Exam 14: Chemical Equilibrium

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Given the following information: 2A(g)+ B(g) Given the following information: 2A(g)+ B(g)   <sub> </sub> A<sub>2</sub>B(g)K<sub>p1</sub> <sub> </sub>2A(g)+ C<sub>2</sub>(g)   <sub> </sub> <sub> </sub>2AC(g)K<sub>p2</sub> <sub> </sub> 3/2 A<sub>2</sub> + B(g)+ C(g)   <sub> </sub> AC(g)+ A<sub>2</sub>B(g)K<sub>p3</sub> <sub> </sub> <sub> </sub>Which relationship represents the equilibrium constant for the reaction: 4A(g)+ C<sub>2</sub>(g)+ A<sub>2</sub>B(g)   <sub> </sub> <sub> </sub>3A<sub>2</sub>(g)+ B(g)+ 2C(g) A2B(g)Kp1 2A(g)+ C2(g) Given the following information: 2A(g)+ B(g)   <sub> </sub> A<sub>2</sub>B(g)K<sub>p1</sub> <sub> </sub>2A(g)+ C<sub>2</sub>(g)   <sub> </sub> <sub> </sub>2AC(g)K<sub>p2</sub> <sub> </sub> 3/2 A<sub>2</sub> + B(g)+ C(g)   <sub> </sub> AC(g)+ A<sub>2</sub>B(g)K<sub>p3</sub> <sub> </sub> <sub> </sub>Which relationship represents the equilibrium constant for the reaction: 4A(g)+ C<sub>2</sub>(g)+ A<sub>2</sub>B(g)   <sub> </sub> <sub> </sub>3A<sub>2</sub>(g)+ B(g)+ 2C(g) 2AC(g)Kp2 3/2 A2 + B(g)+ C(g) Given the following information: 2A(g)+ B(g)   <sub> </sub> A<sub>2</sub>B(g)K<sub>p1</sub> <sub> </sub>2A(g)+ C<sub>2</sub>(g)   <sub> </sub> <sub> </sub>2AC(g)K<sub>p2</sub> <sub> </sub> 3/2 A<sub>2</sub> + B(g)+ C(g)   <sub> </sub> AC(g)+ A<sub>2</sub>B(g)K<sub>p3</sub> <sub> </sub> <sub> </sub>Which relationship represents the equilibrium constant for the reaction: 4A(g)+ C<sub>2</sub>(g)+ A<sub>2</sub>B(g)   <sub> </sub> <sub> </sub>3A<sub>2</sub>(g)+ B(g)+ 2C(g) AC(g)+ A2B(g)Kp3 Which relationship represents the equilibrium constant for the reaction: 4A(g)+ C2(g)+ A2B(g) Given the following information: 2A(g)+ B(g)   <sub> </sub> A<sub>2</sub>B(g)K<sub>p1</sub> <sub> </sub>2A(g)+ C<sub>2</sub>(g)   <sub> </sub> <sub> </sub>2AC(g)K<sub>p2</sub> <sub> </sub> 3/2 A<sub>2</sub> + B(g)+ C(g)   <sub> </sub> AC(g)+ A<sub>2</sub>B(g)K<sub>p3</sub> <sub> </sub> <sub> </sub>Which relationship represents the equilibrium constant for the reaction: 4A(g)+ C<sub>2</sub>(g)+ A<sub>2</sub>B(g)   <sub> </sub> <sub> </sub>3A<sub>2</sub>(g)+ B(g)+ 2C(g) 3A2(g)+ B(g)+ 2C(g)

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The equilibrium constant expression for the following reaction CuO(s)+ H2(g) The equilibrium constant expression for the following reaction CuO(s)+ H<sub>2</sub>(g)   <sub> </sub> Cu(s)+ H<sub>2</sub>O(g)is K<sub>c</sub> = [H<sub>2</sub>]/[H<sub>2</sub>O]. Cu(s)+ H2O(g)is Kc = [H2]/[H2O].

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When the reaction 2H2S(g) When the reaction 2H<sub>2</sub>S(g)   <sub> </sub> 2H<sub>2</sub>(g)+ S<sub>2</sub>(g)is carried out at 1065°C, K<sub>p</sub> = 0.012.Starting with pure H<sub>2</sub>S at 1065°, what must the initial pressure of H<sub>2</sub>S be if the equilibrated mixture at this temperature is to contain 0.250 atm of H<sub>2</sub>(g)? 2H2(g)+ S2(g)is carried out at 1065°C, Kp = 0.012.Starting with pure H2S at 1065°, what must the initial pressure of H2S be if the equilibrated mixture at this temperature is to contain 0.250 atm of H2(g)?

