Exam 18: Electrochemistry: The Quest for Clean Energy

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Because of recent advances in recovery technology, the supply of natural gas, which is mostly methane, has increased significantly. If 1 mole of methane is consumed in a fuel cell powering an automobile, estimate (1) how much work is produced, and (2) the voltage produced by the cell. The data in the table below may be helpful. Species Because of recent advances in recovery technology, the supply of natural gas, which is mostly methane, has increased significantly. If 1 mole of methane is consumed in a fuel cell powering an automobile, estimate (1) how much work is produced, and (2) the voltage produced by the cell. The data in the table below may be helpful. Species

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For the following reaction, predict the pH if the pressure of O2 is 3.00 atm and the bromide ion concentration is 2.10 M. The measured cell potential (Ecell) was 0.100 V. For the following reaction, predict the pH if the pressure of O<sub>2</sub> is 3.00 atm and the bromide ion concentration is 2.10 M. The measured cell potential (E<sub>cell</sub>) was 0.100 V.   Half reactions:   E<font face=symbol></font> <font face=symbol></font> <font face=symbol></font>1.077 V   E<font face=symbol></font> <font face=symbol></font> <font face=symbol></font>1.229 V Half reactions: For the following reaction, predict the pH if the pressure of O<sub>2</sub> is 3.00 atm and the bromide ion concentration is 2.10 M. The measured cell potential (E<sub>cell</sub>) was 0.100 V.   Half reactions:   E<font face=symbol></font> <font face=symbol></font> <font face=symbol></font>1.077 V   E<font face=symbol></font> <font face=symbol></font> <font face=symbol></font>1.229 V E 1.077 V For the following reaction, predict the pH if the pressure of O<sub>2</sub> is 3.00 atm and the bromide ion concentration is 2.10 M. The measured cell potential (E<sub>cell</sub>) was 0.100 V.   Half reactions:   E<font face=symbol></font> <font face=symbol></font> <font face=symbol></font>1.077 V   E<font face=symbol></font> <font face=symbol></font> <font face=symbol></font>1.229 V E 1.229 V

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Which one of the following items does not characterize an oxidizing agent?

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The diagram below represents a voltaic cell. In this cell, which species is the oxidizing agent? Al(s)|Al3(1.0 M)||Cu2(1.0 M)|Cu(s)

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For the following reaction, predict the pH if the pressure of O2 is 3.00 atm and the bromide ion concentration is 2.10 M. The measured cell potential (Ecell) was 0.100V. For the following reaction, predict the pH if the pressure of O<sub>2</sub> is 3.00 atm and the bromide ion concentration is 2.10 M. The measured cell potential (E<sub>cell</sub>) was 0.100V.   Half reactions:   E<font face=symbol></font> <font face=symbol></font> <font face=symbol></font>1.077 V   E<font face=symbol></font> <font face=symbol></font> <font face=symbol></font>1.229 V Half reactions: For the following reaction, predict the pH if the pressure of O<sub>2</sub> is 3.00 atm and the bromide ion concentration is 2.10 M. The measured cell potential (E<sub>cell</sub>) was 0.100V.   Half reactions:   E<font face=symbol></font> <font face=symbol></font> <font face=symbol></font>1.077 V   E<font face=symbol></font> <font face=symbol></font> <font face=symbol></font>1.229 V E 1.077 V For the following reaction, predict the pH if the pressure of O<sub>2</sub> is 3.00 atm and the bromide ion concentration is 2.10 M. The measured cell potential (E<sub>cell</sub>) was 0.100V.   Half reactions:   E<font face=symbol></font> <font face=symbol></font> <font face=symbol></font>1.077 V   E<font face=symbol></font> <font face=symbol></font> <font face=symbol></font>1.229 V E 1.229 V

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In the reaction below, ________ is the oxidizing agent. In the reaction below, ________ is the oxidizing agent.

