Exam 13: Chemical Equilibrium
Exam 1: Chemistry: Matter and Measurement219 Questions
Exam 2: Atoms, molecules, and Ions257 Questions
Exam 3: Formulas, equations, and Moles208 Questions
Exam 4: Reactions in Aqueous Solutions174 Questions
Exam 5: Periodicity and the Atomic Structure of Atoms158 Questions
Exam 6: Ionic Bonds and Some Main-Group Chemistry173 Questions
Exam 7: Covalent Bonds and Molecular Structure232 Questions
Exam 8: Thermochemistry: Chemical Energy163 Questions
Exam 9: Gases: Their Properties and Behavior182 Questions
Exam 10: Liquids,solids,and Phase Changes186 Questions
Exam 11: Solutions and Their Properties192 Questions
Exam 12: Chemical Kinetics206 Questions
Exam 13: Chemical Equilibrium166 Questions
Exam 14: Aqueous Equilibria: Acids and Bases224 Questions
Exam 15: Applications of Aqueous Equilibria190 Questions
Exam 16: Thermodynamics: Entropy, free Energy, and Equilibrium144 Questions
Exam 17: Electrochemistry176 Questions
Exam 18: Hydrogen, oxygen, and Water175 Questions
Exam 19: The Main-Group Elements202 Questions
Exam 20: Transition Elements and Coordination Chemistry185 Questions
Exam 21: Metals and Solid-State Materials149 Questions
Exam 22: Nuclear Chemistry85 Questions
Exam 23: Organic and Biological Chemistry285 Questions
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What is the equilibrium constant,Kc,for the reaction:
2 Hg(l)+ O2(g)⇌ 2 HgO(s)
If the amounts of reactants and products at equilibrium are: 1.00 g of HgO(s),2.00 mL of Hg(l),and 1.60 M O2(g)? (The molar mass and density of HgO(s)is 217 g/mol,and 1.10 g/cm3.The molar mass and density of Hg(l)is 201 g/mol,and 13.6 g/mL. )
(Multiple Choice)
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If Kc = 0.900,and Kp = 538 for a hypothetical reaction,which of the equations below could represent the reaction at 25°C?
(Multiple Choice)
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What is the equilibrium equation for the following reaction?
FeS(s)+ 2 H3O+ (aq)⇌ Fe2+(aq)+ H2S (aq)+ 2 H2O (l)
(Multiple Choice)
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Shown below is a concentration vs.time plot for the reaction A ⇌ 2B.For this reaction the value of the equilibrium constant is 
(Multiple Choice)
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In a reversible reaction,when the rate of the forward reaction equals the rate of the reverse reaction,the reaction is at ________.
(Short Answer)
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Gaseous hydrogen bromide decomposes at elevated temperatures according to the following equation:
2 HBr(g)⇌ H2(g)+ Br2(g).
At a certain temperature a 2.00 L flask is initially filled only with 0.600 mol of HBr.What is the value of Kc at that temperature if the flask contains 0.104 mol of H2 at equilibrium?
(Multiple Choice)
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Nitric oxide reacts with oxygen to form nitrogen dioxide:
2 NO(g)+ O2(g)⇌ 2 NO2(g)
What is Kc for the forward reaction if the equilibrium concentration of NO is 0.200 M,O2 is 0.100 M,and NO2 is 0.250 M at 25°C?
(Multiple Choice)
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For the reaction shown below the equilibrium constant expression for Kc = ________.
HF(aq)+ H2O(l)⇌ H3O+(aq)+ F-(aq)
(Short Answer)
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An equilibrium mixture of CO,O2 and CO2 at a certain temperature contains 0.0010 M CO2 and 0.0100 M O2.At this temperature,Kc equals 1.4 × 102 for the reaction:
2 CO(g)+ O2(g)⇌ 2 CO2(g).
What is the equilibrium concentration of CO?
(Multiple Choice)
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The following pictures represent mixtures of cis-C2H2X2 molecules and trans-C2H2X2 molecules,which interconvert according to the equation cis-C2H2X2 ⇌ trans-C2H2X2.If mixture (1)is at equilibrium,which of the other mixtures are also at equilibrium? 
(Multiple Choice)
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Phosphorus pentachloride decomposes to phosphorus trichloride at high temperatures according to the equation:
PCl5(g)⇌ PCl3(g)+ Cl2(g)
At 250° 0.125 M PCl5 is added to the flask.If Kc = 1.80,what are the equilibrium concentrations of each gas?
(Multiple Choice)
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The esterification of acetic acid and ethanol is given by the reaction below:
C2H5OH(aq)+ CH3COOH(aq)⇌ CH3COOC2H5(aq)+ H2O(l)
When 1.00 mol of ethanol was mixed with 2.00 mol of acid in a 1.00 L flask,0.86 mol of ester was formed at room temperature.What is the value of the equilibrium constant,Kc?
(Multiple Choice)
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Shown below is a concentration vs.time plot for the reaction A ⇌ 2B.For this reaction the value of the equilibrium constant is 
(Multiple Choice)
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What is the equilibrium equation for the dissociation of formic acid in water?
HCOOH (aq)+ H2O (l)⇌ H3O+ (aq)+ HCOO- (aq)
(Multiple Choice)
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The reaction CaCO3(s)⇌ CaO(s)+ O2(g)is endothermic 298 K.The effect of adding a catalyst to the system at equilibrium will ________ (decrease,increase,have no effect on)the total quantity of CaCO3 once equilibrium is reestablished.
(Short Answer)
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Oxalic acid can donate two protons to water in successive reactions:
(1)H2C2O4(aq)+ H2O(l)⇌ H3O+(aq)+ HC2O4-(aq)
(2)HC2O4-(aq)+ H2O(l)⇌ H3O+(aq)+ C2O42-(aq)
If Kc1 = 5.9 × 10-2 and Kc2 = 6.4 × 10-5 at 25°C,what is the value of Kc for reaction (3)?
(3)H2C2O4(aq)+ 2 H2O(l)⇌ 2 H3O+(aq)+ C2O42-(aq)
(Multiple Choice)
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The reaction below virtually goes to completion because cyanide ion forms very stable complexes with Ni2+ ion:
[Ni(H2O)6]2+(aq)+ 4 CN-(aq)→ [Ni(CN)4]2-(aq)+ 6 H2O(l)
At the same time,incorporation of 14C labelled cyanide ion (14CN-)is very rapid:
[Ni(CN)4]2-(aq)+ 4 14CN-(aq)= [Ni(14CN)4]2-(aq)+ 4 CN-(aq)
Which statement below is correct with regard to stability and rate of reaction?
(Multiple Choice)
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The following pictures represent the equilibrium state for four different reactions of the type
A2 + X2 ⇌ 2 AX (X = B,C,D,E).A atoms are unshaded.X atoms are shaded.
-Which reaction has the largest equilibrium constant?
(Multiple Choice)
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The equilibrium constant is equal to 5.00 at 1300 K for the reaction:
2 SO2(g)+ O2(g)⇌ 2 SO3(g).
If initial concentrations are [SO2] = 6.00 M,[O2] = 0.45 M,and [SO3] = 9.00 M,the system is
(Multiple Choice)
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Kc = 57.0 at 700 K for the reaction shown below.
H2(g)+ I2(g)⇌ 2 HI(g)
If [H2(g)] = [I2(g)] = 0.200 M at equilibrium,the molar concentration [HI((g)] = ________ at equilibrium.
(Short Answer)
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