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Which is the correct equilibrium constant expression for the following reaction? Fe2O3 (s)+ 3H2 (g) Which is the correct equilibrium constant expression for the following reaction? Fe<sub>2</sub>O<sub>3 </sub>(s)+ 3H<sub>2 </sub>(g)<sub> </sub> <sub> </sub>   <sub> </sub> <sub> </sub>2Fe (s)+ 3H<sub>2</sub>O (g) 2Fe (s)+ 3H2O (g)

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Consider this reaction at equilibrium at a total pressure P1: 2SO2(g)+ O2(g) Consider this reaction at equilibrium at a total pressure P<sub>1</sub>: 2SO<sub>2</sub>(g)+ O<sub>2</sub>(g)   <sub> </sub> 2SO<sub>3</sub>(g) Suppose the volume of this system is compressed to one-half its initial volume and then equilibrium is reestablished.The new equilibrium total pressure will be 2SO3(g) Suppose the volume of this system is compressed to one-half its initial volume and then equilibrium is reestablished.The new equilibrium total pressure will be

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The Kc for the reaction CO2(g)+ H2(g) The K<sub>c</sub> for the reaction CO<sub>2</sub>(g)+ H<sub>2</sub>(g)   <sub> </sub> H<sub>2</sub>O(g)+ CO(g)is 1.6 at about 990ºC.Calculate the number of moles of hydrogen gas in the final equilibrium system obtained by initially adding 1.00 mol of H<sub>2</sub>, 2.00 mol of CO<sub>2</sub>, 0.750 mol of H<sub>2</sub>O, and 1.00 mol of CO to a 5.00 L reactor at 990ºC. H2O(g)+ CO(g)is 1.6 at about 990ºC.Calculate the number of moles of hydrogen gas in the final equilibrium system obtained by initially adding 1.00 mol of H2, 2.00 mol of CO2, 0.750 mol of H2O, and 1.00 mol of CO to a 5.00 L reactor at 990ºC.

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Calcium carbonate decomposes at high temperatures to give calcium oxide and carbon dioxide as shown below. CaCO3(s) Calcium carbonate decomposes at high temperatures to give calcium oxide and carbon dioxide as shown below. CaCO<sub>3</sub>(s)   <sub> </sub> CaO(s)+ CO<sub>2</sub>(g) The K<sub>P</sub> for this reaction is 1.16 at 800°C.A 5.00 L vessel containing 10.0 g of CaCO<sub>3</sub>(s)was evacuated to remove the air, sealed, and then heated to 800°C.Ignoring the volume occupied by the solid, what will be the overall mass percent of carbon in the solid once equilibrium is reached? CaO(s)+ CO2(g) The KP for this reaction is 1.16 at 800°C.A 5.00 L vessel containing 10.0 g of CaCO3(s)was evacuated to remove the air, sealed, and then heated to 800°C.Ignoring the volume occupied by the solid, what will be the overall mass percent of carbon in the solid once equilibrium is reached?

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Carbon tetrachloride reacts at high temperatures with oxygen to produce two toxic gases, phosgene and chlorine. CCl4(g)+ 1/2O2(g) Carbon tetrachloride reacts at high temperatures with oxygen to produce two toxic gases, phosgene and chlorine. CCl<sub>4</sub>(g)+ <sup>1</sup>/<sub>2</sub>O<sub>2</sub>(g)   <sub> </sub> COCl<sub>2</sub>(g)+ Cl<sub>2</sub>(g), K<sub>c</sub> = 4.4 × 10<sup>9</sup> at 1,000 K Calculate K<sub>c</sub> for the reaction 2CCl<sub>4</sub>(g)+ O<sub>2</sub>(g)   <sub> </sub> 2COCl<sub>2</sub>(g)+ 2Cl<sub>2</sub>(g). COCl2(g)+ Cl2(g), Kc = 4.4 × 109 at 1,000 K Calculate Kc for the reaction 2CCl4(g)+ O2(g) Carbon tetrachloride reacts at high temperatures with oxygen to produce two toxic gases, phosgene and chlorine. CCl<sub>4</sub>(g)+ <sup>1</sup>/<sub>2</sub>O<sub>2</sub>(g)   <sub> </sub> COCl<sub>2</sub>(g)+ Cl<sub>2</sub>(g), K<sub>c</sub> = 4.4 × 10<sup>9</sup> at 1,000 K Calculate K<sub>c</sub> for the reaction 2CCl<sub>4</sub>(g)+ O<sub>2</sub>(g)   <sub> </sub> 2COCl<sub>2</sub>(g)+ 2Cl<sub>2</sub>(g). 2COCl2(g)+ 2Cl2(g).

