Exam 13: Chemical Kinetics

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The activation energy for the following first-order reaction is 102 kJ/mol. N2O5(g) 2NO2(g)+ 1/2O2(g) The value of the rate constant (k)is 1.35 10-4 s-1 at 35°C. What is the value of k at 0°C?

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When the concentrations of reactant molecules are increased, the rate of reaction increases.The best explanation for this phenomenon is that as the reactant concentration increases,

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The oxidation of iodide ions by arsenic acid in acidic aqueous solution occurs according to the net reaction H3AsO4 + 3I - + 2 H3O + H3AsO3 + I3- + H2O.The experimental rate law for this reaction is Rate = k [H3AsO4] [I-] [H3O+]. According to the rate law for the reaction, an increase in the concentration of hydronium ion has what effect on this reaction?

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In the reaction, 2N2O 2N2 + O2, oxygen and nitrogen gases are formed at the same rate (mol/L·s).

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At 25°C, by what factor is the reaction rate increased by a catalyst that reduces the activation energy of the reaction by 1.00 kJ/mol?

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The rate constant of a first-order reaction, A products, can be determined from a graph of ln[A] versus t.

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The isomerization of cyclopropane follows first order kinetics. The rate constant at 700 K is 6.20 10-4 min-1, and the half-life at 760 K is 29.0 min. Calculate the activation energy for this reaction.

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Calculate the activation energy, in kJ/mol, for the redox reaction Sn2+ + 2Co3+ Sn4+ + 2Co2+. Calculate the activation energy, in kJ/mol, for the redox reaction Sn<sup>2+</sup> + 2Co<sup>3+</sup> <font face=symbol></font> Sn<sup>4+</sup> + 2Co<sup>2+</sup>.

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The following initial rate data apply to the reaction below. F2(g)+ 2Cl2O(g) 2FClO2(g)+ Cl2(g) The following initial rate data apply to the reaction below. F<sub>2</sub>(g)+ 2Cl<sub>2</sub>O(g)<font face=symbol></font> 2FClO<sub>2</sub>(g)+ Cl<sub>2</sub>(g)   Which of the following is the rate law (rate equation)for this reaction? Which of the following is the rate law (rate equation)for this reaction?

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A nuclear stress test utilizes a gamma-emitting radioisotope such as thallium-201 to follow the flow of blood through the heart - first at rest, and then under stress.The first-order rate constant for the decay of thallium-201 is 9.5 x 10-3 hr-1.Calculate how long it takes for the amount of thallium-201 to fall to 5.0% of its original value.

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Nitric acid is formed by the gas-phase hydrolysis of N2O5. Draw an energy profile curve for the reaction N2O5 + H2O 2HNO3 given that Ea(forward)= 15 kJ and Ea(reverse)= 51 kJ/mol.Label the activation energies of the forward and reverse reactions and label H for the reaction.

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What is the slope of an Arrhenius plot for the following reaction? 2NOCl 2NO + Cl2 What is the slope of an Arrhenius plot for the following reaction? 2NOCl <font face=symbol></font> 2NO + Cl<sub>2</sub>

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Ammonium ion (NH4+)reacts with nitrite ion (NO2-)to yield nitrogen gas and liquid water.The following initial rates of reaction have been measured for the given reactant concentrations. Ammonium ion (NH<sub>4</sub><sup>+</sup>)reacts with nitrite ion (NO<sub>2</sub><sup>-</sup>)to yield nitrogen gas and liquid water.The following initial rates of reaction have been measured for the given reactant concentrations.   Which of the following is the rate law (rate equation)for this reaction? Which of the following is the rate law (rate equation)for this reaction?

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The isomerization of methyl isocyanide, CH3NC CH3CN, follows first-order kinetics.The half-lives were found to be 161 min at 199°C and 12.5 min at 230°C. Calculate the activation energy for this reaction.

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