Exam 8: Thermochemistry: Chemical Energy

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At constant pressure,the combustion of 5.00 g of C2H6(g)releases 259 kJ of heat.What is ΔH for the reaction given below? 2 C2H6(g)+ 7 O2(g)→ 4 CO2(g)+ 6 H2O(l)

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Which of CH4(g),C2H2(g),and CH3OH(l)provides the most energy per gram upon combustion and which provides the least? CH4(g)+ 2 O2(g)→ CO2(g)+ 2 H2O(l)ΔH° = -890 kJ 2 C2H2(g)+ 5 O2(g)→ 4 CO2(g)+ 2 H2O(l)ΔH° = -2599 kJ 2 CH3OH(l)+ 3 O2(g)→ 2 CO2(g)+ 4 H2O(l)ΔH° = -1453 kJ

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When 1.00 mol of benzene is vaporized at a constant pressure of 1.00 atm and at its normal boiling point of 80.1°C,33.9 kJ are absorbed and PΔV for the vaporization process is equal to 2.90 kJ,then

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Under thermodynamic standard state conditions the element oxygen occurs as

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Which of the following can be interpreted as a measure of randomness?

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It takes 11.2 kJ of energy to raise the temperature of 145 g of benzene from 25.0°C to 70.0°C.What is the specific heat of benzene?

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The following drawing is a representation of the exothermic reaction in which ozone forms dioxygen. The following drawing is a representation of the exothermic reaction in which ozone forms dioxygen.   -What are the signs of ΔH and ΔS for this reaction? -What are the signs of ΔH and ΔS for this reaction?

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The enthalpy of fusion of naphthalene,C10H8,is 19.1 kJ/mol at 78.2°C,its melting point.Calculate the entropy of fusion at the melting point.

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A process is carried out at constant pressure.Given that 0 > ΔH > ΔE,

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For the expansion of an ideal gas into a vacuum at constant temperature,ΔH = 0.What can be said about ΔE and ΔS?

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Calculate the work energy,w,gained or lost by the system when a gas expands from 15 L to 35 L against a constant external pressure of 1.5 atm.[1 L ∙ atm = 101 J]

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The sign of ΔS° for reaction below is expected to be ________. 2 H2(g)+ O2(g)→ 2 H2O(g)

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What is expected when the reaction shown below takes place in a thermally-insulated container outfitted with a movable piston at a constant atmospheric pressure of 1 atm? 2 C2H6(g)+ 7 O2(g)→ 4 CO2(g)+ 6 H2O(g)

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Heat transfer measured in a coffee-cup calorimeter at constant pressure is a measure of ________,but heat transfer measured in a bomb calorimeter at constant volume is a measure of ________.

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The specific heat of copper is 0.385 J/(g ∙°C).If 34.2 g of copper,initially at 25°C,absorbs 4.689 kJ,what will be the final temperature of the copper?

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Because the number of moles of gas are increasing from 6 to 7 in the reaction shown below,at constant pressure ΔE is predicted to be slightly ________ negative than ΔH. C3H8(g)+ 5 O2(g)→ 3 CO2(g)+ 4 H2O(g)

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When 0.455 g of anthracene,C14H10,is combusted in a bomb calorimeter that has a water jacket containing 500.0 g of water,the temperature of the water increases by 8.63°C.Assuming that the specific heat of water is 4.18 J/(g ∙ °C),and that the heat absorption by the calorimeter is negligible,estimate the enthalpy of combustion per mole of anthracene.

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Which is expected to have the largest carbon-oxygen bond dissociation energy?

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Determine the sign of ΔS° for each of the following: I.The mixing of two gases at a given temperature and pressure II.C(s)+ 2 H2O(g)→ CO2(g)+ 2 H2(g)

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At 25°C the heat of fusion of aluminum is 10.6 kJ/mol and the heat of sublimation is 326.4 kJ/mol.What is the heat of vaporization of aluminum at 25°C?

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