Exam 13: Chemical Equilibrium

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A mixture of carbon monoxide,hydrogen,and methanol is at equilibrium.The balanced chemical equation is: CO(g)+ 2H2(g)⇌ CH3OH(g).At 250°C,the mixture contains 0.0960 M CO,0.191 M H2,and 0.150 M CH3OH.What is the value for Kc?

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At a certain temperature,Kc equals 1.4 × 102 for the reaction: 2 CO(g)+ O2(g)⇌ 2 CO2(g). If a 3.00-L flask contains 0.400 mol of CO2 and 0.100 mol of O2 at equilibrium,how many moles of CO are also present in the flask?

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The following pictures represent the initial state and the equilibrium state for the gaseous state reaction of A2 molecules (shaded spheres)with B atoms (unshaded spheres)to give AB molecules. The following pictures represent the initial state and the equilibrium state for the gaseous state reaction of A<sub>2</sub> molecules (shaded spheres)with B atoms (unshaded spheres)to give AB molecules.   -What is the best balanced chemical equation for the reaction? -What is the best balanced chemical equation for the reaction?

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Which of the following statements about a catalyst is true?

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The following picture represents the equilibrium state for the reaction A2 + B2 ⇌ 2AB.What is the relationship between the rate constant for the forward reaction,kf,and the rate constant for the reverse reaction kr? The following picture represents the equilibrium state for the reaction A<sub>2</sub> + B<sub>2</sub> ⇌ 2AB.What is the relationship between the rate constant for the forward reaction,k<sub>f</sub>,and the rate constant for the reverse reaction k<sub>r</sub>?

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"If a stress is applied to a reaction mixture at equilibrium,the reaction occurs in the direction that will relieve the stress." This statement is called

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When baking soda is heated it decomposes according to the following reaction: 2 NaHCO3(s)⇌ Na2CO3(s)+ H2O(g)+ CO2(g) If sufficient baking soda is placed in a container and heated to 90°C,the total pressure of the gases is 0.5451 atm.What is the value of Kp at that temperature?

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If Kc = 7.04 × 10-2 for the reaction: 2 HBr(g)⇌ H2(g)+ Br2(g),what is the value of Kc for the reaction: 1/2 H2(g)+ 1/2 Br2(g)== HBr(g)?

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Given the hypothetical reaction: 2 A(s)+ x B(g)⇌ 3 C(g),Kp = 0.0105 and Kc = 0.45 at 250°C.What is the value of the coefficient x?

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Kp is equal to 48.70 at 731 K for the reaction: H2(g)+ I2(g)⇌ 2 HI(g).Initially the mixture contains 0.08592 atm each of H2 and I2 and 1.0000 atm of HI.What is the pressure of HI at equilibrium?

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Picture (1)represents the equilibrium mixture for the gas-phase reaction A + B ⇌ 2 AB at 298 K.If the volume of the equilibrium mixture is decreased,which picture (2)-(4)represents the equilibrium at the reduced volume? Picture (1)represents the equilibrium mixture for the gas-phase reaction A + B ⇌ 2 AB at 298 K.If the volume of the equilibrium mixture is decreased,which picture (2)-(4)represents the equilibrium at the reduced volume?

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The decomposition of ammonia is: 2 NH3(g)⇌ N2(g)+ 3 H2(g).If the partial pressure of ammonia is 1.6 × 10-3 atm and the partial pressures of N2 and H2 are each 0.25 atm at equilibrium,what is the value for Kc at 400°C for the forward reaction?

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Shown below is a concentration vs.time plot for the reaction A ⇌ B.For this reaction the value of the equilibrium constant is Shown below is a concentration vs.time plot for the reaction A ⇌ B.For this reaction the value of the equilibrium constant is

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The reaction A2 + B2 ⇌ 2AB has an equilibrium constant Kc = 1.8.The following pictures represent reaction mixtures that contain A2 molecules (shaded)and B2 molecules (unshaded),and AB molecules. The reaction A<sub>2</sub> + B<sub>2 </sub>⇌ 2AB has an equilibrium constant K<sub>c</sub> = 1.8.The following pictures represent reaction mixtures that contain A<sub>2</sub> molecules (shaded)and B<sub>2</sub> molecules (unshaded),and AB molecules.   -Which nonequilibrium mixture will react in the forward direction to reach equilibrium? -Which nonequilibrium mixture will react in the forward direction to reach equilibrium?

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Which of the following statements is false regarding the equilibrium constant,Kc?

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Iron oxide ores are reduced to iron metal by exothermic reaction with carbon monoxide: FeO(s)+ CO(g)⇌ Fe(s)+ CO2(g) Which of the following changes in condition will cause the equilibrium to shift to the right?

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Which will not alter the composition of an equilibrium mixture?

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For the reaction CaCO3(s)⇌ CaO(s)+ O2(g)the equilibrium expression is Kp = ________.

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Salt solubilities can be compared by the concentration of cation formed when the salt dissolves in the general reaction: MaXb(s)⇌ a Mb+(aq)+ b Xa-(aq).Given the following salts and their equilibrium constants for the reaction above at 25°C,which salt is the least soluble?

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For the reaction shown below,which change in conditions made to the system at equilibrium will result in a net reaction to the right to form more product? C(s)+ 2 H2(g)⇌ CH4(g)ΔH° = -74.8 kJ

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