Exam 14: Chemical Equilibrium
Exam 1: Chemistry: the Study of Change168 Questions
Exam 2: Atoms, Molecules, and Ions156 Questions
Exam 3: Mass Relationships in Chemical Reactions194 Questions
Exam 4: Reactions in Aqueous Solutions186 Questions
Exam 5: Gases121 Questions
Exam 6: Thermochemistry118 Questions
Exam 7: Quantum Theory and the Electronic Structure of Atoms136 Questions
Exam 8: Periodic Relationships Among the Elements144 Questions
Exam 9: Chemical Bonding I: Basic Concepts137 Questions
Exam 10: Chemical Bonding Ii: Molecular Geometry and Hybridization of Atomic Orbitals147 Questions
Exam 11: Intermolecular Forces and Liquids and Solids149 Questions
Exam 12: Physical Properties of Solutions122 Questions
Exam 13: Chemical Kinetics130 Questions
Exam 14: Chemical Equilibrium109 Questions
Exam 15: Acids and Bases178 Questions
Exam 16: Acid-Base Equilibria and Solubility Equilibria131 Questions
Exam 17: Entropy Free Energy and Equilibrium128 Questions
Exam 18: Electrochemistry154 Questions
Exam 19: Nuclear Chemistry133 Questions
Exam 20: Chemistry in the Atmosphere50 Questions
Exam 21: Metallurgy and the Chemistry of Metals63 Questions
Exam 22: Nonmetallic Elements and Their Compounds52 Questions
Exam 23: Transition Metal Chemistry and Coordination Compounds92 Questions
Exam 24: Organic Chemistry67 Questions
Exam 25: Synthetic and Natural Organic Polymers50 Questions
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Given the following information: 2A(g)+ B(g)
A2B(g)Kp1
2A(g)+ C2(g)
2AC(g)Kp2
3/2 A2 + B(g)+ C(g)
AC(g)+ A2B(g)Kp3
Which relationship represents the equilibrium constant for the reaction:
4A(g)+ C2(g)+ A2B(g)
3A2(g)+ B(g)+ 2C(g)
(Multiple Choice)
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The equilibrium constant expression for the following reaction
CuO(s)+ H2(g)
Cu(s)+ H2O(g)is Kc = [H2]/[H2O].
(True/False)
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When the reaction 2H2S(g)
2H2(g)+ S2(g)is carried out at 1065°C, Kp = 0.012.Starting with pure H2S at 1065°, what must the initial pressure of H2S be if the equilibrated mixture at this temperature is to contain 0.250 atm of H2(g)?
(Multiple Choice)
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Which is the correct equilibrium constant expression for the following reaction? Fe2O3 (s)+ 3H2 (g)
2Fe (s)+ 3H2O (g)
(Multiple Choice)
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Consider this reaction at equilibrium at a total pressure P1: 2SO2(g)+ O2(g)
2SO3(g)
Suppose the volume of this system is compressed to one-half its initial volume and then equilibrium is reestablished.The new equilibrium total pressure will be
(Multiple Choice)
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The Kc for the reaction CO2(g)+ H2(g)
H2O(g)+ CO(g)is 1.6 at about 990ºC.Calculate the number of moles of hydrogen gas in the final equilibrium system obtained by initially adding 1.00 mol of H2, 2.00 mol of CO2, 0.750 mol of H2O, and 1.00 mol of CO to a 5.00 L reactor at 990ºC.
(Short Answer)
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Calcium carbonate decomposes at high temperatures to give calcium oxide and carbon dioxide as shown below.
CaCO3(s)
CaO(s)+ CO2(g)
The KP for this reaction is 1.16 at 800°C.A 5.00 L vessel containing 10.0 g of CaCO3(s)was evacuated to remove the air, sealed, and then heated to 800°C.Ignoring the volume occupied by the solid, what will be the overall mass percent of carbon in the solid once equilibrium is reached?
