Exam 22: Reactions of Benzene and Its Derivatives

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Consider the following compounds. Consider the following compounds.         Use the number of the compound to answer the following question. Place the number in the blank provided. -The name of the expected product from the following reaction is ___________________.  Consider the following compounds.         Use the number of the compound to answer the following question. Place the number in the blank provided. -The name of the expected product from the following reaction is ___________________.  Consider the following compounds.         Use the number of the compound to answer the following question. Place the number in the blank provided. -The name of the expected product from the following reaction is ___________________.  Consider the following compounds.         Use the number of the compound to answer the following question. Place the number in the blank provided. -The name of the expected product from the following reaction is ___________________.  Use the number of the compound to answer the following question. Place the number in the blank provided. -The name of the expected product from the following reaction is ___________________. Consider the following compounds.         Use the number of the compound to answer the following question. Place the number in the blank provided. -The name of the expected product from the following reaction is ___________________.

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4-ethyl-1,3-dimethylbenzene

Which of the following sets of substituents are all deactivating groups in electrophilic aromatic substitution reactions?

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A

What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

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D

What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

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MATCHING MATCH a structure or term from the following list with each description below. Place the letter of the structure or term in the blank to the left of the description. -______ The electrophile in aromatic nitration.

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MATCHING MATCH a structure or term from the following list with each description below. Place the letter of the structure or term in the blank to the left of the description. -______ Intermediate in the elimination-addition mechanism of nucleophilic aromatic substitution.

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What type of intermediate is formed in the reaction between bromobenzene and sodium amide to give aniline?

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

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Which of the following is the reactive intermediate formed in the electrophilic Friedel-Crafts acylation of toluene with CH3COCl and AlCl3? Which of the following is the reactive intermediate formed in the electrophilic Friedel-Crafts acylation of toluene with CH<sub>3</sub>COCl and AlCl<sub>3</sub>?

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What type of intermediate is formed in the reaction between chlorobenzene and tert-butyl chloride and AlCl3 to give 4-chloro-1-tert-butylbenzene?

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

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MATCHING MATCH a structure or term from the following list with each description below. Place the letter of the structure or term in the blank to the left of the description. -______ Groups which activate aromatic rings towards nucleophilic substitution.

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Among the following groups, 2, 3, and 5 are meta-directing. 1. -Cl 2. -NO2 3. -SO3H 4. -CH3 5. -COCH3

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

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Which of the following is not true about Meissenheimer complexes?

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

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What type of intermediate is formed in upon irradiation of a mixture of toluene and chlorine to give benzyl chloride?

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

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Which of the following sets of reagents does not result in alkylation of benzene?

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