Exam 19: Electrochemistry

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Complete and balance the following redox reaction under acidic conditions: MnO4-(aq)+ C2O42-(aq) →\to Mn2+(aq)+ CO2(aq)

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2MnO4-(aq)+ 5C2O42-(aq)+ 16H+(aq) →\to 2Mn2+(aq)+ 10CO2(aq)+ 8H2O(l)

Calculate the value of E°cell for the following reaction: 2Au(s)+ 3Ca2+(aq) →\to 2Au3+(aq)+ 3Ca(s)

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A

The half-reaction occurring at the cathode during electrolysis of an aqueous copper(II)iodide solution is

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C

Given the following standard reduction potentials in acid solution Given the following standard reduction potentials in acid solution   write the formula of the weakest reducing agent. write the formula of the weakest reducing agent.

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A battery is constructed by placing copper and lead electrodes in contact with 1.0 molar CuSO4(aq)and Pb(NO3)2 (aq)solutions, respectively. If sulfuric acid is then added to the Pb(NO3)2 solution, thereby forming a precipitate of PbSO4, what will happen to the cell potential?

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Under standard-state conditions, which of the following half-reactions occurs at the cathode during the electrolysis of aqueous nickel sulfate at 25°C?

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According to the following cell diagram, which chemical species undergoes reduction? Sn | Sn2+ || NO3- (acid soln), NO(g)| Pt

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You wish to electroplate a metal utensil with a surface area of 736 cm2 with gold to give an average thickness of 0.025 mm over the entire surface.Starting with a solution of excess Au3+ and applying a constant current of 14 A, how long will it take to electroplate the utensil? The density of gold is 19.3 g/cm3.

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Complete and balance the following redox equation using the set of smallest whole-number coefficients. Now sum the coefficients of all species in the balanced equation. (Remember the coefficients that are equal to one.)The sum of the coefficients is BrO3-(aq)+ Sb3+(aq) →\to Br-(aq)+ Sb5+(aq)(acidic solution)

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In an electrolytic cell, electrical energy is used to cause a chemical reaction to occur that would otherwise be nonspontaneous.

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Complete and balance the following redox equation. The sum of the smallest whole-number coefficients is Br2 →\to BrO3- + Br- (basic solution)

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A standard hydrogen electrode is immersed in an acetic acid solution. This electrode is connected by an external circuit to an iron nail dipping into 0.10 M FeCl2. If Ecell is found to be 0.24 V, what is the pH of the acetic acid solution?

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Complete and balance the following redox reaction under acidic conditions: Cr2O72-(aq)+ I-(aq) →\to Cr3+(aq)+ IO3-(aq)

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Given the following standard reduction potentials in acid solution Given the following standard reduction potentials in acid solution   write the formula of the strongest oxidizing agent. write the formula of the strongest oxidizing agent.

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How many grams of nickel would be electroplated by passing a constant current of 7.2 A through a solution of NiSO4 for 90.0 min?

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How many moles of silver metal are produced in 1.2 hours by the electrolysis of AgNO3(aq)using a current of 6.0 A?

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Complete and balance the following redox reaction under acidic conditions: Cu(s)+ NO3-(aq) →\to Cu2+(aq)+ NO2(g)

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Complete and balance the following redox equation using the smallest whole-number coefficients. What is the coefficient of Sn in the balanced equation? Sn + HNO3 →\to SnO2 + NO2 + H2O (acidic solution)

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What concentration of Ni2+ ion remains in solution after electrolysis of 100.mL of 0.250 M NiSO4 solution when using a current of 2.40 amperes for 30.0 minutes? Assume Ni metal is plated out.

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Complete and balance the following redox equation that occurs in acidic solution using the set of smallest whole-number coefficients. What is the sum of all the coefficients in the equation? PbO2(s)+ Cl- →\to Pb2+ + Cl2(g)(acidic solution)

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