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A voltaic cell is constructed based on the oxidation of zinc metal and the reduction of silver cations. Solutions of silver nitrate and zinc nitrate also were used. Locate the silver nitrate on the diagram. A voltaic cell is constructed based on the oxidation of zinc metal and the reduction of silver cations. Solutions of silver nitrate and zinc nitrate also were used. Locate the silver nitrate on the diagram.

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An electrochemical cell at 298 K is composed of two compartments, labeled C1 and C2. C1 consists of a copper metal electrode immersed in a 0.30 M copper sulfate solution. C2 consists of a copper metal electrode immersed in a 1.5 M copper sulfate solution. An electrochemical cell at 298 K is composed of two compartments, labeled C1 and C2. C1 consists of a copper metal electrode immersed in a 0.30 M copper sulfate solution. C2 consists of a copper metal electrode immersed in a 1.5 M copper sulfate solution.   ,   <font face=symbol></font><font face=symbol></font> <font face=symbol></font> 0.34 V Which statement regarding this electrochemical cell is not correct? , An electrochemical cell at 298 K is composed of two compartments, labeled C1 and C2. C1 consists of a copper metal electrode immersed in a 0.30 M copper sulfate solution. C2 consists of a copper metal electrode immersed in a 1.5 M copper sulfate solution.   ,   <font face=symbol></font><font face=symbol></font> <font face=symbol></font> 0.34 V Which statement regarding this electrochemical cell is not correct? 0.34 V Which statement regarding this electrochemical cell is not correct?

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The capacity of a battery usually is specified in units of amperes hours. Show that with this information and the voltage of the battery, you can determine the amount of energy that can be obtained from the battery.

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When aluminum metal is obtained from aluminum oxide (Al2O3), ________ moles of electrons must be transferred for each mole of aluminum oxide processed.

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Oxidation is the ________

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The following reaction is called the "super iron reaction." In this reaction, identify (1) the species oxidized, (2) the species reduced, and (3) the number of electrons transferred for the reaction as written, and (4) explain why it is called the "super iron reaction." The following reaction is called the super iron reaction. In this reaction, identify  (1) the species oxidized,  (2) the species reduced, and  (3) the number of electrons transferred for the reaction as written, and  (4) explain why it is called the super iron reaction.

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Where in the periodic table do you find the elements that are the best reducing agents with the most negative standard reduction potentials?

