Exam 13: Chemical Equilibrium

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The following pictures represent the equilibrium state for four different reactions of the type A2 + X2 ⇌ 2 AX (X = B,C,D,E).A atoms are unshaded.X atoms are shaded. The following pictures represent the equilibrium state for four different reactions of the type A<sub>2</sub> + X<sub>2</sub> ⇌ 2 AX (X = B,C,D,E).A atoms are unshaded.X atoms are shaded.   -Which reaction has the smallest equilibrium constant? -Which reaction has the smallest equilibrium constant?

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Write the equilibrium equation for the reverse reaction: 2 CH4 (g)+ 3 O2 (g)⇌ 2 CO (g)+ 4 H2O (g)

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The reaction CaCO3(s)⇌ CaO(s)+ O2(g)is endothermic 298 K.The effect of adding additional CaO to the system at equilibrium will ________ (decrease,increase,have no effect on)the total quantity of CaCO3 once equilibrium is reestablished.

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The following pictures represent the initial state and the equilibrium state for the gaseous state reaction of A2 molecules (shaded spheres)with B atoms (unshaded spheres)to give AB molecules. The following pictures represent the initial state and the equilibrium state for the gaseous state reaction of A<sub>2</sub> molecules (shaded spheres)with B atoms (unshaded spheres)to give AB molecules.   -If the volume of the equilibrium mixture is decreased,what will happen to the number of AB molecules and the number of B atoms? -If the volume of the equilibrium mixture is decreased,what will happen to the number of AB molecules and the number of B atoms?

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If Kc is the equilibrium constant for a forward reaction,2 A⇌ B,what is Kc´ for the reaction 4 A⇌ 2B?

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Which statement is true for a reaction with Kc equal to 2.43 × 10-12?

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For the reaction shown below the value of Kp is ________ than the value of Kc,because Δn = ________. N2O4(g)⇌ 2 NO2(g)

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The equilibrium constant Kc for the reaction HF(aq)+ H2O(l)⇌ H3O+(aq)+F-(aq)is 3.5 × 10-4.What is the equilibrium concentration of H3O+ if the initial concentration of HF is 1.0 M?

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Kc is 1.67 × 1020 at 25°C for the formation of iron(III)oxalate complex ion: Fe3+(aq)+ 3 C2O42-(aq)⇌ [Fe(C2O4)3]3-(aq). If 0.0200 M Fe3+ is initially mixed with 1.00 M oxalate ion,what is the concentration of Fe3+ ion at equilibrium?

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The pink and blue species below form a violet colored mixture at equilibrium: [Co(H2O)6]2+ (aq)+ 4 Cl- (aq)⇌ [CoCl4]2- (aq)+ 6 H2O (l) (pink)(blue) If the concentration of [Co(H2O)6]2+ is increased,what happens to the solution?

(Multiple Choice)
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The reaction CaCO3(s)⇌ CaO(s)+ O2(g)is endothermic 298 K.The effect of increasing the temperature of the system at equilibrium will ________ (decrease,increase,have no effect on)the total quantity of CaCO3 once equilibrium is reestablished.

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For the reaction shown below,N2O4 and NO2 have equilibrium concentrations,[N2O4]eq = 2.160 × 10-4 and [NO2]eq = 1.001 × 10-3,respectively.The equilibrium constant,Kc,for this reaction equals ________. N2O4(g)⇌ 2 NO2(g)

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If Kc = 2.0 x 1033 at 25°C,for the following reaction: H2(g)+ Cl2(g)⇌ 2 HCl(g),then find Kp at the same temperature.

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A reaction in which reactants form products in the forward reaction and products simultaneously form reactants in the reverse reaction is said to be ________.

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At a certain temperature,Kc equals 1.4 × 102 for the reaction: 2 CO(g)+ O2(g)⇌ 2 CO2(g). If a 2.50-L flask contains 0.400 mol of CO2 and 0.100 mol of O2 at equilibrium,how many moles of CO are also present in the flask?

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Which equilibrium below is homogeneous?

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A reaction reaches dynamic equilibrium at a given temperature when

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Phosphorus pentachloride decomposes to phosphorus trichloride at high temperatures according to the reaction: PCl5(g)⇌ PCl3(g)+ Cl2(g) At 250°C,0.250 M PCl5 is added to a flask.If Kc = 1.80,what are the equilibrium concentrations of each gas?

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Write the equilibrium equation for the reverse reaction: 2 CH4(g)+ 3 O2(g)⇌ 2 CO(g)+ 4 H2O(g)

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Given the reaction: 2 HI ⇌ H2 + I2.If Kc' for the reverse reaction is 1.85 × 10-2 at 425°C,what is Kc for the forward reaction at the same temperature?

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