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The Kc for the reaction CO2(g)+ H2(g) The K<sub>c</sub> for the reaction CO<sub>2</sub>(g)+ H<sub>2</sub>(g)   <sub> </sub> H<sub>2</sub>O(g)+ CO(g)is 1.6 at about 990ºC.Calculate the number of moles of carbon monoxide in the final equilibrium system obtained by initially adding 1.00 mol of H<sub>2</sub>, 2.00 mol of CO<sub>2</sub>, 0.750 mol of H<sub>2</sub>O, and 1.00 mol of CO to a 5.00 L reactor at 990ºC. H2O(g)+ CO(g)is 1.6 at about 990ºC.Calculate the number of moles of carbon monoxide in the final equilibrium system obtained by initially adding 1.00 mol of H2, 2.00 mol of CO2, 0.750 mol of H2O, and 1.00 mol of CO to a 5.00 L reactor at 990ºC.

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The equilibrium constant expression for the reaction: N2 (g)+ O2 (g) The equilibrium constant expression for the reaction: N<sub>2 </sub>(g)+ O<sub>2 </sub>(g)   <sub> </sub> 2NO (g)is 2NO (g)is

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Consider the reaction, N2(g)+ 3H2(g) Consider the reaction, N<sub>2</sub>(g)+ 3H<sub>2</sub>(g)   <sub> </sub> 2NH<sub>3</sub>(g).K<sub>c</sub> = 8.1 x 10<sup>-3</sup> at 900 K. What is the value of K<sub>c</sub> for NH<sub>3</sub>(g)   <sub> </sub> ½N<sub>2</sub>(g)+ 3/2H<sub>2</sub>(g) 2NH3(g).Kc = 8.1 x 10-3 at 900 K. What is the value of Kc for NH3(g) Consider the reaction, N<sub>2</sub>(g)+ 3H<sub>2</sub>(g)   <sub> </sub> 2NH<sub>3</sub>(g).K<sub>c</sub> = 8.1 x 10<sup>-3</sup> at 900 K. What is the value of K<sub>c</sub> for NH<sub>3</sub>(g)   <sub> </sub> ½N<sub>2</sub>(g)+ 3/2H<sub>2</sub>(g) ½N2(g)+ 3/2H2(g)

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The reaction A(g)+ 2B(g) The reaction A(g)+ 2B(g)   <sub> </sub> <sub> </sub>C(g)was allowed to come to equilibrium.The initial amounts of reactants placed into a 5.00 L vessel were 1.0 mol A and 1.8 mol B.After the reaction reached equilibrium, 1.0 mol of B was found.Calculate K<sub>c</sub> for this reaction. C(g)was allowed to come to equilibrium.The initial amounts of reactants placed into a 5.00 L vessel were 1.0 mol A and 1.8 mol B.After the reaction reached equilibrium, 1.0 mol of B was found.Calculate Kc for this reaction.

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Consider the following equilibrium, 4NH3(g)+ 3O2(g) Consider the following equilibrium, 4NH<sub>3</sub>(g)+ 3O<sub>2</sub>(g)   <sub> </sub> 2N<sub>2</sub>(g)+ 6H<sub>2</sub>O(g)+ 1531 kJ State whether the concentrations of the reactants would increase, decrease, or remain constant when the temperature is increased. 2N2(g)+ 6H2O(g)+ 1531 kJ State whether the concentrations of the reactants would increase, decrease, or remain constant when the temperature is increased.

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If one starts with pure NO2(g)at a pressure of 0.500 atm, the total pressure inside the reaction vessel when 2NO2(g) If one starts with pure NO<sub>2</sub>(g)at a pressure of 0.500 atm, the total pressure inside the reaction vessel when 2NO<sub>2</sub>(g)   <sub> </sub> 2NO(g)+ O<sub>2</sub>(g)reaches equilibrium is 0.674 atm.Calculate the equilibrium partial pressure of NO<sub>2</sub>. 2NO(g)+ O2(g)reaches equilibrium is 0.674 atm.Calculate the equilibrium partial pressure of NO2.

