Exam 13: Chemical Equilibrium

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Ammonium bromide is a crystalline solid that decomposes endothermically when heated: NH4Br(s)⇌ NH3(g)+ HBr(g).When solid NH4Br is added to an evacuated flask at 300°C,which change in reaction conditions below will cause the equilibrium to shift to the right?

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D

For the reaction H2(g)+ S(s)⇌ H2S(g),if the rate constant for the forward reaction is greater than the rate constant for the reverse reaction,the value of Kc must be ________ (equal to,greater than,less than)1.

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greater than

Calcium carbonate is relatively insoluble and the dissolution reaction is endothermic: CaCO3(s)⇌ Ca2+(aq)+ CO32-(aq).Which change in reaction condition below will shift the equilibrium to the right?

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D

The equilibrium constant,Kp,equals 3.40 for the isomerization reaction: Cis-2-butene ⇌ trans-2-butene. If a flask initially contains 0.250 atm of cis-2-butene and 0.145 atm of trans-2-butene,what is the equilibrium pressure of each gas?

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Nickel metal can be prepared by the reduction of nickel oxide: NiO(s)+ CO(g)⇌ CO2(g)+ Ni(s) At 936 K,Kp = 4.54 × 103 and at 1125 K,Kp = 1.58 × 103.Which statement is true?

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Which one of the following statements about the equilibrium constant,Kp,is false?

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The following picture represents the equilibrium state for the reaction A2 + B2 ⇌ 2AB.What is the relationship between the rate constant for the forward reaction,kf,and the rate constant for the reverse reaction kr? The following picture represents the equilibrium state for the reaction A<sub>2</sub> + B<sub>2</sub> ⇌ 2AB.What is the relationship between the rate constant for the forward reaction,k<sub>f</sub>,and the rate constant for the reverse reaction k<sub>r</sub>?

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The decomposition of ammonia is: 2 NH3(g)= N2(g)+ 3 H2(g).If Kp is 1.5 × 103 at 400°C,what is the partial pressure of ammonia at equilibrium when N2 is 0.10 atm and H2 is 0.15 atm?

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The decomposition of ammonia is: 2 NH3(g)= N2(g)+ 3 H2(g).If Kp is 1.5 × 103 at 400°C,what is the partial pressure of ammonia at equilibrium when N2 is 0.10 atm and H2 is 0.15 atm?

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For a homogeneous equilibrium of gases,which of the following changes in reaction conditions will not alter the equilibrium concentrations?

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Write the equilibrium equation for the forward reaction: 2 CH4(g)+ 3 O2(g)⇌ 2 CO(g)+ 4 H2O(g)

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If Kc is the equilibrium constant for a forward reaction what is Kc´ for the reverse reaction?

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What is the equilibrium equation for the reaction: NH4NO3(s)⇌ N2O(g)+ 2 H2O(g)?

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For the reaction: 4 HCl(g)+ O2(g)⇌ 2 Cl2(g)+ 2 H2O(l),the equilibrium constant is 0.063 at 400 K.If the reaction quotient is 0.100,which of the following statements is not correct?

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Consider the reaction A + B ⇌ 2 AB.The vessel on the right contains an equilibrium mixture of A atoms (shaded spheres),B atoms (unshaded spheres),and AB molecules. Consider the reaction A + B ⇌ 2 AB.The vessel on the right contains an equilibrium mixture of A atoms (shaded spheres),B atoms (unshaded spheres),and AB molecules.   -If the barrier between the two vessels is removed and the contents of the two vessels are allowed to mix,what will be observed? -If the barrier between the two vessels is removed and the contents of the two vessels are allowed to mix,what will be observed?

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For the reaction: N2(g)+ 2 O2(g)⇌ 2 NO2(g),Kc = 8.3 × 10-10 at 25°C.What is the concentration of N2 gas at equilibrium when the concentration of NO2 is five times the concentration of O2 gas?

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A catalyst increases the overall rate of reaction by lowering the activation energy,Ea,for

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At a certain temperature the equilibrium constant,Kc,equals 0.11 for the reaction: 2 ICl(g)⇌ I2(g)+ Cl2(g). What is the equilibrium concentration of ICl if 0.75 mol of I2 and 0.75 mol of Cl2 are initially mixed in a 2.0-L flask?

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What is true about the relationship of Kp and Kc for the reaction: 2 CH4(g)+ 3 O2(g)⇌ 2 CO(g)+ 4 H2O(g)?

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If Kc equals 0.11 at 25°C for the reaction: N2O4(g)⇌ 2 NO2(g),what is Kc for the reaction: NO2(g)⇌ 1/2 N2O4(g)?

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