Exam 9: Chemical Bonding I: Basic Concepts

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Carbonic acid, H2CO3, is a weak acid that contributes to the taste and produces the carbon dioxide bubbles in all carbonated beverages.Write a Lewis structure for H2CO3,

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The number of resonance structures for the nitrate ion that satisfy the octet rule is

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C

Which one of the following is most likely to be an ionic compound?

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A

Which one of the following molecules has an atom with an expanded octet?

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The number of lone electron pairs in the NO2- ion is ___.

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Which one of the following is most likely to be a covalent compound?

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The Lewis dot symbol for the calcium ion is

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Calculate the energy change for the reaction K(g)+ Br(g) →\rarr K+(g)+ Br- (g) Given the following ionization energy (IE)and electron affinity (EA)values  Calculate the energy change for the reaction K(g)+ Br(g) \rarr  K<sup>+</sup>(g)+ Br<sup>-</sup> (g) Given the following ionization energy (IE)and electron affinity (EA)values

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Which of the following is a useful guideline for the application of formal charges in neutral molecules?

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Which one of the following ionic solids would have the largest lattice energy?

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The electron dot formula for O2 shows

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Assuming the octet rule is obeyed, how many covalent bonds will a nitrogen atom form to give a formal charge of zero?

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Nitrous oxide, N2O, is sometimes called "laughing gas". What is the formal charge on the central nitrogen atom in the best Lewis structure for nitrous oxide? (The atom connectivity is N-N-O.)

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Write the chemical equation for which the enthalpy of reaction is the lattice energy of KCl(s).

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Write a Lewis structure for the chlorate ion, ClO3-, that expands the octet to minimize formal charge and if necessary places negative formal charges on the most electronegative atom(s).

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Use bond energies to estimate the enthalpy of formation of HBr(g). BE(H-H)= 436 kJ/mol BE(Br-Br)= 192 kJ/mol BE(H-Br)= 366 kJ/mol

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Write a Lewis structure for the phosphate ion, PO43-, that obeys the octet rule, showing all non-zero formal charges, and give the total number of resonance structures for PO43- that obey the octet rule.

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Write a Lewis structure for SO3 that expands the octet to minimize formal charge and if necessary places negative formal charges on the most electronegative atom(s).

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Write a Lewis structure for the chlorite ion, ClO2-, that expands the octet to minimize formal charge and if necessary places negative formal charges on the most electronegative atom(s).

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Which of the following Lewis structures is incorrect?

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