Exam 20: Chemistry in the Atmosphere

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A possible reaction leading to removal of ClO from the atmosphere is 2ClO →\rarr Cl2 + O2.Studies of this reaction have yielded an Arrhenius frequency factor, A, and an activation energy of 1.0 × 10-12 cm3 molecule-1 s-1 and 13.2 kJ/mol, respectively.Calculate the rate constant for the disappearance of ClO at -30°C.

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E

The first "hole" in the ozone layer was found over which continent?

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D

Select all of the following that are capable of destroying stratospheric ozone through chemical meAns : I.CF2Cl2 II.NO III.CO2

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Write out the steps in the mechanism of ozone destruction by nitric oxide (NO).

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List the following greenhouse gases in order of their overall magnitude of contribution to global warming: N2O, CFCs, CO2, CH4

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The most prevalent noble gas in our atmosphere is

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Which region of the atmosphere contains the ozone layer?

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The normal process occurring on Earth that warms its surface and the lower atmosphere is called

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What mass of solid CaO is needed to remove the sulfur dioxide from 1.0 × 106 m3 of air having an SO2 concentration of 1.5 × 10-9 M? Assume that the reaction leading to removal of the sulfur dioxide is CaO(s)+ SO2(g) →\rarr CaCO3(s).

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What happens to nitrogen dioxide in sunlight? Write the reaction for this process.

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Which of the following would NOT help reduce the amount of CO2 introduced into the atmosphere?

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Peroxyacetyl nitrate, called PAN for short, is a powerful lachrymator.A lachrymator is

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Write out the steps in the mechanism by which ozone is formed in the stratosphere.

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Write out the steps in the reaction scheme for nitrogen fixation by lightening.

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An unusual atmospheric reaction leading to ozone destruction is CF3O + O3 →\rarr CF3O2 + O2, the analysis of which has yielded an Arrhenius frequency factor (A)and activation energy of 2.0 × 10-12 cm3 molecule-1 s-1 and 11.6 kJ/mol, respectively.Calculate the rate constant for this reaction at an altitude of 35 km, where the temperature is -34°C.

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Determine which of the following pollutants are of capable of forming acid rain when combined with water. I.SO2 II.SO3 III.CaCO3 IV.CaO

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The rate constant of the reaction Cl + CHCl3 →\rarr HCl + CCl3 is 5.8 × 107 M-1s-1 at 25°C and has an activation energy of 11.0 kJ/mol.Calculate the rate constant for this reaction in the lower stratosphere where the temperature is -57°C.

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Determine two effects expected from the depletion of the ozone layer. 1)asthma 2)lung cancer 3)skin cancer 4)genetic mutations 5)emphysema

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One of the steps in the fixation of nitrogen by lightening is given below. 2NO2(g)+ H2O(l) →\rarr HNO2(aq)+ HNO3(aq) In this reaction, is the element nitrogen oxidized or reduced?

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The compound CFCl3 is used as a/an

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