Exam 11: Solutions and Their Properties

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Drawing (1)shows a nonequilibrium system comprised of pure water separated from an aqueous solution by a semipermeable membrane.Shaded spheres represent solute particles and unshaded spheres represent water molecules.Which drawing (2)-(5)represents this system after equilibrium is reached? Drawing (1)shows a nonequilibrium system comprised of pure water separated from an aqueous solution by a semipermeable membrane.Shaded spheres represent solute particles and unshaded spheres represent water molecules.Which drawing (2)-(5)represents this system after equilibrium is reached?

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  -What is the approximate boiling temperature of a mixture that is 0.70 X<sub>A</sub> and 0.30 X<sub>B</sub>? -What is the approximate boiling temperature of a mixture that is 0.70 XA and 0.30 XB?

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A solution of LiCl in water has XLiCl = 0.0 900.What is the molality?

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A phase diagram of temperature versus composition for a mixture of the two volatile liquids octane (bp = 69°C)and decane (bp = 126°C)is shown. A phase diagram of temperature versus composition for a mixture of the two volatile liquids octane (bp = 69°C)and decane (bp = 126°C)is shown.   -Assume that you start with a mixture containing 0.80 mol of decane and 0.20 mol of octane,what region of the diagram corresponds to liquid? -Assume that you start with a mixture containing 0.80 mol of decane and 0.20 mol of octane,what region of the diagram corresponds to liquid?

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Which of the following solutions will have the lowest freezing point?

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What volume of a 0.716 M KBr solution is needed to provide 30.5 g of KBr?

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  -Which drawing above represents the system with the lowest entropy? -Which drawing above represents the system with the lowest entropy?

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The Henry's Law constant of methyl bromide,CH3Br,is k = 0.159 mol/(L ∙ atm)at 25°C.What is the solubility of methyl bromide in water at 25°C and at a partial pressure of 270.mm Hg?

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How much water must be added to 40.0 g of CaCl2 to produce a solution that is 35.0 wt% CaCl2?

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Two beakers,one with pure water (light gray)and the other with an aqueous solution of KBr (dark gray),are placed in a closed container represented by drawing (a).Which of the drawings (a)-(d)represents what the beakers will look like after a substantial amount of time has passed? Two beakers,one with pure water (light gray)and the other with an aqueous solution of KBr (dark gray),are placed in a closed container represented by drawing (a).Which of the drawings (a)-(d)represents what the beakers will look like after a substantial amount of time has passed?

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Concentrations of fluoride in drinking water greater than 4.0 mg/L can cause mottled teeth in children.What is 4.0 mg/L expressed as molality?

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When ethylene glycol,HOCH2CH2OH,is added to the water in an automobile radiator,the effect is to

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When two similar liquids mix to form a solution,the entropy of solution (ΔSsoln)is expected to be

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What is the freezing point of a solution of 7.15 g MgCl2 in 100 g of water? Kf for water is What is the freezing point of a solution of 7.15 g MgCl<sub>2</sub> in 100 g of water? K<sub>f</sub> for water is

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A 1.0 m aqueous CaCl2 solution will have a ________ vapor pressure,________ freezing point,and ________ boiling point than a 1.0 m aqueous solution of NaCl.

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Freezing point depression,boiling point elevation,vapor pressure lowering,and osmotic pressure are examples of ________ properties,which depend on the amount but not the chemical identity of dissolved particles.

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What is the mole fraction of I2 in a solution made by dissolving 55.6 g of I2 in 245 g of hexane,C6H14?

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Which cation in each set would be expected to have the larger (more negative)hydration energy? I.Fe2+ or Fe3+ II.Li+ or NH4+

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Stainless steel is an example of a ________ solution.

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Drawing (1)shows a system in which an equilibrium exists between dissolved and undissolved gas particles at P = 1 atm.According to Henry's law,if the pressure is increased to 2 atm and equilibrium is restored,which drawing (2)-(5)best represents the equilibrium at 2 atm? Drawing (1)shows a system in which an equilibrium exists between dissolved and undissolved gas particles at P = 1 atm.According to Henry's law,if the pressure is increased to 2 atm and equilibrium is restored,which drawing (2)-(5)best represents the equilibrium at 2 atm?

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