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A quantity of liquid methanol, CH3OH, is introduced into a rigid 3.00-L vessel, the vessel is sealed, and the temperature is raised to 500K.At this temperature, the methanol vaporizes and decomposes according to the reaction CH3OH(g) A quantity of liquid methanol, CH<sub>3</sub>OH, is introduced into a rigid 3.00-L vessel, the vessel is sealed, and the temperature is raised to 500K.At this temperature, the methanol vaporizes and decomposes according to the reaction CH<sub>3</sub>OH(g)   <sub> </sub> CO(g)+ 2 H<sub>2</sub>(g), K<sub>c</sub>= 6.90×10<sup>-2</sup>. If the concentration of H<sub>2</sub> in the equilibrium mixture is 0.426M, what mass of methanol was initially introduced into the vessel? CO(g)+ 2 H2(g), Kc= 6.90×10-2. If the concentration of H2 in the equilibrium mixture is 0.426M, what mass of methanol was initially introduced into the vessel?

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The data below refer to the following reaction: 2NO(g)+ Br2(g) The data below refer to the following reaction: 2NO(g)+ Br<sub>2</sub>(g)   <sub> </sub> 2NOBr(g)   Find the concentration of NOBr when the system reaches equilibrium. 2NOBr(g) The data below refer to the following reaction: 2NO(g)+ Br<sub>2</sub>(g)   <sub> </sub> 2NOBr(g)   Find the concentration of NOBr when the system reaches equilibrium. Find the concentration of NOBr when the system reaches equilibrium.

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At 35ºC, the equilibrium constant for the reaction 2NOCl(g) At 35ºC, the equilibrium constant for the reaction 2NOCl(g)   <sub> </sub> 2NO(g)+ Cl<sub>2</sub>(g)is K<sub>c</sub> = 1.6 × 10<sup>-5</sup>.An equilibrium mixture was found to have the following concentrations of Cl<sub>2</sub> and NOCl: [Cl<sub>2</sub>] = 1.2 × 10<sup>-2 </sup>M; [NOCl] = 2.8 × 10<sup>-1 </sup>M.Calculate the concentration of NO(g)at equilibrium. 2NO(g)+ Cl2(g)is Kc = 1.6 × 10-5.An equilibrium mixture was found to have the following concentrations of Cl2 and NOCl: [Cl2] = 1.2 × 10-2 M; [NOCl] = 2.8 × 10-1 M.Calculate the concentration of NO(g)at equilibrium.

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Consider the reaction N2(g)+ 3H2(g) Consider the reaction N<sub>2</sub>(g)+ 3H<sub>2</sub>(g)   <sub> </sub> 2NH<sub>3</sub>(g).If hydrogen gas is added to this system at equilibrium, will the reaction shift towards reactants or products? 2NH3(g).If hydrogen gas is added to this system at equilibrium, will the reaction shift towards reactants or products?

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For the reaction 2NOCl(g) For the reaction 2NOCl(g)   <sub> </sub> 2NO(g)+ Cl<sub>2</sub>(g), K<sub>c</sub> = 8.0 at a certain temperature.What concentration of NOCl must be put into an empty 4.00 L reaction vessel in order that the equilibrium concentration of NOCl be 1.00 M? 2NO(g)+ Cl2(g), Kc = 8.0 at a certain temperature.What concentration of NOCl must be put into an empty 4.00 L reaction vessel in order that the equilibrium concentration of NOCl be 1.00 M?

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The common allotropes of carbon (graphite and diamond), C(gr)  The common allotropes of carbon (graphite and diamond), C(gr)   <sub> </sub> C(dia)with equilibrium constant K = 0.32.The molar volumes of graphite and diamond are, respectively, 5.30 cm<sup>3</sup>/mol and 3.42 cm<sup>3</sup>/mol;  \Delta H<sub>f</sub> of diamond is 1.90 kJ/mol.This data suggests that the formation of diamond is favored at C(dia)with equilibrium constant K = 0.32.The molar volumes of graphite and diamond are, respectively, 5.30 cm3/mol and 3.42 cm3/mol; Δ\Delta Hf of diamond is 1.90 kJ/mol.This data suggests that the formation of diamond is favored at

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