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What is the standard cell potential for a voltaic cell using the Pb2/Pb and Mg2/Mg half-reactions? Which metal is the cathode? Standard Reduction Potentials (volts) in Aqueous Solution What is the standard cell potential for a voltaic cell using the Pb<sup>2</sup><font face=symbol><sup></sup></font>/Pb and Mg<sup>2</sup><font face=symbol><sup></sup></font>/Mg half-reactions? Which metal is the cathode? Standard Reduction Potentials (volts) in Aqueous Solution   <font face=symbol></font>1.80   <font face=symbol></font>1.50   <font face=symbol></font>0.771   <font face=symbol></font>0.535   <font face=symbol></font>0.124   <font face=symbol></font>1.66   <font face=symbol></font>2.37   <font face=symbol></font>2.93 1.80 What is the standard cell potential for a voltaic cell using the Pb<sup>2</sup><font face=symbol><sup></sup></font>/Pb and Mg<sup>2</sup><font face=symbol><sup></sup></font>/Mg half-reactions? Which metal is the cathode? Standard Reduction Potentials (volts) in Aqueous Solution   <font face=symbol></font>1.80   <font face=symbol></font>1.50   <font face=symbol></font>0.771   <font face=symbol></font>0.535   <font face=symbol></font>0.124   <font face=symbol></font>1.66   <font face=symbol></font>2.37   <font face=symbol></font>2.93 1.50 What is the standard cell potential for a voltaic cell using the Pb<sup>2</sup><font face=symbol><sup></sup></font>/Pb and Mg<sup>2</sup><font face=symbol><sup></sup></font>/Mg half-reactions? Which metal is the cathode? Standard Reduction Potentials (volts) in Aqueous Solution   <font face=symbol></font>1.80   <font face=symbol></font>1.50   <font face=symbol></font>0.771   <font face=symbol></font>0.535   <font face=symbol></font>0.124   <font face=symbol></font>1.66   <font face=symbol></font>2.37   <font face=symbol></font>2.93 0.771 What is the standard cell potential for a voltaic cell using the Pb<sup>2</sup><font face=symbol><sup></sup></font>/Pb and Mg<sup>2</sup><font face=symbol><sup></sup></font>/Mg half-reactions? Which metal is the cathode? Standard Reduction Potentials (volts) in Aqueous Solution   <font face=symbol></font>1.80   <font face=symbol></font>1.50   <font face=symbol></font>0.771   <font face=symbol></font>0.535   <font face=symbol></font>0.124   <font face=symbol></font>1.66   <font face=symbol></font>2.37   <font face=symbol></font>2.93 0.535 What is the standard cell potential for a voltaic cell using the Pb<sup>2</sup><font face=symbol><sup></sup></font>/Pb and Mg<sup>2</sup><font face=symbol><sup></sup></font>/Mg half-reactions? Which metal is the cathode? Standard Reduction Potentials (volts) in Aqueous Solution   <font face=symbol></font>1.80   <font face=symbol></font>1.50   <font face=symbol></font>0.771   <font face=symbol></font>0.535   <font face=symbol></font>0.124   <font face=symbol></font>1.66   <font face=symbol></font>2.37   <font face=symbol></font>2.93 0.124 What is the standard cell potential for a voltaic cell using the Pb<sup>2</sup><font face=symbol><sup></sup></font>/Pb and Mg<sup>2</sup><font face=symbol><sup></sup></font>/Mg half-reactions? Which metal is the cathode? Standard Reduction Potentials (volts) in Aqueous Solution   <font face=symbol></font>1.80   <font face=symbol></font>1.50   <font face=symbol></font>0.771   <font face=symbol></font>0.535   <font face=symbol></font>0.124   <font face=symbol></font>1.66   <font face=symbol></font>2.37   <font face=symbol></font>2.93 1.66 What is the standard cell potential for a voltaic cell using the Pb<sup>2</sup><font face=symbol><sup></sup></font>/Pb and Mg<sup>2</sup><font face=symbol><sup></sup></font>/Mg half-reactions? Which metal is the cathode? Standard Reduction Potentials (volts) in Aqueous Solution   <font face=symbol></font>1.80   <font face=symbol></font>1.50   <font face=symbol></font>0.771   <font face=symbol></font>0.535   <font face=symbol></font>0.124   <font face=symbol></font>1.66   <font face=symbol></font>2.37   <font face=symbol></font>2.93 2.37 What is the standard cell potential for a voltaic cell using the Pb<sup>2</sup><font face=symbol><sup></sup></font>/Pb and Mg<sup>2</sup><font face=symbol><sup></sup></font>/Mg half-reactions? Which metal is the cathode? Standard Reduction Potentials (volts) in Aqueous Solution   <font face=symbol></font>1.80   <font face=symbol></font>1.50   <font face=symbol></font>0.771   <font face=symbol></font>0.535   <font face=symbol></font>0.124   <font face=symbol></font>1.66   <font face=symbol></font>2.37   <font face=symbol></font>2.93 2.93

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What is the most important use for a standard hydrogen electrode?

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What constitutes a standard hydrogen electrode?

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Which statement about a cathode in a voltaic cell is not correct?

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The charge supplied by a battery can be determined by ________

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If the potential of a voltaic cell is 0.837 V, what is the free-energy change when two moles of electrons are transferred in the oxidation-reduction reaction?

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How much work can be done using a 1.50-V alkaline battery in which 2 moles of electrons are transferred from the anode to the cathode?

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