Exam 6: Thermochemistry

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Potential energy is

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Calculate the enthalpy of reaction for H2(g)+ C2H4(g) →\rarr C2H6(g). [ Δ\Delta H°f(C2H4(g))= 52.3 kJ/mol; Δ\Delta H°f(C2H6(g))= -84.7 kJ/mol]

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-137 kJ/mol

The combustion of butane produces heat according to the equation 2C4H10(g)+ 13O2(g) →\rarr 8CO2(g)+ 10H2O(l), Δ\Delta H°rxn= -5,314 kJ/mol How many grams of CO2 are produced per 1.00 × 104 kJ of heat released?

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A 0.3423 g sample of pentane, C5H12, was burned in a bomb calorimeter.The temperature of the calorimeter and the 1.000 kg of water contained therein rose from 20.22°C to 22.82°C.The heat capacity of the calorimeter is 2.21 kJ/°C.The heat capacity of water = 4.184 J/g·°C.What is the heat of combustion, in kilojoules, per gram of pentane?

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How much heat (kJ)is evolved when 4.50 g of Fe2O3 is reacted with excess carbon monoxide using the equation below? Fe2O3(s)+ 3CO(g) →\rarr 2 Fe(s)+ 3 CO2(g) , Δ\Delta H°rxn = - 24.8 kJ/mol,

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According to the first law of thermodynamics:

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The heat of neutralization of HCl by NaOH is Δ\Delta H°rxn = -56.2 kJ/mol.How much heat is released when 125 mL of 1.750 M HCl is mixed with 195 mL of 0.667 M NaOH?

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Which of the following has a Δ\Delta H°f = 0 kJ/mol?

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Define specific heat.

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The combustion of one mole of benzene, C6H6, in oxygen liberates 3268 kJ of heat.The products of the reaction are carbon dioxide and water.How much heat is given off when 183 g of oxygen are reacted with excess benzene?

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Styrene, C8H8, is one of the substances used in the production of synthetic rubber.When styrene burns in oxygen to form carbon dioxide and liquid water under standard-state conditions at 25°C, 42.62 kJ are released per gram of styrene.Find the standard enthalpy of formation of styrene at 25°C. (Given: Δ\Delta H°f[CO2(g)] = -393.5 kJ/mol, Δ\Delta H°f[H2O(l)] = -285.8 kJ/mol, Δ\Delta H°f[H2O(g)] = -241.8 kJ/mol)

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Ozone (O3)in the atmosphere can be converted to oxygen gas by reaction with nitric oxide (NO).Nitrogen dioxide is also produced in the reaction.What is the enthalpy change when 8.50L of ozone at a pressure of 1.00 atm and 25°C reacts with 12.00 L of nitric oxide at the same initial pressure and temperature? [ Δ\Delta H°f(NO)= 90.4 kJ/mol; Δ\Delta H°f(NO2)= 33.85 kJ/mol; Δ\Delta H°f(O3)= 142.2 kJ/mol]

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Ethanol (C2H5OH)burns according to the equation C2H5OH(l)+ 3O2(g) →\rarr 2CO2(g)+ 3H2O(l), Δ\Delta H°rxn = -1367 kJ/mol. How much heat is released when 35.0 g of ethanol is burned?

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The heat released when one mole of water is formed from the elements is 1,198 kJ.An experiment was conducted that permitted water to form in this manner, and the heat was contained in 2.0 liters of water.The water temperature before the reaction was 34.5°C, and after the reaction it had risen to 52.0°C.How many moles of water were formed? (The specific heat of water is 4.184 J/g·°C.)

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Which of the following processes always results in an increase in the energy of a system?

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Find the heat absorbed from the surroundings when 15 g of O2 reacts according to the equation O + O2 →\rarr O3, Δ\Delta H°rxn= -103 kJ/mol.

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The enthalpy change when a strong acid is neutralized by strong base is -56.1 kJ/mol.If 12.0 mL of 6.00 M HBr at 21.30°C is mixed with 300.mL of 0.250 M NaOH, also at 21.30°C, what will the maximum temperature reached by the resulting solution? (Assume that there is no heat loss to the container, that the specific heat of the final solution is 4.18 J/g·°C, and that the density of the final solution is that of water.)

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Which of the following processes is endothermic, given the following: S(s)+ O2(g) →\rarr SO2(g) Δ\Delta H = -299 kJ/mol S(s)+ 3/2 O2(g) →\rarr SO3(g) Δ\Delta H = -395 kJ/mol

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Calculate the amount of work done against an atmospheric pressure of 1.00 atm when 500.0 g of zinc dissolves in excess acid at 30.0°C. Zn(s)+ 2H+(aq) →\rarr Zn2+(aq)+ H2(g)

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Methanol (CH3OH)burns according to the equation 2CH3OH(l)+ 3O2(g) →\rarr 2CO2(g)+ 4H2O(l), Δ\Delta H°rxn = -1454 kJ/mol. How much heat, in kilojoules, is given off when 75.0 g of methanol is burned?

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