-solvent interactions   -Which arrows represent ΔH<sub>solute-solute</sub> and ΔH<sub>solvent-solvent</sub>? -Which arrows represent ΔHsolute-solute and ΔHsolvent-solvent?

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According to the rule of thumb "like dissolves like." ionic solids like NaCl or polar substances like glucose are more soluble in ________ solvents,whereas nonpolar substances like I2 are more soluble in ________ solvents.

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Which of the following pairs of solutions have roughly the same boiling point elevation?

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When an ionic solute dissolves in water to form an unsaturated solution,the free energy change (ΔGsoln)is

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At 80.0°C heptane,C7H16,has a vapor pressure of 428 mm Hg and octane,C8H18,has a vapor pressure of 175 mm Hg.What is the vapor pressure of a solution that contains 20.0 g C7H16 and 11.4 g C8H18?

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Which cation in each set is expected to have the larger (more negative)hydration energy? I.Mg2+ or Ba2+ II.K+ or Al3+

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A solution of LiCl in water has XLiCl = 0.0500.What is the molality?

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What volume of 3.00 M CH3OH solution is needed to provide 0.220 mol of CH3OH?

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What is the weight percent of a caffeine solution made by dissolving 4.35 g of caffeine,C8H10N4O2,in 75 g of benzene,C6H6?

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A solution has a density of 1.023 g/mL and a concentration of 0.0800 g/dL.What is the concentration in parts per million?

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A 0.50 m solution of which solute has the largest van't Hoff factor?

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The solubility of argon in water at 25°C is 0.0150 mol/L.What is the Henry's Law constant for argon if the partial pressure of argon in air is 0.00934 atm?

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For which case would ΔHsoln be expected to be negative?

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When 2.36 g of a nonvolatile solute is dissolved in 100 g of solvent,the largest change in freezing point will be achieved when the solvent is

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Arrange the following compounds in order of their expected increasing solubility in water: KCl,CH3CH2-O-CH2CH3,CH3CH2CH2CH2-OH,CH3CH2CH2CH2CH3.

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What is the expected freezing point of a 0.50 m solution of Na2SO4 in water? Kf for water is 1.86°C/m.

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How many grams of KBr are required to make 350.mL of a 0.115 M KBr solution?

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A phase diagram of temperature versus composition for a mixture of the two volatile liquids octane (bp = 69°C)and decane (bp = 126°C)is shown. A phase diagram of temperature versus composition for a mixture of the two volatile liquids octane (bp = 69°C)and decane (bp = 126°C)is shown.   -Assume that the vapor at point c is condensed and reboiled.What is the liquid composition of the condensed vapor prior to reboiling? -Assume that the vapor at point c is condensed and reboiled.What is the liquid composition of the condensed vapor prior to reboiling?

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Calculate the freezing point of a solution of 20.0 g methyl salicylate,C7H6O2,dissolved in 800.g of benzene,C6H6.Kf for benzene is 5.10°C/m and the freezing point is 5.50°C for benzene.

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