Exam 13: Chemical Equilibrium
Exam 1: Chemistry: Matter and Measurement219 Questions
Exam 2: Atoms, molecules, and Ions257 Questions
Exam 3: Formulas, equations, and Moles208 Questions
Exam 4: Reactions in Aqueous Solutions174 Questions
Exam 5: Periodicity and the Atomic Structure of Atoms158 Questions
Exam 6: Ionic Bonds and Some Main-Group Chemistry173 Questions
Exam 7: Covalent Bonds and Molecular Structure232 Questions
Exam 8: Thermochemistry: Chemical Energy163 Questions
Exam 9: Gases: Their Properties and Behavior182 Questions
Exam 10: Liquids,solids,and Phase Changes186 Questions
Exam 11: Solutions and Their Properties192 Questions
Exam 12: Chemical Kinetics206 Questions
Exam 13: Chemical Equilibrium166 Questions
Exam 14: Aqueous Equilibria: Acids and Bases224 Questions
Exam 15: Applications of Aqueous Equilibria190 Questions
Exam 16: Thermodynamics: Entropy, free Energy, and Equilibrium144 Questions
Exam 17: Electrochemistry176 Questions
Exam 18: Hydrogen, oxygen, and Water175 Questions
Exam 19: The Main-Group Elements202 Questions
Exam 20: Transition Elements and Coordination Chemistry185 Questions
Exam 21: Metals and Solid-State Materials149 Questions
Exam 22: Nuclear Chemistry85 Questions
Exam 23: Organic and Biological Chemistry285 Questions
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Acids donate protons to water according to the general equation:
HA(aq)+ H2O(l)⇌ H3O+(aq)+ A-(aq)
Consider the following acids and their equilibrium constants for reaction with water at 25°C.If all the acids have the same initial concentration,which is the strongest acid (i.e.which donates the most protons to water)?
(Multiple Choice)
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Shown below is a concentration vs.time plot for the reaction A ⇌ B.For this reaction the value of the equilibrium constant is 
(Multiple Choice)
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The reaction A2 + B2 ⇌ 2 AB has an equilibrium constant Kc = 1.8.The following pictures represent reaction mixtures that contain A2 molecules (shaded)and B2 molecules (unshaded),and AB molecules.Which reaction mixture is at equilibrium? 
(Multiple Choice)
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Nitric oxide reacts with oxygen to form nitrogen dioxide:
2 NO(g)+ O2(g)⇌ 2 NO2(g)
What is Kc' for the reverse reaction if the equilibrium concentration of NO is 0.300 M,O2 is 0.200 M,and NO2 is 0.530 M at 25°C?
(Multiple Choice)
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What is the value for Kc for the following reaction:
PbCl2(s)⇌ Pb2+(aq)+ 2 Cl-(aq),
If PbCl2(s)= 1.50 grams,[Pb2+] = 1.6 × 10-2 M and [Cl-] = 3.2 × 10-2 M at equilibrium? (The molar mass of PbCl2(s)is 278 g/mol and its density is 5.85 g/cm3. )
(Multiple Choice)
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Picture (1)represents an equilibrium mixture of solid CaCO3,solid CaO,and gaseous CO2,obtained as a result of the endothermic decomposition of CaCO3.
-Which picture (2)-(4)represents the equilibrium mixture after addition of four more CO2 molecules?
(Multiple Choice)
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Kc = 1.2 × 10-42 at 500 K for the reaction shown below.
H2(g)⇌ 2 H(g)
If [H2] = 1 × 10-2 M and [H] = 1.2 × 10-22 M,in order to achieve equilibrium a net reaction must occur from ________ to ________ until Qc = ________.
(Short Answer)
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The reaction CaCO3(s)⇌ CaO(s)+ O2(g)is endothermic 298 K.The effect of increasing the total volume of the system at equilibrium will ________ (decrease,increase,have no effect on)the total quantity of CaCO3 once equilibrium is reestablished.
(Short Answer)
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Phosphorus pentachloride decomposes to phosphorus trichloride and chlorine gas at elevated temperatures by the following reaction:
PCl5(g)⇌ PCl3(g)+ Cl2(g).If Kc = 1.8 at 250°C.
What is the value of Kp at the same temperature?
(Multiple Choice)
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At a certain temperature the equilibrium constant,Kc,equals 0.11 for the reaction:
2 ICl(g)⇌ I2(g)+ Cl2(g).
What is the equilibrium concentration of ICl if 0.75 mol of I2 and 0.75 mol of Cl2 are initially mixed in a 2.0-L flask?
(Multiple Choice)
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The reaction CaCO3(s)⇌ CaO(s)+ O2(g)is endothermic 298 K.The effect of increasing the partial pressure of O2 in the system at equilibrium will ________ (decrease,increase,have no effect on)the total quantity of CaCO3 once equilibrium is reestablished.
(Short Answer)
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If additional SCN- is added to the equilibrium system shown below,Le Châtelier's principle predicts a net reaction from ________ to ________,causing the red color to become ________.
Fe3+(aq)+ SCN-(aq)⇌ FeSCN2+(aq)
yellow colorless red
(Short Answer)
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The equilibrium constant,Kp,equals 3.40 at 25°C for the isomerization reaction:
Cis-2-butene ⇌ trans-2-butene.
If a flask initially contains 5.00 atm of each gas,in what direction will the system shift to reach equilibrium?
(Multiple Choice)
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Write the equilibrium equation for the forward reaction:
2 CH4 (g)+ 3 O2 (g)⇌ 2 CO (g)+ 4 H2O (g)
(Multiple Choice)
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At an elevated temperature,Kp = 4.2 × 10-9 for the reaction 2 HBr(g)⇌ H2(g)+ Br2(g).If the initial partial pressures of HBr,H2,and Br2 are 1.0 × 10-2 atm,2.0 × 10-4 atm,and 2.0 × 10-4 atm,respectively,what is the equilibrium partial pressure of H2?
(Short Answer)
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An equilibrium mixture of CO,O2 and CO2 at a certain temperature contains 0.0010 M CO2 and 0.0015 M O2.At this temperature,Kc,equals 1.4 × 102 for the reaction:
2 CO(g)+ O2(g)⇌ 2 CO2(g).
What is the equilibrium concentration of CO?
(Multiple Choice)
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The reaction A2 + B2 ⇌ 2AB has an equilibrium constant Kc = 1.8.The following pictures represent reaction mixtures that contain A2 molecules (shaded)and B2 molecules (unshaded),and AB molecules.
-Which nonequilibrium mixtures will react in the reverse direction to reach equilibrium?
(Multiple Choice)
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Kp = 1.5 × 103 at 400°C for the reaction 2 NH3(g)⇌ N2(g)+ 3 H2(g).What is the value of Kp for the reaction:
2 N2(g)+ 6 H2(g)⇌ 4 NH3(g)?
(Multiple Choice)
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Which of the following changes in reaction conditions will alter the composition of an equilibrium mixture of gases for a reaction having unequal moles of gaseous products and gaseous reactants?
(Multiple Choice)
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