Exam 18: Entropy, Free Energy, and Equilibrium

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The heat of vaporization of 1-pentanol is 55.5 kJ/mol, and its entropy of vaporization is 148 J/K•mol. What is the approximate boiling point of 1-pentanol?

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Sodium carbonate can be made by heating sodium bicarbonate: 2NaHCO3(s) → Na2CO3(s) + CO2(g) + H2O(g) At 25°C, for this reaction, ΔH°rxn = 128.9 kJ/mol and ΔG°rxn = 33.1 kJ/mol. Above what minimum temperature will the reaction become spontaneous under standard state conditions?

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How does the entropy change when a gas is liquified?

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What is defined as a measure of the randomness or disorder of a system?

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What is ΔG°rxn for the following reaction? 2NO(g) + Cl2(g) → 2NOCl(g) What is ΔG°<sub>rxn </sub>for the following reaction? 2NO(g) + Cl<sub>2</sub>(g) → 2NOCl(g)

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For a chemical reaction to be spontaneous only at high temperatures, which conditions must be met?

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HI has a normal boiling point of -35.4°C, and its ΔHvap is 21.16 kJ/mol. What is the molar entropy of vaporization (ΔSvap) of HI?

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The reaction SiO2(s) + Pb(s) → PbO2(s) + Si(s) is spontaneous: ΔG°f (PbO2(s)) = -217 kJ/mol ΔG°f (SiO2(s)) = -856 kJ/mol

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Which species will have the lowest absolute entropy at 25°C?

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Ozone (O3) in the atmosphere can react with nitric oxide (NO) as follows. O3(g) + NO(g) → NO2(g) + O2(g). ΔH°rxn = -199 kJ/mol, ΔS°rxn = -4.1 J/K • mol What is ΔG°rxn for this reaction at 25°C?

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The absolute standard entropy of atom X(g) is 100 J/K • mol. Which is a reasonable value for the absolute standard entropy of X2(g)?

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The higher the pressure of a gas sample, the greater is its entropy.

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The entropy change ΔS° at 298 K for the reaction NH4Cl(s) →NH3(g) + HCl(g) is negative.

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At equilibrium, ΔG° = 0.

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________ is the pressure required for standard entropy conditions.

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The following reaction is spontaneous under standard state conditions at 25°C: AgCl(s) → Ag+ (aq) + Cl- (aq) (ΔG° = 55 kJ/mol)

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Consider the figure below which shows ΔG° for a chemical process plotted against absolute temperature. Which one of the following is an incorrect conclusion, based on the information in the diagram? Consider the figure below which shows ΔG° for a chemical process plotted against absolute temperature. Which one of the following is an incorrect conclusion, based on the information in the diagram?

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Which of the following has ΔG°f = 0 at 25oC?

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What is ΔG°rxn at 298 K for the following reaction? 2Cl2(g) + SO2(g) → SOCl2(g) + Cl2O(g) What is ΔG°<sub>rxn </sub>at 298 K for the following reaction? 2Cl<sub>2</sub>(g) + SO<sub>2</sub>(g) → SOCl<sub>2</sub>(g) + Cl<sub>2</sub>O(g)

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Which of the following is an example of a nonspontaneous process?

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