Exam 8: Thermochemistry: Chemical Energy

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Imagine a reaction that results in a change in both volume and temperature,as shown in the diagram below.What is the sign of the work being done,and what is the sign of the enthalpy change involved in this reaction? Imagine a reaction that results in a change in both volume and temperature,as shown in the diagram below.What is the sign of the work being done,and what is the sign of the enthalpy change involved in this reaction?

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The reaction 4 Ag(s)+ O2(g)→ 2 Ag2O(s)favors Ag2O at low temperature,but it favors Ag and O2 at high temperatures.How can this be explained in terms of ΔH and ΔS?

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For the reaction I2(g)→ I2(s),ΔH° = -62.4 kJ at 25°C.Based on these data,at 25°C

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When 1.50 mol of CH4(g)reacts with excess Cl2(g)at constant pressure according to the chemical equation shown below,1062 kJ of heat are released.Calculate the value of ΔH for this reaction,as written. 2 CH4(g)+ 3 Cl2(g)→ 2 CHCl3(l)+ 3 H2(g)ΔH = ?

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Most chemical reactions are carried out in one of two ways: I.in an open vessel at constant atmospheric pressure II.in a closed vessel Which is true?

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When 1.0 mole of MgSO4 is dissolved in water contained in a calorimeter,the temperature of the water and dissolved ions increases.Therefore the sign of ΔH for this reaction is ________,heat is transferred ________ the system ________ the surroundings,and the reaction is classified as ________.

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At 1 atm pressure,the heat of sublimation of gallium is 277 kJ/mol and the heat of vaporization is 271 kJ/mol.To the correct number of significant figures,how much heat is required to melt 2.50 mol of gallium at 1 atm pressure?

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For a system at constant pressure,12,400 calories of heat are released.This quantity of heat is equivalent to

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When 0.250 mol of CH4(g)reacts with excess Cl2(g)at constant pressure according to the chemical equation shown below,177 kJ of heat are released.Calculate the value of ΔH for this reaction,as written. 2 CH4(g)+ 3 Cl2(g)→ 2 CHCl3(l)+ 3 H2(g)ΔH = ?

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For the conversion of ice to water at 0°C and 1 atm,

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The intermediate,T,+ S is represented by

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Energy can be classified as either ________ energy (energy of motion)or ________ energy (stored energy).

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Calculate the total quantity of heat required to convert 25.0 g of liquid CCl4(l)from 25.0°C to gaseous CCl4 at 76.8°C (the normal boiling point for CCl4)? The specific heat of CCl4(l)is 0)857 J/(g·°C),its heat of fusion is 3.27 kJ/mol,and its heat of vaporization is 29.82 kJ/mol.

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Consider the conversion of white tin to gray tin: Sn(white)→ Sn(gray)ΔH° = -2.09 kJ ΔS° = -7.41 J/K Based on these data,

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The nutritional calorie (abbreviated Cal)is equal to

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The heat of combustion per mole for acetylene,C2H2(g),is -1299.5 kJ/mol.Assuming that the combustion products are CO2(g)and H2O(l),and given that the enthalpy of formation is -393.5 kJ/mol for CO2(g)and -285.8 kJ/mol for H2O(l),find the enthalpy of formation of C2H2(g).

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Which equation represents the reaction whose ΔH,represents the standard enthalpy of formation of CHCl3(l)at 25°C? (i.e. ,for which is ΔH = ΔH°f of CHCl3)

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  -What are the signs of ΔH and ΔS for the reaction represented in the above drawing? -What are the signs of ΔH and ΔS for the reaction represented in the above drawing?

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The values of ΔH°f for the three states of benzene are approximately -22 kcal/mol,-11 kcal/mol,and 20 kcal/mol.Which is the value for solid benzene?

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The heat of vaporization of water at 100°C is 40.66 kJ/mol.Calculate the quantity of heat that is absorbed/released when 5.00 g of steam condenses to liquid water at 100°C.

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