Exam 19: Electrochemistry

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Consider an electrochemical cell constructed from the following half cells, linked by an external circuit and by a KCl salt bridge. • an Al(s)electrode in 1.0 M Al(NO3)3 solution • a Pb(s)electrode in 1.0 M Pb(NO3)2 solution The balanced overall (net)cell reaction is

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Calculate the cell emf for the following reaction at 25°C: 2Ag+(0.010 M)+ H2(1 atm) →\to 2Ag(s)+ 2H+(pH = 6.0)

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Calculate the cell emf for the following reaction at 25°C: 2Ag+(0.010 M)+ H2(1 atm) →\to 2Ag(s)+ 2H+(pH = 10.0)

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How long will it take to produce 78 g of Al metal by the reduction of Al3+ in an electrolytic cell with a current of 2.0 A?

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For the electrochemical cell Pt(s)| H2(1 atm)| H+(1 M)|| Cu2+(1 M)| Cu(s), which one of the following changes will cause an increase in the cell voltage?

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Consider the following standard reduction potentials in acid solution: Consider the following standard reduction potentials in acid solution:   The strongest reducing agent among those shown above is The strongest reducing agent among those shown above is

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A certain electrochemical cell has for its cell reaction: Zn + HgO →\to ZnO + Hg Which is the half-reaction occurring at the anode?

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Consider an electrochemical cell based on the spontaneous reaction 2AgCl(s)+ Zn(s) →\to 2Ag(s)+ 2Cl- + Zn2+. If the zinc ion concentration is kept constant at 1 M, and the chlorine ion concentration is decreased from 1 M to 0.001 M, the cell voltage should

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Given the following standard reduction potentials, Given the following standard reduction potentials,   calculate the solubility product of AgCN at 25°C. calculate the solubility product of AgCN at 25°C.

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The half-reaction that occurs at the cathode during electrolysis of an aqueous CuCl2 solution is

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Predict the products obtained from electrolysis of a 1 M AlBr3 solution. Note that 2H2O(l)+ 2e- →\to H2(g)+ 2OH-(aq), E°red = -0.83 V, and O2(g)+ 4H+(aq)+ 4e- →\to 2H2O(l), E°red = +1.23 V

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Consider the reaction Fe + Sn2+(1 ×\times 10-3 M) →\to Fe2+(1.0 M)+ Sn. Calculate the voltage theoretically generated by the cell.

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Complete and balance the following redox equation. When properly balanced using the smallest whole-number coefficients, the coefficient of S is H2S + HNO3 →\to S + NO (acidic solution)

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A current of 0.80 A was applied to an electrolytic cell containing molten CdCl2 for 2.5 hours.Calculate the mass of cadmium metal deposited.

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If the measured voltage of the cell Zn(s)| Zn2+(aq)|| Ag+(aq)| Ag(s)is 1.37 V when the concentration of Zn2+ ion is 0.010 M, what is the Ag+ ion concentration?

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Which one of the following reagents is capable of transforming Fe3+ (1 M)to Fe2+ (1 M)?

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For the reaction Ni2+(aq)+ 2Fe2+(aq) →\to Ni(s)+ 2Fe3+(aq), the standard cell potential E°cell is

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Which of these metals will not be oxidized in hydrochloric acid under standard conditions at 25°C?

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Consider an electrochemical cell with the following cell reaction where all reactants and products are at standard-state conditions: Cu2+(aq)+ H2(g) →\to Cu(s)+ 2H+(aq).Predict the effect on the emf of this cell of adding NaOH solution to the hydrogen half-cell until the pH equals 7.0.

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Which one of the following reagents is capable of transforming Cu(s)to Cu2+ (1 M)?

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