(Short Answer)
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Carbon tetrachloride reacts at high temperatures with oxygen to produce two toxic gases, phosgene and chlorine. CCl4(g)+ 1/2O2(g)
COCl2(g)+ Cl2(g), Kc = 4.4 × 109 at 1,000 K
Calculate Kc for the reaction 2CCl4(g)+ O2(g)
2COCl2(g)+ 2Cl2(g).
(Multiple Choice)
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The Kc for the reaction CO2(g)+ H2(g)
H2O(g)+ CO(g)is 1.6 at about 990ºC.Calculate the number of moles of carbon monoxide in the final equilibrium system obtained by initially adding 1.00 mol of H2, 2.00 mol of CO2, 0.750 mol of H2O, and 1.00 mol of CO to a 5.00 L reactor at 990ºC.
(Short Answer)
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The equilibrium constant expression for the reaction: N2 (g)+ O2 (g)
2NO (g)is
(Multiple Choice)
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Consider the reaction, N2(g)+ 3H2(g)
2NH3(g).Kc = 8.1 x 10-3 at 900 K.
What is the value of Kc for NH3(g)
½N2(g)+ 3/2H2(g)
(Short Answer)
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The reaction A(g)+ 2B(g)
C(g)was allowed to come to equilibrium.The initial amounts of reactants placed into a 5.00 L vessel were 1.0 mol A and 1.8 mol B.After the reaction reached equilibrium, 1.0 mol of B was found.Calculate Kc for this reaction.
(Multiple Choice)
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Consider the following equilibrium,
4NH3(g)+ 3O2(g)
2N2(g)+ 6H2O(g)+ 1531 kJ
State whether the concentrations of the reactants would increase, decrease, or remain constant when the temperature is increased.
(Short Answer)
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If one starts with pure NO2(g)at a pressure of 0.500 atm, the total pressure inside the reaction vessel when 2NO2(g)
2NO(g)+ O2(g)reaches equilibrium is 0.674 atm.Calculate the equilibrium partial pressure of NO2.
(Multiple Choice)
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A quantity of liquid methanol, CH3OH, is introduced into a rigid 3.00-L vessel, the vessel is sealed, and the temperature is raised to 500K.At this temperature, the methanol vaporizes and decomposes according to the reaction CH3OH(g)
CO(g)+ 2 H2(g), Kc= 6.90×10-2.
If the concentration of H2 in the equilibrium mixture is 0.426M, what mass of methanol was initially introduced into the vessel?
(Multiple Choice)
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The data below refer to the following reaction:
2NO(g)+ Br2(g)
2NOBr(g)
Find the concentration of NOBr when the system reaches equilibrium.
(Short Answer)
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At 35ºC, the equilibrium constant for the reaction 2NOCl(g)
2NO(g)+ Cl2(g)is Kc = 1.6 × 10-5.An equilibrium mixture was found to have the following concentrations of Cl2 and NOCl: [Cl2] = 1.2 × 10-2 M; [NOCl] = 2.8 × 10-1 M.Calculate the concentration of NO(g)at equilibrium.
(Multiple Choice)
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Consider the reaction N2(g)+ 3H2(g)
2NH3(g).If hydrogen gas is added to this system at equilibrium, will the reaction shift towards reactants or products?
(Short Answer)
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For the reaction 2NOCl(g)
2NO(g)+ Cl2(g), Kc = 8.0 at a certain temperature.What concentration of NOCl must be put into an empty 4.00 L reaction vessel in order that the equilibrium concentration of NOCl be 1.00 M?
(Multiple Choice)
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The common allotropes of carbon (graphite and diamond), C(gr)
C(dia)with equilibrium constant K = 0.32.The molar volumes of graphite and diamond are, respectively, 5.30 cm3/mol and 3.42 cm3/mol; Hf of diamond is 1.90 kJ/mol.This data suggests that the formation of diamond is favored at
(Multiple Choice)
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